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1-[(4-Methylphenyl)sulfonyl]-1H-imidazole

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1-[(4-Methylphenyl)sulfonyl]-1H-imidazole Basic information
1-[(4-Methylphenyl)sulfonyl]-1H-imidazole Chemical Properties
  • Melting point:76-78 °C(lit.)
  • Boiling point:409.1±38.0 °C(Predicted)
  • Density 1.3038 (rough estimate)
  • refractive index 1.5650 (estimate)
  • storage temp. Inert atmosphere,Room Temperature
  • solubility chloroform: soluble25mg/mL, clear, colorless to faintly yellow
  • form Crystals or Crystalline Powder
  • pka1.22±0.10(Predicted)
  • color White to slightly yellow
  • Sensitive Moisture Sensitive
  • BRN 612451
  • InChIKeyYJYMYJRAQYREBT-UHFFFAOYSA-N
  • CAS DataBase Reference2232-08-8(CAS DataBase Reference)
Safety Information
MSDS
1-[(4-Methylphenyl)sulfonyl]-1H-imidazole Usage And Synthesis
  • Chemical Propertieswhite to slightly yellow crystals
  • UsesAlcohols to azides in one step.1
  • Uses
    1-(p-Toluenesulfonyl)imidazole was used in the synthesis of cationic water soluble cyclodextrin, mono-6A-(1-butyl-3-imidazolium)-6A-deoxy-β-cyclodextrin chloride (BIMCD), useful in chiral separation of amino acids and anionic pharmaceuticals by capillary electrophoresis.
  • Synthesis Reference(s)The Journal of Organic Chemistry, 45, p. 547, 1980 DOI: 10.1021/jo01291a044
  • General Description
    1-(p-Toluenesulfonyl)imidazole converts alcohols to azides in one step.
1-[(4-Methylphenyl)sulfonyl]-1H-imidazole Preparation Products And Raw materials
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