p-Menth-1-en-8-ylacetat

Bezeichnung:p-Menth-1-en-8-ylacetat

CAS-Nr80-26-2

Englisch Name:Terpinyl acetate

CBNumberCB2161886

SummenformelC12H20O2

Molgewicht196.29

MOL-Datei80-26-2.mol

Synonyma

p-Menth-1-en-8-ylacetat

p-Menth-1-en-8-ylacetat physikalisch-chemischer Eigenschaften

Schmelzpunkt	112-113.5 °C
Siedepunkt	220 °C (lit.)
Dichte	0.953 g/mL at 25 °C (lit.)
Dampfdruck	3.515Pa at 23℃
FEMA	3047 \| TERPINYL ACETATE (ISOMER MIXTURE)
Brechungsindex	n20/D 1.465(lit.)
Flammpunkt	>230 °F
storage temp.	Store at -20°C
Löslichkeit	DMSO : 100 mg/mL (509.45 mM; Need ultrasonic)
Aggregatzustand	clear liquid
Farbe	Colorless to Almost colorless
Geruch (Odor)	at 100.00 %. herbal bergamot lavender lime citrus
Geruchsart	herbal
Wasserlöslichkeit	23mg/L at 23℃
JECFA Number	368
BRN	3198769
LogP	4.4 at 30℃
CAS Datenbank	80-26-2(CAS DataBase Reference)
NIST chemische Informationen	3-Cyclohexene-1-methanol, «alpha»,«alpha»,4-trimethyl-, acetate(80-26-2)
EPA chemische Informationen	.alpha.-Terpinyl acetate (80-26-2)

Sicherheit

Kennzeichnung gefährlicher	Xi
R-Sätze:	36/38
S-Sätze:	26-36
WGK Germany	2
RTECS-Nr.	OT0200000
TSCA	Yes
HS Code	29153900
Toxizität	The acute oral LD₅₀ value in rats was reported as 5.075 g/kg (Jenner, Hagan, Taylor, Cook & Fitzhugh, 1964).

Gefahreninformationscode (GHS)

Terpinyl acetate Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R36/38:Reizt die Augen und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
The enantiomers and the racemate occur in many essential oils (e.g., Siberian pine-needle oil and cypress oil), but generally not as the main component. Pure Terpinyl acetate are colorless liquids with a fresh bergamot–lavender odor. Commercially available terpinyl acetate consists mainly of alpha-terpinyl acetate, but also contains a number of other isomeric compounds such as beta-terpinyl acetate. It can be prepared by acetylating the terpineol mixture obtained from terpin hydrate, using a customary procedure for tertiary alcohols.
Because of its odor properties, stability, and low price, large quantities of terpinyl acetate are used in perfumery for lavender and bergamot types, as well as in essential oil reconstitutions.
Physikalische Eigenschaften
Terpinyl acetate is a p-menthane monoterpenoid that naturally found in melanoleuca, elettaria cardamomum. It is a colorless liquid with a bergamot, bergamot odor. Soluble in five or more volumes of 70% alcohol; slightly soluble in water and glycerol. Combustible.
Occurrence
Reported in over 40 essential oils, including cypress, Malabar cardamom, cajeput niaouli, Siberian pine needles, pine, Melaleuca trichostachya, Melaleuca pauciflora and others; also identified in the essential oils of bitter orange (Fenarolfs Handbook of Flavor Ingredients, 1971 ; Gildemeister & Hoffman, 1966). Terpinyl Acetate is found in Pine oil, Cajeput oil, Pine needle oil, Cardamom oil and other essential oils.
Verwenden
Perfumes, flavoring agent.
synthetische
Terpinyl acetate was successfully synthesized from (x-terpineol and acetic anhydride in supercritical carbon dioxide (SC-C02) by enzymatic catalysis.
By acetylation of a-terpineol or mixed isomeric terpineols (Bedoukian, 1967).
Definition
ChEBI: Alpha-Terpinyl acetate is a p-menthane monoterpenoid.
Synthesis Reference(s)
Tetrahedron, 38, p. 1843, 1982 DOI: 10.1016/0040-4020(82)80261-5
Allgemeine Beschreibung
Α-Terpinyl acetate, a monoterpene ester, is a commercially important fragrance molecule. It can be prepared from α-pinene in the presence of H-beta zeolite catalysts. The essential oils obtained from Stachys setifera ssp. iranica, Chamaecyparis obtuse leaves and Thymus willkomii contain Α-terpinyl acetate as one of the main components.
Flammability and Explosibility
Non flammable
Sicherheitsprofil
Mildly toxic by ingestion. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.

Terpinyl acetate Upstream-Materialien And Downstream Produkte

p-Menth-1-en-8-ylacetat Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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