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(R,R)-DIPAMP
(R,R)-DIPAMP
- CAS No.55739-58-7
- Chemical Name:(R,R)-DIPAMP
- CBNumber:CB0300441
- Molecular Formula:C28H28O2P2
- Formula Weight:458.48
- MOL File:55739-58-7.mol
(R,R)-DIPAMP Property
- Melting point 102-104 °C
- alpha -88o (C=1 IN CHLOROFORM)
- Boiling point 580.2±45.0 °C(Predicted)
- refractive index -85 ° (C=1, CHCl3)
- form Crystalline Powder
- color White
- optical activity [α]22/D 81°, c = 1 in chloroform
- CAS DataBase Reference 55739-58-7
- FDA UNII BLJ831OWLW
- UNSPSC Code 12352112
- NACRES NA.22
Safety
- Hazard Codes :Xi
- Risk Statements :36/37/38
- Safety Statements :37/39-26-36/37
- WGK Germany :3
- TSCA :No
- HS Code :29319090
-
NFPA 704:
1 2 0
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H315-H319-H335-H413
- Precautionary statements P273-P302+P352-P305+P351+P338
(R,R)-DIPAMP Price
More Price(3)
- Brand: Sigma-Aldrich(India)
- Product number: 697761
- Product name : (R,R)-DIPAMP
- Purity: 95%
- Packaging: 100MG
- Price: ₹8551.75
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 697761
- Product name : (R,R)-DIPAMP
- Purity: 95%
- Packaging: 500MG
- Price: ₹26445.48
- Updated: 2022/06/14
- Buy: Buy
- Brand: TCI Chemicals (India)
- Product number: B3035
- Product name : (R,R)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane
- Purity: min. 97.0 %
- Packaging: 100MG
- Price: ₹5700
- Updated: 2022/05/26
- Buy: Buy
(R,R)-DIPAMP Chemical Properties,Usage,Production
- Uses Rhodium DIPAMP catalysts have shown high activity and enantioselectivity in the asymmetric hydrogenation of enamides, enol acetates and olefins.
- Chemical Properties White crystalline powder
-
Uses
(R, R)-DIPAMP can be used:
- As a catalyst in the enantioselective [3+2] cycloaddition of γ-substituted allenoates with β-perfluoroalkyl enones and 3-butynoates with electron-deficient olefins to yield substituted cyclopentenes.
- To prepare its rhodium metal complexes, which are used as catalysts in asymmetric hydrogenation reactions.
- Uses (R,R)-DIPAMP is a reactant used in the synthesis of Rhodium diphosphine trinuclear complexes.
(R,R)-DIPAMP Preparation Products And Raw materials
Raw materials
Preparation Products
Global(0)Suppliers
55739-58-7, (R,R)-DIPAMPRelated Search:
- [RH(COD)(R,R-DIPAMP)] BF4 (R,R)-o-Tolyl-DIPAMP (S,S)-DIPAMP [RH(COD)(S,S-DIPAMP)] BF4 (R,R)-1-Naphthyl-DIPAMP (S,S)-1-Naphthyl-DIPAMP (S,S)-o-Tolyl-DIPAMP (R,R)-DIPAMP DIBORANE,(S,S)-DIPAMP DIBORANE CATAXA/RH(COD)/(S,S-DIPAMP) (R)-(2-METHOXYPHENYL)METHYLPHENYLPHOSPHINE 1,2-Bis(diphenylphosphino)ethane 1,2-BIS(PHENYLPHOSPHINO)ETHANE 1,2-BIS[(2-METHOXYPHENYL)PHENYLPHOSPHINO]ETHANE (R,R)-DIPAMP
- organophosphine ligand
- Synthetic Organic Chemistry
- Phosphine Ligands
- Asymmetric Synthesis
- Chiral Phosphine
- 高端化学
- 有机配体
- 有机磷
- 膦配体
- 催化剂配体
- 有机砌块
- Privileged Ligands
- Asymmetric Synthesis
- Chiral Catalysts, Ligands, and Reagents
- CH3OC6H4PC6H5CH22
- C28H28O2P2
- C6H4OCH3C6H5PCH2CH2PC6H4OCH3C6H5
- 1,2-双((R)-(2-甲氧基苯基)(苯基)膦基)乙烷
- (R,R)-双[(2-甲氧基苯基)苯基磷]乙烷,97%
- (1R,2R)-二[(2-甲氧基苯基)苯基磷]乙烷,97%
- (R,R)-(-)-1,2-双[(2-甲氧基苯基)(苯基)膦]乙烷 (R,R)-DIPAMP
- (R,R)-1,2-乙二基双[(2-甲氧苯基)苯基膦]
- (1R,2R)-二[(2-甲氧基苯基)苯基膦]乙烷
- (1R,2R)-双[(2-甲氧基苯基)苯基磷]乙烷
- 二[(2-甲氧基苯基)苯基磷]乙烷
- (1R,2R)-二[(2-甲氧基苯基)苯基磷]乙烷
- (R,R)-1,2-双[(2-甲氧基苯基)苯基膦基]乙烷
- (1R,2R)-双[(2-甲氧基苯基)苯基膦基]乙烷
- (R,R)-乙烯二[(2-甲氧基苯基)苯基膦]
- (R,R)-1,2-乙烷二基双[(2-甲氧基苯基)苯基膦]
- (R,R)-(-)-1,2-双[(2-甲氧基苯基)(苯基)膦]乙烷
- (1R,2R)-双[(2-甲氧基苯基)苯基膦]乙烷
- (R,R)-DIPAMP,(R,R)-乙烯二[(2-甲氧基苯基)苯基膦] (R,R)-1,2-乙烷二基双[(2-甲氧基苯基)苯基膦] (R,R)-1,2-双[(2-甲氧基苯基)(苯基膦基)]乙烷 [(1R,2R)-(-)-双[(2-甲氧基苯基)苯基膦]乙烷]
- 55739-58-7
- (<i>R,R</i>)-DIPAMP
- 1,2-bis((R)-(2-methoxyphenyl)(phenyl)phosphanyl)ethane
- (R,R)-DIPAMP,97%
- Phosphine, 1,1'-(1,2-ethanediyl)bis[1-(2-methoxyphenyl)-1-phenyl-, (1R,1'R)-rel-
- (R,R)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane>
- R)-DIPAMP
- (1R,2R)-Bis[(2-methoxypheny)phenylphosphino]ethane
- (R,R)-(-)-1,2-Bis[(2-methoxyphenyl)(phenyl)phosphino]ethane,98% (R,R)-DIPAMP
- 1,2-Bis((R)-(2-Methoxyphenyl)(phenyl)phosphino)ethane
- (R,R)-(-)-1,2-BIS[(2-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE
- (R,R)-DIPAMP
- (R,R)-ETHYLENEBIS[(2-METHOXYPHENYL)PHENYLPHOSPHINE]
- (R,R)-(-)-1,2-Bis[(2-Methoxyphenyl)(phenyl)phosphino]ethane,(R,R)-DIPAMP
- (-)-DIPAMP
- (R,R)-Ethylenebis[(2-methoxyphenyl)phenylphosphine] (R,R)-DIPAMP
- (R,R)-DIPAMP,(R,R)-1,2-Bis[(2-methoxyphenyl)(phenylphosphino)]ethane, (R,R)-1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine], (R,R)-Ethylenebis[(2-methoxyphenyl)phenylphosphine], [(1R,2R)-()-Bis[(
- (R,R)-Dipamp ,0%
- (R,R)-1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine]
- (1R,2R)-Bis[(2-methoxyphenyl)phenylphosphino]ethane,90%
- Ethylenebis[phenyl(2-methoxyphenyl)phosphine]
- Ethylenebis[(2-methoxyphenyl)phenylphosphine]
- Ethylenebis(2-methoxyphenylphenylphosphine)
- (R,R)-Ethylenebis[(2-methoxyphenyl)phenylphosphine], [(1R,2R)-(-)-Bis[(2-methoxyphenyl)phenylphosphino]ethane], (R,R)-1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine], (R,R)-1,2-Bis[(2-methoxyphenyl)(phenylphosphino)]ethane
- (R,R)-Diphenylbis-[(o-anisyl)-methylenephosphine]