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Chlorodiphenylphosphine

Chlorodiphenylphosphine Structure
Chlorodiphenylphosphine
  • CAS No.1079-66-9
  • Chemical Name:Chlorodiphenylphosphine
  • CBNumber:CB6365608
  • Molecular Formula:C12H10ClP
  • Formula Weight:220.63
  • MOL File:1079-66-9.mol
Chlorodiphenylphosphine Property
  • Melting point: :14-16°C
  • Boiling point: :320 °C(lit.)
  • Density  :1.229 g/mL at 25 °C(lit.)
  • vapor density  :7.8 (vs air)
  • vapor pressure  :1.3 hPa (20 °C)
  • refractive index  :n20/D 1.636(lit.)
  • Flash point: :>230 °F
  • storage temp.  :Store below +30°C.
  • solubility  :Miscible with alcohol. Slightly miscible with ammonia.
  • form  :Liquid
  • color  :Colorless to yellow
  • Specific Gravity :1.229
  • Water Solubility  :Reacts violently
  • Sensitive  :Air & Moisture Sensitive
  • Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
  • BRN  :512032
  • InChIKey :XGRJZXREYAXTGV-UHFFFAOYSA-N
  • CAS DataBase Reference :1079-66-9(CAS DataBase Reference)
  • FDA UNII :WO975PJK1Y
  • NIST Chemistry Reference :Chlorodiphenylphosphine(1079-66-9)
  • EPA Substance Registry System :Phosphinous chloride, diphenyl- (1079-66-9)
Safety
  • Hazard Codes  :C
  • Risk Statements  :14-34-29-36
  • Safety Statements  :26-36/37/39-45-8-30-25-27
  • RIDADR  :UN 3265 8/PG 2
  • WGK Germany  :2
  • F  :1-9-19
  • Autoignition Temperature :320 °C
  • TSCA  :Yes
  • HazardClass  :8
  • PackingGroup  :II
  • HS Code  :29310095
  • Toxicity :LD50 orally in Rabbit: 316 mg/kg
  • NFPA 704:
    1
    3 2
    W
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H302-H318-H314
  • Precautionary statements P280-P305+P351+P338-P310-P260-P303+P361+P353-P304+P340+P310-P305+P351+P338+P310-P264-P301+P330+P331+P310-P303+P361+P353+P310+P363-P405-P501-P402
Chlorodiphenylphosphine Price More Price(23)
  • Brand: Sigma-Aldrich
  • Product number: C39601
  • Product name : Chlorodiphenylphosphine
  • Purity: 96%
  • Packaging: 25g
  • Price: $52.7
  • Updated: 2021/03/22
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  • Brand: Sigma-Aldrich
  • Product number: 8.10158
  • Product name : Chlorodiphenylphosphine
  • Purity: for synthesis
  • Packaging: 25 mL
  • Price: $59.85
  • Updated: 2021/03/22
  • Buy: Buy
  • Brand: Sigma-Aldrich
  • Product number: 766054
  • Product name : P-Chlorodiphenylphosphine
  • Purity: 99%
  • Packaging: 25g
  • Price: $71.2
  • Updated: 2021/03/22
  • Buy: Buy
  • Brand: Sigma-Aldrich
  • Product number: 8.10158
  • Product name : Chlorodiphenylphosphine
  • Purity: for synthesis
  • Packaging: 100 mL
  • Price: $143.37
  • Updated: 2021/03/22
  • Buy: Buy
  • Brand: TCI Chemical
  • Product number: C0597
  • Product name : Chlorodiphenylphosphine
  • Purity: >97.0%(T)
  • Packaging: 25g
  • Price: $22
  • Updated: 2021/03/22
  • Buy: Buy

Chlorodiphenylphosphine Chemical Properties,Usage,Production

  • Chemical Properties Colorless to light yellow liqui
  • Synthesis Reference(s) Journal of the American Chemical Society, 77, p. 3526, 1955 DOI: 10.1021/ja01618a030
  • Purification Methods This air-sensitive, pale yellow lachrymatory liquid is purified by careful fractional distillation and discarding the lower boiling fraction which contains the main impurity PhPCl2 (b 48-51o/0.7mm), and checking for impurities by NMR. [Weinberg J Org Chem 40 3586 1975, Honer et al. Chem Ber 94 2122 1961, Beilstein 16 IV 969.]
Chlorodiphenylphosphine Preparation Products And Raw materials
Raw materials
Preparation Products
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  • 1079-66-9
  • 1070-66-9
  • 079-66-9
  • C12H10PCl
  • C6H52PCl
  • C12H10ClP
  • Catalysis and Inorganic Chemistry
  • Phosphorus Precursors
  • Phosphorus Compounds
  • Ligand
  • organophosphine halide