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56-35-9

Name Bis(tributyltin) oxide
CAS 56-35-9
EINECS(EC#) 200-268-0
Molecular Formula C24H54OSn2
MDL Number MFCD00009418
Molecular Weight 596.1
MOL File 56-35-9.mol

Chemical Properties

Description
TBTO (bis(tri-n-butyltin)oxide) appears as thin, colourless to pale yellow, flammable and combustible liquid. It is soluble in organic solvents. TBTO, or bis(tri-n-butyltin)oxide, is an organotin compound used as a biocide, fungicide, and molluscicide. Uses of tributyltin also include as an anti-fouling chemical in marine paints for boats, anti-fungal agent in textiles and industrial water systems, in cooling tower and refrigeration water systems, wood pulp preservative in paints and paper mill systems, inner surfaces of cardboard, and in the manufacturing processes of leather goods, textiles, wood, plastics, and mothproof stored garments. In fact, TBT compounds are considered the most hazardous of all tin compounds.
Appearance Clear colorless liquid
Melting point  -45°C
Boiling point  180 °C2 mm Hg(lit.)
density  1.17 g/mL at 25 °C(lit.)
vapor pressure  <0.01 mm Hg ( 25 °C)
refractive index  n20/D 1.486(lit.)
Fp  >230 °F
storage temp.  +4°C
solubility  Chloroform (Soluble), Methanol (Slightly)
form  liquid
color  colorless
Specific Gravity 1.170
Water Solubility  INSOLUBLE
Hydrolytic Sensitivity 5: forms reversible hydrate
Sensitive  Air & Moisture Sensitive
BRN  745057
Exposure limits ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
Stability: Moisture Sensitive
Contact allergens
Tributyl tin oxide is used as an antifouling and biocide agent against fungi, algae, and bacteria, particularly in paints. Sometimes used in chemistry, tributyltin oxide is a strong irritant.
InChIKey APQHKWPGGHMYKJ-UHFFFAOYSA-N
LogP 3.840 (est)
CAS DataBase Reference 56-35-9(CAS DataBase Reference)
NIST Chemistry Reference Distannoxane, hexabutyl-(56-35-9)
EPA Substance Registry System 56-35-9(EPA Substance)

Safety Data

Hazard Codes  T,N
Risk Statements 
R21:Harmful in contact with skin.
R25:Toxic if swallowed.
R36/38:Irritating to eyes and skin .
R48/23/25:Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
Safety Statements 
S35:This material and its container must be disposed of in a safe way .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
RIDADR  UN 2788 6.1/PG 2
WGK Germany  3
RTECS  JN8750000
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29310095
Hazardous Substances Data 56-35-9(Hazardous Substances Data)
Toxicity
LD50 oral in rat: 87mg/kg

Hazard Information

Material Safety Data Sheet(MSDS)

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