Chemical Properties
white powder
Uses
2-Imidazolidinethione(96-45-7) is a pesticide used in production of fruits and vegetables. It is also used as a new contrast agent for MRI studies based on proton chemical exchange dependent saturation transfe
r. 2-Imidazolidinethione is also a corrosion inhibitor due to the adsorption of the mol. species.
Uses
elastomer accelerator;chlorinated polyethylene (CPE) rubber vulcanizing accelerator agent
Uses
Accelerator in synthetic rubber production.
General Description
White to pale green crystals or an off-white solid. Odorless when pure, but technical product may have an amine odor.
Reactivity Profile
ETHYLENE THIOUREA(96-45-7) may be sensitive to prolonged exposure to light. Incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. May react with acids to liberate hydrogen sulfide.
Air & Water Reactions
Slightly soluble in water.
Hazard
Questionable carcinogen.
Potential Exposure
Ethylene thiourea(96-45-7) is used extensively
as an accelerator in the curing of polychloroprene
(Neoprene) and other elastomers; as a vulcanizing accelerator in rubber processing; in electroplating baths. In addition, exposure to ethylene thiourea also results from the
very widely used ethylene bisdithiocarbamate fungicides.
Ethylene thiourea may be present as a contaminant in the
ethylene bisdithiocarbamate fungicides and can also be
formed when food containing the fungicides is cooked
Fire Hazard
This chemical is combustible.
First aid
Move victim to fresh air. Call 911 or emergency
medical service. Give artificial respiration if victim is not
breathing. Do not use mouth-to-mouth method if victim
ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device.
Administer oxygen if breathing is difficult. Remove and
isolate contaminated clothing and shoes. In case of contact
with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact,
avoid spreading material on unaffected skin. Keep victim
warm and quiet. Effects of exposure (inhalation, ingestion
or skin contact) to substance may be delayed. Ensure that
medical personnel are aware of the material(s) involved
and take precautions to protect themselves. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed.
As first aid for pulmonary edema, a doctor or authorized
paramedic may consider administering a drug or other
inhalation therapy
Shipping
UN2811 Toxic solids, organic, n.o.s., Hazard
Class: 6.1; Labels: 6.1-Poisonous materials, Technical
Name Required
Incompatibilities
Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases,
strong acids, oxoacids, epoxides, acid anhydrides, and
acrolein
Description
Ethylenethiourea, a thiourea derivative, is a rubber
chemical. It has caused contact dermatitis mainly in
rubber workers.
Waste Disposal
Incineration in a furnace
equipped with afterburner and scrubber.
Definition
ChEBI: Ethylenethiourea is a member of imidazolidines.
Health Hazard
Ethylene thiourea (ETU) is an
antithyroid substance and animal carcinogen.
Flammability and Explosibility
Nonflammable
Carcinogenicity
Ethylene thiourea is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.
storage
Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, well-ventilated area away from strong oxidizers, acids, acidanhydrides, acrolein. Store in a refrigerator or a cool, dryplace. A regulated, marked area should be establishedwhere this chemical is handled, used, or stored in compliance with OSHA Standard 1910.1045.
Purification Methods
Crystallise it from EtOH or amyl alcohol. [Beilstein 24 III/IV 22.]