13139-86-1
| Name | 4-Methoxyphenylmagnesium bromide |
| CAS | 13139-86-1 |
| Molecular Formula | C7H7BrMgO |
| MDL Number | MFCD00013515 |
| Molecular Weight | 211.34 |
| MOL File | 13139-86-1.mol |
Chemical Properties
| Appearance | Clear to brown solution when properly stored |
| Boiling point | 65-67 °C |
| density | 0.955 g/mL at 25 °C |
| Fp | −4 °F |
| storage temp. | Flammables + water-Freezer (-20°C)e area |
| form | Liquid |
| color | Yellow to brown |
| Water Solubility | Severe reaction |
| Sensitive | Air & Moisture Sensitive |
| Exposure limits | ACGIH: TWA 50 ppm; STEL 100 ppm (Skin) OSHA: TWA 200 ppm(590 mg/m3) NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) |
| InChI | 1S/C7H7O.BrH.Mg/c1-8-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1 |
| InChIKey | JKXAZEXIOPFJSC-UHFFFAOYSA-M |
| SMILES | COc1ccc([Mg]Br)cc1 |
Safety Data
| Symbol(GHS) |     GHS02,GHS05,GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H225-H302-H314-H335-H351-H318-H333 |
| Precautionary statements | P260h-P303+P361+P353-P405-P501a-P210-P260-P280-P305+P351+P338-P370+P378-P403+P235 |
| Hazard Codes | F,C |
| Risk Statements | |
| Safety Statements | |
| RIDADR | UN 2924 3/PG 2 |
| WGK Germany | - |
| HazardClass | 4.3 |
| PackingGroup | II |
| HS Code | 29319090 |
| Storage Class | 3 - Flammable liquids |
| Hazard Classifications | Acute Tox. 4 Oral Carc. 2 Eye Dam. 1 Flam. Liq. 2 Skin Corr. 1B STOT SE 3 |