Thifensulfuron methyl

Bezeichnung:Thifensulfuron methyl

CAS-Nr79277-27-3

Englisch Name:Thifensulfuron methyl

CBNumberCB7439269

SummenformelC12H13N5O6S2

Molgewicht387.39

MOL-Datei79277-27-3.mol

Thifensulfuron methyl physikalisch-chemischer Eigenschaften

Schmelzpunkt	176°C
Dichte	1.560±0.06 g/cm3(Predicted)
storage temp.	Sealed in dry,Room Temperature
Wasserlöslichkeit	Practically insoluble in water
Löslichkeit	DMSO (Slightly, Heated), Methanol (Slightly, Heated)
pka	pKa at 25°: 4.0
Farbe	White to Almost white
maximale Wellenlänge (λmax)	280nm(Acidic aq.)(lit.)
Merck	14,9316
BRN	7448062
LogP	1.560
CAS Datenbank	79277-27-3(CAS DataBase Reference)
EPA chemische Informationen	Thifensulfuron-methyl (79277-27-3)

Sicherheit

Kennzeichnung gefährlicher	N
R-Sätze:	50/53
S-Sätze:	60-61
RIDADR	UN3077 9/PG 3
WGK Germany	2
RTECS-Nr.	XM8463000
HazardClass	9
PackingGroup	III
HS Code	29350090
Giftige Stoffe Daten	79277-27-3(Hazardous Substances Data)
Toxizität	LC50 (96-hour) for both bluegill sun?sh and rainbow trout >100 mg/L; LC50 (48-hour) for Daphnia magna >1,000 mg/L (Humburg et al., 1989); acute oral LD50 for rats >5,000 mg/kg (Hartley and Kidd, 1987).

Gefahreninformationscode (GHS)

Thifensulfuron methyl Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
S-Sätze Betriebsanweisung:
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Verwenden
Postemergence herbicide used to control wild garlic and many broad-leaved weeds in barley and spring wheat.
Verwenden
Herbicide.
Definition
ChEBI: A methyl ester resulting from the formal condensation of the carboxy group of thifensulfuron with methanol. It is used as a post-emergence herbicide for the control of grass and broad-leaved weeds.
Landwirtschaftliche Anwendung
Herbicide: A herbicide for postemergence broadleaf weed control in crops for food such as soybeans and cotton. Not listed for use in EU countries.
Handelsname
ALLY®; BASIS® (rimsulfuron + thifensulfuron methyl); CANVAS® (thifensulfuron methyl + tribenuron methyl + metsulfuron-methyl); DPX-M6316®; EXPRESS®; HARMONY® Extra (thifensulfuron methyl + tribenuron methyl); INM-6316®; PINNACLE®; PROSPECT®; RELIANCE® SYNCHRONY®, (chlorimuron- ethyl + thifensulfuron methyl)
Environmental Fate
Chemical/Physical. May hydrolyze in aqueous solutions forming methyl alcohol and 3-(((((4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino)carbonyl)amino)sulfonyl)-2- thiophenecarboxylic acid.
Stoffwechselwegen
The hydrolytic degradation of thifensulfuron methyl is pH dependent and, in alkaline condition, specifically yields the corresponding free acid. Primary degradation cleaves the sulfonylurea moiety to give two typical hydrolyzed products, sulfonamide and aminotriazine analogs, derived from thifensulfuron methyl in acidic and neutral conditions. Hydrolysis of the ester linkage proceeds in mammals, plants, soils, and also chemical hydrolysis, and opening of the triazine ring occurs to yield the acetyltriuret analog identified. On the other hand, by hydrolysis, O- demethylated thifensulfuron methyl undergoes opening of the triazine ring to give the corresponding acetyltriuret analog. Under photolytic conditions, methyl 3-(4-methoxy-6-methyl-1,3,5-triazin-2- yl)aminothiophene-2-carboxylate is identified.

Thifensulfuron methyl Upstream-Materialien And Downstream Produkte

Thifensulfuron methyl Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

79277-27-3, Thifensulfuron methyl Verwandte Suche:

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