ChemicalBook CAS DataBase List 644-97-3

644-97-3

Name	Dichlorophenylphosphine
CAS	644-97-3
EINECS(EC#)	211-425-8
Molecular Formula	C6H5Cl2P
MDL Number	MFCD00000528
Molecular Weight	178.98
MOL File	644-97-3.mol

Synonyms

AURORA KA-1275 BENZENEPHOSPHONOUS DICHLORIDE BENZENEPHOSPHORUS DICHLORIDE BPD DICHLOROPHENYLPHOSPHINE PHENYLDICHLOROPHOSPHINE PHENYLPHOSPHONOUS DICHLORIDE Phenyl phosphorus dichloride PHENYLPHOSPONOUS CHLORIDE P,P DICHLOROPHENYLPHOSPHINE benzenephosphorusdichloride[qr] dichlorophenyl-phosphin Phenylphosphine dichloride phenylphosphinedichloride Phenylphosphonous acid dichloride phenylphosphonousaciddichloride phenyl-phosphonousdichlorid Phosphine, dichlorophenyl- Phenylphosphine dichloride~Phenylphosphonous dichloride Dichlorophenylphosphine,97%

Chemical Properties

Appearance	Colorless to light yellow liqui
Melting point	−51 °C(lit.)
Boiling point	222 °C759 mm Hg(lit.)
density	1.319 g/mL at 25 °C(lit.)
refractive index	n20/D 1.597(lit.)
Fp	>230 °F
storage temp.	Store below +30°C.
form	Liquid
color	Clear colorless to slightly yellow
Specific Gravity	1.319 (20℃)
Water Solubility	Reacts
Sensitive	Moisture Sensitive
BRN	508189
Henry's Law Constant	6.5×10^-1 mol/(m³Pa) at 25℃, Zhang et al. (2010)
Uses	Organic synthesis, for derivation of plasticizers, polymers, antioxidants; oil additives. less more
CAS DataBase Reference	644-97-3(CAS DataBase Reference)
NIST Chemistry Reference	Phosphonous dichloride, phenyl-(644-97-3)
EPA Substance Registry System	644-97-3(EPA Substance)

Safety Data

Symbol(GHS)	GHS05,GHS06
Signal word	Danger
Hazard statements	H301-H314-H335
Precautionary statements	P261-P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes	F,T
Risk Statements	R17:Spontaneously flammable in air. R25:Toxic if swallowed. R34:Causes burns. R29:Contact with water liberates toxic gas. less more
Safety Statements	S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . less more
RIDADR	UN 2845 4.2/PG 1
WGK Germany	3
RTECS	TB2478000
F	10-21
TSCA	Yes
REACH Registrations	Active
HazardClass	8
PackingGroup	II
HS Code	29310095
Safety Profile	A poison irritant to skin, eyes, and mucous membranes and poison by ingestion and inhalation. When heated to decomposition it emits very toxic fumes of Cland POx. See also PHOSPHINE. less more
Hazardous Substances Data	644-97-3(Hazardous Substances Data)

Raw materials And Preparation Products

Hazard Information

General Description

A colorless, fuming liquid. Density 1.32 g/cm3. Flash point 102°C. Corrosive to metals and tissue.

Reactivity Profile

BENZENE PHOSPHORUS DICHLORIDE(644-97-3) is incompatible with water, with bases (including amines), with strong oxidizing agents, and with alcohols. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Air & Water Reactions

Reacts with water, including moisture in air or soil, to liberate heat and hydrochloric acid [Merck, 11th ed. 1989].

Hazard

Highly corrosive to skin, tissue. Flammable.

Health Hazard

Inhalation causes irritation of nose and throat; pulmonary edema may develop following severe exposures. Contact with skin or eyes causes severe burns. Ingestion causes severe burns of mouth and stomach.

Chemical Properties

Colorless to light yellow liqui

Flammability and Explosibility

Nonflammable

Purification Methods

Distil it in a vacuum byfractionating through a 20cm column packed with glass helices (better use a spinning band column) [Buchner & Lockhart J Am Chem Soc 73 755 1951, NMR: Müller et al. J Am Chem Soc 78 3557 1956, IR: Daasch & Smith Anal Chem 23 853 1951]. It forms a yellow Ni complex: Ni(C6H5Cl2P)4 (m 91-92o, from H2O) [Quin J Am Chem Soc 79 3681 1957 ] and a yellow complex with molybdenum carbonyl: Mo(CO)3.(C6H5Cl2P)3 (m 106-110o dec) [Abel et al. J Chem Soc 2323 1959]. [Beilstein 16 IV 972.]

Material Safety Data Sheet(MSDS)

Spectrum Detail

Well-known Reagent Company Product Information

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