Mancozeb

Gefahreninformationscode (GHS)

• Bildanzeige (GHS)

  

• Alarmwort

  Achtung

• Gefahrenhinweise

  H317：Kann allergische Hautreaktionen verursachen.

  H351：Kann vermutlich Krebs verursachen.

  H373：Kann die Organe schädigen bei längerer oder wiederholter Exposition.

  H410：Sehr giftig für Wasserorganismen mit langfristiger Wirkung.

• Sicherheit

  P201：Vor Gebrauch besondere Anweisungen einholen.

  P202：Vor Gebrauch alle Sicherheitshinweise lesen und verstehen.

  P260：Dampf/Aerosol/Nebel nicht einatmen.

  P261：Einatmen von Staub vermeiden.

  P272：Kontaminierte Arbeitskleidung nicht außerhalb des Arbeitsplatzes tragen.

  P273：Freisetzung in die Umwelt vermeiden.

  P280：Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.

  P281：Vorgeschriebene persönliche Schutzausrüstung verwenden.

  P302+P352：BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.

  P308+P313：BEI Exposition oder falls betroffen: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.

  P314：Bei Unwohlsein ärztlichen Rat einholen / ärztliche Hilfe hinzuziehen.

  P321：Besondere Behandlung

  P333+P313：Bei Hautreizung oder -ausschlag: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.

  P363：Kontaminierte Kleidung vor erneutem Tragen waschen.

  P391：Verschüttete Mengen aufnehmen.

  P405：Unter Verschluss aufbewahren.

  P501：Inhalt/Behälter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen.

Mancozeb Chemische Eigenschaften,Einsatz,Produktion Methoden

• ERSCHEINUNGSBILD

  GRäULICH- GELBES PULVER.

• PHYSIKALISCHE GEFAHREN

  Staubexplosion der pulverisierten oder granulierten Substanz in Gemischen mit Luft möglich.

• CHEMISCHE GEFAHREN

  Langsame Zersetzung beim Erhitzen oder bei Kontakt mit Säuren und Feuchtigkeit unter Bildung giftiger und reizender Rauche mit Schwefeloxiden, Stickstoffoxiden, Zinkoxid, Manganoxid, Schwefelwasserstoff, Schwefelkohlenstoff, Ethylenthiuramsulfid, Ethylenbisisothiocyanat, Ethylenharnstoff und 2-Mercaptoimidazolin.

• ARBEITSPLATZGRENZWERTE

  TLV nicht festgelegt (ACGIH 2005).
  MAK nicht festgelegt (DFG 2005).
  

• AUFNAHMEWEGE

  Aufnahme in den Körper durch Inhalation des Aerosols und durch Verschlucken.

• INHALATIONSGEFAHREN

  Verdampfung bei 20°C vernachlässigbar; eine gesundheitsschädliche Partikelkonzentration in der Luft kann jedoch beim Dispergieren schnell erreicht werden.

• WIRKUNGEN BEI KURZZEITEXPOSITION

  WIRKUNGEN BEI KURZZEITEXPOSITION:
  Die Substanz reizt die Augen und die Atemwege, und reizt leicht die Haut.

• WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION

  Wiederholter oder andauernder Kontakt kann zu Hautsensibilisierung führen.(S. Anm.)

• LECKAGE

  NICHT in die Kanalisation spülen. Verschüttetes Material in abdichtbaren Behältern sammeln. Reste sorgfältig sammeln. An sicheren Ort bringen. Persönliche Schutzausrüstung: Atemschutzgerät, P2-Filter für schädliche Partikel.

• R-Sätze Betriebsanweisung:

  R37:Reizt die Atmungsorgane.
  R43:Sensibilisierung durch Hautkontakt möglich.

• S-Sätze Betriebsanweisung:

  S8:Behälter trocken halten.
  S24/25:Berührung mit den Augen und der Haut vermeiden.
  S46:Bei Verschlucken sofort ärztlichen Rat einholen und Verpackung oder Etikett vorzeigen.

• Beschreibung

  Mancozeb is a fungicide of the ethylene-bis-dit-hiocarbamate group. It is present in Rondo-M with pyrifenox. Occupational exposure occurs mainly in agricultural workers, in vineyard workers or in florists.

• Chemische Eigenschaften

  Grayish-yellow powder

• Verwenden

  Fungicide.

• Verwenden

  Mancozeb is a mixture of Maneb (M163500) and Zineb, a manganese and zinc (1:1) complex mixture with the ethylene bis(dithiocarbamate) anionic ligand. Mancozeb is a foliate fungicide used to protect cr ops in agriculture. Mancozeb has a broader and more effective fungacidal activity than either of its component on their own. Mancozeb also significantly enhances the copper activity against several ba cteriosis.

• Verwenden

  Fungicide used as a foliar or seed treatment to control a wide variety of pathogens in many field crops, fruits, ornamentals and vegetables.

• Verwenden

  Mancozeb is a contact fungicide that provides protection against a wide variety of fungal diseases (including rots, leaf spot, blight, rust, downy mildew, scab, etc.) in field crops, fruits, vines, vegetables, ornamentals, potatoes, turf, berries, rice, citrus and cereals. Mancozeb is a mixture containing zineb and maneb as active ingredients.

• Landwirtschaftliche Anwendung

  Fungicide: Mancozeb is used to control a wide variety of fungal diseases, including potato blight, leaf spot, scab (on apples and pears), and rust (on roses). It is used on fruits, vegetables, nuts and field crops, and many more. It is also used as a seed treatment of cotton, potatoes, corn, safflower, sorghum, peanuts, tomatoes, flax, and cereal grains.

• Handelsname

  ACROBAT® (mancozeb + dimethomorph); ASHLAND SOLACE® (cymoxanil + mancozeb); CARMAZINE®; CUPROFIX®; DITHANE®; EMCARB® (mancozeb + carbendez); EMTHANE M-15®; EVOLVE®; F 2966®; FORE®; FORMEC®; GAUCHO® (imidacloprid + mancozeb); GAVEL® (mancozeb + zoxamide); GREEN-DAISEN M®; KARAMATE®; KENCOZEB®; MANCOFOL®; MANOSEB®; MANTOX®; MANZATE 200®; MANZEB®; MANZIN 80®; MARZIN®; MAXIM®; MILOR®; NEMISPOR®; PACE® fungicide (mixture of mancozeb and metalaxyl); PENNCOZEB®; POLICAR®; TRIZIMAN®; TRIZIMAN-D®; VONDOZEB PLUS®; ZIMANAT®; ZIMMAN-DITHANE®; ZIMANEB®

• Kontakt-Allergie

  Mancozeb is a fungicide of the ethylene-bis-dithiocarbamate group. It is present in Rondo-M? with pyrifenox.Occupational exposure occurs mainly in agriculturalworkers, in vineyard workers, or in florists.

• mögliche Exposition

  Mancozeb is a dithiocarbamate fungicide. It is used to control a wide variety of fungal diseases, including potato blight, leaf spot, scab (on apples and pears), and rust (on roses). It is used on fruits, vegetables, nuts and field crops, and many more. It is also used as a seed treatment of cotton, potatoes, corn, safflower, sorghum, peanuts, tomatoes, flax, and cereal grains

• Environmental Fate

  Plant. Undergoes metabolism in plants to ethyl thiourea, ethylene thiuram disulfide, thiuram monosulfide and sulfur (Hartley and Kidd, 1987).
  Chemical/Physical. Decomposes in acids releasing carbon disulfide. In oxygenated waters, mancozeb degraded to ethylene thiuram monosulfide, ethylene diisocyanate, ethylene thiourea, ethylenediamine and sulfur (Worthing and Hance, 1991).

• Stoffwechselwegen

  Mancozeb is a mixture containing maneb and zineb as the active ingredients. Maneb and zineb and other alkylenebis( dithiocarbamate) fungicides are degraded and metabolised via a common pathway. The primary degradation reaction of maneb and zineb in water, soil, plants and animals involves the initial dissociation of the metal complex and decomposition to numerous degradation products including ethylenethiourea (ETU) and ethyleneurea (EU) as major products. See zineb and maneb summaries for detailed descriptions.

• Versand/Shipping

  UN2771 Dithiocarbamate and Thiocarbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1- Poisonous materials.

• Degradation

  Mancozeb (1) was readily hydrolysed in neutral and alkaline solution with DT9 values of 20 days (pH 5), 17 hours (pH 7) and 34 hours (pH 9) (PM). See zineb and maneb summaries for the hydrolytic degradation pathway.

• Toxicity evaluation

  The mechanism of toxicity for MZ is similar to other EBDC fungicides like maneb. EBDC are able to modify and inactivate redox-sensitive proteins. Because of the thiol reactivity of these compounds, redox-sensitive processes like transcription, translation, and other metabolic processes can be altered, resulting in cytotoxicity. It is due to this multitarget mode of action that MZ and other EBDC compounds are used in fungicide resistance management programs. In contrast to other fungicidal agents, in over 40 years of use, resistance to any of the EBDC compounds has never developed. MZ has also been reported to cause oxidative stress, DNA damage, and apoptosis in rat cells. Additionally, like all EBDC, MZ can act as a chelating agent, allowing it to interfere with enzymes that contain metals which are essential for activity, like dopamine b-hydroxylase.

• Inkompatibilitäten

  Combustible material. Dust may form explosive mixture in air. Decomposes in temperatures above 170C. Keep away from water, acid, oxidizing materials. Dithiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of Dithiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of dithiocarbamate with aldehydes, nitrides, and hydrides. Dithiocarbamate are incompatible with acids, peroxides, and acid halides. Corrosive to iron, copper brass, and zinc metals, especially in the presence of moisture. Contact with lime, moisture can cause decomposition. Decomposes on prolonged storage. Degradation produces ethylene thiourea.

• Waste disposal

  Disposal Method Suggested: Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number N450, must conform to USEPA regulations for storage, transportation, treatment, and disposal of waste. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Dispose of contents and container to an approved waste disposal plant. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. All federal, state, and local environmental regulations must be observed. Do not discharge into drains or sewers. A potential candidate for liquid injection incineration at a temperature range of 650 to 1600C and a residence time 0.1 to 2 seconds. Also, a potential candidate for rotary kiln incineration at a temperature range of 820 to 1600C and residence times of seconds for liquids and gases, and hours for solids.

Mancozeb Upstream-Materialien And Downstream Produkte

Mancozeb Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global(269)Suppliers

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