ChemicalBook > CAS DataBase List > Dichlorophenylphosphine
Dichlorophenylphosphine
Dichlorophenylphosphine
- CAS No.644-97-3
- Chemical Name:Dichlorophenylphosphine
- CBNumber:CB7304468
- Molecular Formula:C6H5Cl2P
- Formula Weight:178.98
- MOL File:644-97-3.mol
Dichlorophenylphosphine Property
- Melting point −51 °C(lit.)
- Boiling point 222 °C759 mm Hg(lit.)
- Density 1.319 g/mL at 25 °C(lit.)
- refractive index n
20/D 1.597(lit.) - Flash point >230 °F
- storage temp. Store below +30°C.
- form Liquid
- Specific Gravity 1.319 (20℃)
- color Clear colorless to slightly yellow
- Water Solubility Reacts
- Sensitive Moisture Sensitive
- BRN 508189
- CAS DataBase Reference 644-97-3(CAS DataBase Reference)
- EWG's Food Scores 1
- NCI Dictionary of Cancer Terms BPD
- FDA UNII WRU258L1EW
- NIST Chemistry Reference Phosphonous dichloride, phenyl-(644-97-3)
- EPA Substance Registry System Phosphonous dichloride, P-phenyl- (644-97-3)
Safety
- Hazard Codes :F,T
- Risk Statements :17-25-34-29-37-35-14
- Safety Statements :26-28-36/37/39-43-45-28A
- RIDADR :UN 2845 4.2/PG 1
- WGK Germany :3
- RTECS :TB2478000
- F :10-21
- TSCA :Yes
- HazardClass :8
- PackingGroup :II
- HS Code :29310095
- Hazardous Substances Data :644-97-3(Hazardous Substances Data)
-
NFPA 704:
1 3 0
-
Symbol(GHS)
- Signal wordDanger
- Hazard statements H301-H314-H335
- Precautionary statements P261-P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Dichlorophenylphosphine Price
More Price(6)
- Brand: Sigma-Aldrich(India)
- Product number: D71984
- Product name : P,P-Dichlorophenylphosphine
- Purity: 97%
- Packaging: 100G
- Price: ₹6430.05
- Updated: 2022/06/14
- Buy: Buy
- Brand: ALFA India
- Product number: ALF-A10284-30
- Product name : Dichlorophenylphosphine, 97%
- Purity:
- Packaging: 250g
- Price: ₹5767
- Updated: 2022/05/26
- Buy: Buy
- Brand: ALFA India
- Product number: ALF-A10284-18
- Product name : Dichlorophenylphosphine, 97%
- Purity:
- Packaging: 50g
- Price: ₹3099
- Updated: 2022/05/26
- Buy: Buy
- Brand: TCI Chemicals (India)
- Product number: P0207
- Product name : Dichlorophenylphosphine
- Purity:
- Packaging: 25ML
- Price: ₹2100
- Updated: 2022/05/26
- Buy: Buy
- Brand: ALFA India
- Product number: ALF-A10284-0B
- Product name : Dichlorophenylphosphine, 97%
- Purity:
- Packaging: 1000g
- Price: ₹16582
- Updated: 2022/05/26
- Buy: Buy
Dichlorophenylphosphine Chemical Properties,Usage,Production
- Chemical Properties Colorless to light yellow liqui
- Uses Organic synthesis, for derivation of plasticizers, polymers, antioxidants; oil additives.
- Uses Dichlorophenylphosphine and its derivatives are used as an intermediate to make plasticizers, antioxidants, stabilizers, catalysts and high pressure lubricant additives and in lacquer formulatings.
- General Description A colorless, fuming liquid. Density 1.32 g / cm3. Flash point 102°C. Corrosive to metals and tissue.
- Air & Water Reactions Reacts with water, including moisture in air or soil, to liberate heat and hydrochloric acid [Merck, 11th ed. 1989].
- Reactivity Profile Dichlorophenylphosphine is incompatible with water, with bases (including amines), with strong oxidizing agents, and with alcohols. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
- Hazard Highly corrosive to skin, tissue. Flammable.
- Health Hazard Inhalation causes irritation of nose and throat; pulmonary edema may develop following severe exposures. Contact with skin or eyes causes severe burns. Ingestion causes severe burns of mouth and stomach.
- Flammability and Explosibility Non flammable
- Safety Profile A poison irritant to skin, eyes, and mucous membranes and poison by ingestion and inhalation. When heated to decomposition it emits very toxic fumes of Cland POx. See also PHOSPHINE.
- Purification Methods Distil it in a vacuum byfractionating through a 20cm column packed with glass helices (better use a spinning band column) [Buchner & Lockhart J Am Chem Soc 73 755 1951, NMR: Müller et al. J Am Chem Soc 78 3557 1956, IR: Daasch & Smith Anal Chem 23 853 1951]. It forms a yellow Ni complex: Ni(C6H5Cl2P)4 (m 91-92o, from H2O) [Quin J Am Chem Soc 79 3681 1957 ] and a yellow complex with molybdenum carbonyl: Mo(CO)3.(C6H5Cl2P)3 (m 106-110o dec) [Abel et al. J Chem Soc 2323 1959]. [Beilstein 16 IV 972.]
Dichlorophenylphosphine Preparation Products And Raw materials
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- 644-97-3
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