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74-85-1

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Identification

Name
ETHYLENE
CAS
74-85-1
Synonyms
ETHYLENE
Acetene
Athylen
bicarburettedhydrogen
Bicarburretted hydrogen
bicarburrettedhydrogen
C2H4
Elayl
Ethen
Ethylen
ethylene,refrigeratedliquid(cryogenicliquid)
etileno
Liquid ethyene
liquidethyene
liquidethylene
Olefiant gas
olefiantgas
R1150
R-1150
ETHYLENE, 99.5+%
EINECS(EC#)
200-815-3
Molecular Formula
C2H4
MDL Number
MFCD00008604
Molecular Weight
28.05
MOL File
74-85-1.mol

Chemical Properties

Appearance
colourless gas
Appearance
Ethylene, an alkene is a colorless gas (at room temperature). Sweet odor. Minimum detectable odor 5 260 ppm.
Melting point 
−169 °C(lit.)

mp 
−169 °C(lit.)

Boiling point 
−104 °C(lit.)

bp 
−104 °C(lit.)

density 
0.00126
vapor density 
0.97 (vs air)

vapor pressure 
35.04 atm ( 20 °C)

refractive index 
1.363
Fp 
-100 °C
form 
Colorless gas
Stability:
Stable. Highly flammable-note wide explosion limits. Incompatible with strong oxidizing agents. Readily forms explosive mixtures with air.
explosive limit
36%
Water Solubility 
90.91g/L(25 ºC)
FreezingPoint 
-169.4℃
Merck 
13,3825
BRN 
1730731
CAS DataBase Reference
74-85-1(CAS DataBase Reference)
IARC
3 (Vol. Sup 7, 60) 1994
NIST Chemistry Reference
Ethylene(74-85-1)
EPA Substance Registry System
74-85-1(EPA Substance)

Questions And Answer

Uses
Chemical intermediate in the manufacture of polyethylene, ethylene oxide, ethylene dichloride, and ethyl benzene; used as a fruit and vegetable ripening agent
Uses
Ethylene finds use in the manufacture of ethyl benzene, ethanol, ethylene oxide, ethylene glycol, and ethylene dichloride. About half of the ethylene produced in the United States is used for the production of high- and low-density polyethylene plastics. Other chemical raw materials made with ethylene include ethyl chloride, dichloroethane, vinyl chloride, ethyl ether, methyl acrylate, and styrene.
Ethylene is also used as a refrigerant and a fuel for metal cutting and welding, and it has been used for anesthesia. It is also used to accelerate plant growth and fruit ripening.

Safety Data

Hazard Codes 
F+,F
Risk Statements 
R12:Extremely Flammable.
R67:Vapors may cause drowsiness and dizziness.
Safety Statements 
S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking .
S33:Take precautionary measures against static discharges .
S46:If swallowed, seek medical advice immediately and show this container or label .
RIDADR 
UN 1962 2.1

WGK Germany 
-

RTECS 
KU5340000


4.5-31
Autoignition Temperature
842 °F
DOT Classification
2.1 (Flammable gas)
HazardClass 
2.1
HS Code 
29012100
Safety Profile
Suspected carcinogen. A simple asphyxiant. High concentrations cause anesthesia. A common air contaminant. It is phytotoxic. A very dangerous fire hazard when exposed to heat or flame. Moderate explosion hazard when exposed to flame. A flammable gas. To figh fire, stop flow of gas, use Co2, dry chemical, or fine water spray. Mixtures with aluminum chloride explode in the presence of nickel catalysts, methyl chloride, or nitromethane. Explosive reaction with bromotrichloromethane (at 120℃/51 bar), carbon tetrachloride (25-100°C/30 bar). Explosive reaction with chlorine catalyzed by sunlight or UV light or in the presence of mercury(I) oxide, mercury(Ⅱ) oxide, or silver oxide. Mixtures with chlorotrifluoroethylene polymerize explosively when exposed to 50 kV gamma rays at 308 krad/hr. Has been involved in industrial accidents. Violent polymerization is catalyzed by copper above 4OO0C/54 bar. Incompatible with AlCl3, (CC4 + benzoyl peroxide), (bromotrichloromethane + NCh), 03, CCl4, Cl2, NOx, tetrafluoroethylene trifluorohypofluorite. When heated to decomposition it emits acrid smoke and irritating fumes
Hazardous Substances Data
74-85-1(Hazardous Substances Data)
Toxicity
LC for mice in air: 950,000 ppm (Flury)

Raw materials And Preparation Products

Hazard Information

General Description
A colorless gas with a sweet odor and taste. ETHYLENE(74-85-1) is lighter than air. ETHYLENE(74-85-1) is easily ignited and a flame can easily flash back to the source of the leak. Under prolonged exposure to fire or heat the containers may rupture violently and rocket. Can cause explosion.
Reactivity Profile
Peroxidizable monomer may initiate exothermic polymerization of the bulk material [Bretherick 1979. p. 160]. Ethylene in the presence of aluminum chloride may undergo a violent reaction [J. Inst. Pet. 33:254. 1947]. Ozone and ethylene react explosively [Berichte 38:3837]. Ethylene can polymerize at low pressure if catalyzed by titanium halides. (Sundaram, K. M, M. M. Shreehan, E. F. Olszewski. thylene. Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc. 2001.)
Air & Water Reactions
Highly flammable.
Hazard
Highly flammable, dangerous fire and explosion risk; explosive limits in air 3–36% by volume. Simple asphyxiant; questionable carcinogen.
Health Hazard
Moderate concentration in air causes drowsiness, dizziness, and unconsciousness. Overexposure causes headache, drowsiness, muscular weakness.
Potential Exposure
Ethylene is used in production of fabricated plastics, antifreeze; making fibers; to manufacture ethylene oxide, polyethylene for plastics, alcohol, mustard gas and other organics. It is used to accelerate ripening of fruit; as an anesthetic; and for oxyethylene welding and cutting of metals
First aid
If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. If frostbite has occurred, seek medical attention immediately; do NOT rub the affected areas or flush them with water. In order to prevent further tissue damage, do NOT attempt to remove frozen clothing from frostbitten areas. If frostbite has NOT occurred, immediately and thoroughly wash contaminated skin with soap and water.
Shipping
UN1962 Ethylene, Hazard Class: 2.1; Labels: 2.1-Flammable gas; UN1038 Ethylene, refrigerated liquid (cryogenic liquid), Hazard Class: 2.1; Labels: 2.1- Flammable gas. Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner.
Incompatibilities
A highly flammable gas at room temperature. Contact with oxidizers may cause explosive polymerization and fire. May be spontaneously explosive in sunlight or ultraviolet light when mixed with chlorine. Reacts violently with mixtures of carbon tetrachloride and benzoyl peroxide; bromotrichloromethane; aluminum chloride and ozone. Incompatible with acids, halogens, nitrogen oxides; hydrogen bromide; aluminum chloride; chlorine dioxide; nitrogen dioxide. May accumulate static electrical charges, and may cause ignition of its vapors.
Description
Ethylene is a colorless, odorless gas that is the simplest alkene hydrocarbon. It is a natural plant hormone and is produced synthetically from natural gas and petroleum. The double bond in ethylene makes this compound highly reactive, and the volume of ethylene used in the chemical industry is greater than any other organic compound.
Chemical Properties
colourless gas
Chemical Properties
Ethylene, an alkene is a colorless gas (at room temperature). Sweet odor. Minimum detectable odor 5 260 ppm.
Waste Disposal
Return refillable compressed gas cylinders to supplier
Definition
ethylene: A colourlessflammable gaseous hydrocarbon,C2H4; m.p. –169°C; b.p. –103.7°C. It isthe first member of the alkene seriesof hydrocarbons. It is made bycracking hydrocarbons from petroleumand is now a major raw materialfor making other organicchemicals (e.g. ethanal, ethanol,ethane-1,2-diol). It can be polymerizedto polyethene. It occurs naturallyin plants, in which it acts as agrowth substance promoting theripening of fruits.
Production Methods
Ethylene is primarily obtained from the ethane and propane components of natural gas andfrom the naphtha, kerosene, and gas oil components of crude oil. It can also be synthesizedthrough the dehydration of ethanol (C2H5OH). The production of ethylene from hydrocarbonfeedstocks involves mixing with steam and then subjecting the hydrocarbons to thermalor catalytic cracking. Cracking is a process in which organic molecules are broken down intosmaller molecules. Thermal cracking involves the use of heat and pressure. Catalytic crackinguses various catalysts to reduce the amount of heat and pressure required in the process.Th ermal cracking of hydrocarbons to ethylene occurs between approximately 650°C and800°C (1200°F and 1500°F). After hydrocarbons are cracked, a mixture containing ethyleneand other gases such as methane, ethane, and propane is obtained. Ethylene is separated fromthese through physical processes such as fractional distillation, refrigeration, absorption, oradsorption.
Reactions
Ethylene reacts: (1) with the halogens to form substitution halides; (2) with hypochlorous and hypobromous acid to form ethylene chlorohydrin or ethylene bromohydrin, respectively; (3) with hydrogen iodide or bromide (not chloride) to form ethyl iodide or ethyl bromide; (4) with hydrogen, in the presence of a catalyst, e.g., finely divided nickel at 150 °C, to form ethane; (5) with concentrated sulfuric acid at 160 °C to form ethyl hydrogen sulfate; and (6) with potassium permanganate to form ethylene glycol, although glycol is preferably made from ethylene dichloride or chlorohydrin.
Fire Hazard
Flammable gas; burns with a luminous flame; autoignition temperature 490°C (914°F) (NFPA 1997), 543°C (1009°F) (Merck 1996); fire-extinguishing measure: shut off the flow of gas; use a water spray to keep fire-exposed containers cool.
Ethylene forms explosive mixtures in air; the LEL and UEL values are 2.7% and 36% by volume of air, respectively. Its reaction with fluorine is explosively violent (△H=- 112 kcal/mol), and violent with chlorine (△H=- 36 kcal/mol). In the presence of sunlight or UV light, an ethylene– chlorine mixture will explode spontaneously. The reaction is explosive at room temperature over the oxides of mercury or silver (Mellor 1946, Suppl. 1956). Ethylene reacts vigorously with oxidizing substances. It reacts with ozone to form ethylene ozonide, H2C(O3)CH2, which is unstable and explodes on mechanical shock. Acidcatalyzed addition of hydrogen peroxide may produce ethyl hydroperoxide, which is unstable and explodes on heat or shock:.
Industrial uses
Ethylene, also called ethane, is a colorless,inflammable gas, CH2:CH2, produced in thecracking of petroleum. Ethylene liquefies at–68.2°C. Ethylene is the largest-volume organicchemical produced today, and is the basic buildingblock of the petrochemical industry. Polymerizationof ethylene is its largest use. Whenethylene is reacted in the presence of transitionmetal catalysts, such as Mo2O5 or Cr2O3, at highpressures, it forms low-density polyethylene(LDPE); at lower pressures, high-density polyethylene(HDPE) is produced. Recently, lowpressures have been employed for making a newvariant, linear low-density polyethylene(LLDPE). Ethylene is now used to produce ethylalcohol, acrylic acid, and styrene, and it is thebasis for many types of reactive chemicals.
Trichloroethylene is a colorless liquid ofpleasant odor of the composition CHCl:CCl2,also known as westrosol. Its boiling point is87°C and its specific gravity 1.471. It is insolublein water and is unattacked by dilute acidsand alkalis. It is non flammable and is less toxicthan tetrachlorethane. Trichloroethylene is apowerful solvent for fats, waxes, resins, rubber,and other organic substances, and is employedfor the extraction of oils and fats, for cleaningfabrics, and for degreasing metals preparatoryto plating. The freezing point is –88°C, and itis also used as a refrigerant. It is also used insoaps employed in the textile industry fordegreasing.
Materials Uses
Installations must be designed to withstand the pressures involved and must comply with all applicable regulations. Because it is noncorrosive, any common commercially available metals may be used with ethylene.
Physiological effects
When used for anesthesia, ethylene is a nontoxic gas found pleasant and nonirritating by patients. Prolonged inhalation of substantial concentrations results in unconsciousness; light and moderate anesthesia is attained, and deep anesthesia seldom occurs.
Inhalation is fatal only if the gas acts as a simple asphyxiant, depriving the body of necessary oxygen. Because of its flammability, however, other agents have replaced ethylene for use in anesthesia in the United States and Canada.
No deleterious action by ethylene on circulatory, respiratory, or other systems or organs has been observed. Exhalation eliminates the major portion of ethylene within minutes, although complete desaturation from body fat takes several hours. Minute traces can be detected in the blood a number of hours after anesthesia has ended.
Carcinogenicity
A case-control study of brain cancer among Texas petrochemical workers reported increased risks associated with exposure to multiple chemicals, including ethene. The findings were not statistically significant. The risks for ethene have not been shown to increase with increasing duration of employment. The observed increases could not be attributed to specific chemical exposures.
Environmental Fate
Emitted ethene is distributed primarily into the atmosphere and reacts with photochemically reactive hydroxyl radicals, ozone, and nitrate radicals, with half-lives ranging from 1.9, 6.5, and 190 days, respectively. Biodegradation in water occurs with half-lives in the range of 1–28 days, or under anaerobic conditions, 3–112 days. Bioaccumulation in aquatic organisms is not expected to occur, based on ethene’s high vapor pressure and log octanol/water partition coefficient.
storage
Ethylene is stored in a cool, well-ventilatedarea isolated from oxygen, chlorine, andflammable and oxidizing substances. It isprotected against lightning, statical electricity,heat, and physical damage. It is shippedin steel pressure cylinders and tank barges.
Purification Methods
Purify ethylene by passage through a series of towers containing molecular sieves or anhydrous CaSO4 or a cuprous ammonia solution, then conc H2SO4, followed by KOH pellets. Alternatively, it has been condensed in liquid nitrogen, with melting, freezing and pumping to remove air before passage through an activated charcoal trap, followed by a further condensation in liquid air. A sputtered sodium trap was used to remove oxygen. [Beilstein 1 IV 677.]
Toxicity evaluation
Ethene is classified as a simple asphyxiant. In sufficient concentrations, ethene causes central nervous system depression and unconsciousness by displacing oxygen in air, which reduces the oxygen available to support cell function.
GRADES AVAILABLE
Ethylene is typically available for commercial and industrial purposes in a c.P. grade (minimum purity of 99.5 mole percent), and a technical grade (minimum purity of 98.1 mole percent).

Material Safety Data Sheet(MSDS)

msds information
ethylene(74-85-1).msds

Spectrum Detail

Spectrum Detail
ETHYLENE(74-85-1)ESR

Well-known Reagent Company Product Information

Sigma Aldrich
74-85-1(sigmaaldrich)
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