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Бутилацетат
- английское имяButyl acetate
- CAS №123-86-4
- CBNumberCB6671615
- ФормулаC6H12O2
- мольный вес116.16
- EINECS204-658-1
- номер MDLMFCD00009445
- файл Mol123-86-4.mol
химическое свойство
Температура плавления | -78 °C (lit.) |
Температура кипения | 124-126 °C (lit.) |
плотность | 0.88 g/mL at 25 °C (lit.) |
плотность пара | 4 (vs air) |
давление пара | 15 mm Hg ( 25 °C) |
показатель преломления | n |
FEMA | 2174 | BUTYL ACETATE |
Fp | 74 °F |
температура хранения | Store at +5°C to +30°C. |
растворимость | 5.3g/l |
форма | Liquid |
Удельный вес | 0.883 (20/20℃) |
цвет | ≤10(APHA) |
Запах | Characteristic; agreeable fruity (in low concentrations); non residual. |
РН | 6.2 (5.3g/l, H2O, 20℃)(External MSDS) |
Пределы взрываемости | 1.4-7.5%(V) |
Порог?обнаружения?запаха? | 0.016ppm |
Odor Type | ethereal |
Вязкость | 0.83mm2/s |
Растворимость в воде | 0.7 g/100 mL (20 ºC) |
Точка замерзания | -77.9℃ |
λмакс | λ: 254 nm Amax: 1.0 λ: 260 nm Amax: 0.20 λ: 275 nm Amax: 0.04 λ: 300 nm Amax: 0.02 λ: 320-400 nm Amax: 0.01 |
Мерк | 14,1535 |
Номер JECFA | 127 |
БРН | 1741921 |
констант закона Генри | 5.79 at 37 °C (static headspace-GC, van Ruth et al., 2001) |
Диэлектрическая постоянная | 5.0(20℃) |
Пределы воздействия | TLV-TWA 150 ppm (~710 mg/m3) (ACGIH, MSHA, and OSHA); TLV-STEL 200 ppm (~950 mg/m3); IDLH 10,000 ppm (NIOSH). |
Стабильность | Stable. Flammable. Incompatible with strong oxidizing agents, strong acids, strong bases. |
ИнЧИКей | DKPFZGUDAPQIHT-UHFFFAOYSA-N |
LogP | 1.82-2.3 at 25℃ |
Вещества, добавляемые в пищу (ранее EAFUS) | BUTYL ACETATE |
FDA 21 CFR | 172.515; 175.105; 175.320; 177.1200 |
Справочник по базе данных CAS | 123-86-4(CAS DataBase Reference) |
Рейтинг продуктов питания EWG | 1 |
FDA UNII | 464P5N1905 |
Справочник по химии NIST | Acetic acid, butyl ester(123-86-4) |
Система регистрации веществ EPA | n-Butyl acetate (123-86-4) |
Информация о косметике | Butyl Acetate |
больше
Заявления о рисках | 10-66-67-R67-R66-R10 | |||||||||
Заявления о безопасности | 25-S25 | |||||||||
РИДАДР | UN 1123 3/PG 3 | |||||||||
OEB | A | |||||||||
OEL | TWA: 150 ppm (710 mg/m3), STEL: 200 ppm (950 mg/m3) | |||||||||
WGK Германия | 1 | |||||||||
RTECS | AF7350000 | |||||||||
Температура самовоспламенения | 790 °F | |||||||||
TSCA | Yes | |||||||||
кода HS | 2915 33 00 | |||||||||
Класс опасности | 3 | |||||||||
Группа упаковки | III | |||||||||
Банк данных об опасных веществах | 123-86-4(Hazardous Substances Data) | |||||||||
Токсичность | LD50 orally in rats: 14.13 g/kg (Smyth) | |||||||||
ИДЛА | 1,700 ppm | |||||||||
NFPA 704: |
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рисовальное письмо(GHS)
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рисовальное письмо(GHS)
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сигнальный язык
предупреждение
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вредная бумага
H226:Воспламеняющаяся жидкость. Пары образуют с воздухом взрывоопасные смеси.
H336:Может вызывать сонливость или головокружение.
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оператор предупредительных мер
P210:Беречь от тепла, горячих поверхностей, искр, открытого огня и других источников воспламенения. Не курить.
Бутилацетат химические свойства, назначение, производство
Описание
Butyl acetate is a clear, flammable ester of acetic acid that occurs in n-, sec-, and tert- forms (INCHEM, 2005). Butyl acetate isomers have a fruity, banana-like odor (Furia, 1980). Isomers of butyl acetate are found in apples (Nicholas, 1973) and other fruits (Bisesi, 1994), as a well as in a number of food products, such as cheese, coffee, beer, roasted nuts, vinegar (Maarse and Visscher, 1989). Butyl acetate is manufactured via esterification of the respective alcohol with acetic acid or acetic anhydride (Bisesi, 1994). N-butyl acetate is used as a solvent for nitrocellulose-based lacquers, inks, and adhesives. Other uses include manufacture of artificial leathers, photographic film, safety glass, and plastics (Budavari, 1996). Isomers of butyl acetate are also used as flavoring agents, in manicure products, and as larvicides (Bisesi, 1994). The tert-isomer has been used as a gasoline additive (Budavari, 1996). It may be used as a synthetic fruit flavoring in candy, ice cream, cheeses, and baked goods (Dikshith, 2013).![Butyl acetate](/NewsImg/2020-02-10/202021017104130372.jpg)
Химические свойства
Butyl acetate is a colorless or yellowish liquid with a strong fruity odor. burning and then sweet taste reminiscent of pineapple. It occurs in many fruits and is a constituent of apple aromas. Butyl acetate is incompatible with strong oxidizing agents, strong acids, and strong bases.There are 4 isomers. At 20 °C, the density of the n-butyl isomer is 0.8825 g/ cm3, and the density of the sec-isomer is 0.8758 g/cm3 (Bisesi, 1994). The n-butyl isomer is soluble in most hydrocarbons and acetone, and it is miscible with ethanol, ethyl ether, and chloroform (Haynes, 2010). It dissolves many plastics and resins (NIOSH, 1981).
Физические свойства
Clear, colorless liquid with a strong fruity odor resembling bananas. Sweetish taste as low concentrations (<30 μg/L). Experimentally determined detection and recognition odor threshold concentrations were 30 μg/m3 (6.3 ppbv) and 18 μg/m3 (38 ppbv), respectively (Hellman and Small, 1974). Cometto-Mu?iz et al. (2000) reported nasal pungency threshold concentrations ranged from approximately 550 to 3,500 ppm.Вхождение
Reported present in rum ether, pears, pear brandy, cider, mango, mountain papaya (C. pubescens), soybean, roasted peanuts and honey and other natural products.Использование
Butyl Acetate is a flavoring agent which is a clear, colorless liquid possessing a fruity and strong odor. it is sparingly soluble in water and miscible in alcohol, ether, and propylene glycol. it is also termed n-butyl acetate.Подготовка
By esterification of n-butyl alcohol with acetic acid.Методы производства
Butyl alcohol is combined with acetic acid in the presence of a catalyst such as sulfuric acid. After esterification is complete, the solution is distilled to yield butyl acetate .Определение
ChEBI: Butyl acetate is the acetate ester of butanol. It has a role as a metabolite. It is functionally related to a butan-1-ol.Общее описание
A clear colorless liquid with a fruity odor. Flash point 72 - 88°F. Density 7.4 lb / gal (less than water). Hence floats on water. Vapors heavier than air.Реакции воздуха и воды
Highly flammable. Very slightly soluble in water.Профиль реактивности
Butyl acetate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Attacks many plastics. [Handling Chemicals Safely 1980. p. 233].Опасность
Skin irritant, toxic. Flammable, moderate fire risk. Eye and upper respiratory tract irritant.Угроза здоровью
Exposures to n-butyl acetate cause harmful effects that include, but are not limited to, coughing and shortness of breath. High concentrations have a narcotic effect, with symp toms such as sore throat, abdominal pain, nausea, vomiting, and diarrhea. High concen trations of n-butyl acetate cause severe poisoning. Prolonged periods of exposure cause adverse effects to the lungs, the nervous system, and the mucous membranes. Repeated skin contact causes skin dryness or cracking, and dermatitis.Пожароопасность
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.Профиль безопасности
Moderately toxic by intraperitoneal route. Mdly toxic by inhalation and ingestion. An experimental teratogen. A skin and severe eye irritant. Human systemic effects by inhalation: conjunctiva irritation, unspecified nasal and respiratory system effects. A mild allergen. High concentrations are irritating to eyes and respiratory tract and cause narcosis. Evidence of chronic systemic toxicity is inconclusive. Flammable liquid. Moderately explosive when exposed to flame. Ignites on contact with potassium tert-butoxide. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid and irritating fumes. See also ESTERS.Возможный контакт
n-Butyl acetate is an important solvent in the production of lacquers, leather and airplane dopes, and perfumes. It is used as a solvent and gasoline additive. sec-Butyl acetate is used as a widely used solvent for nitrocellulose, nail enamels and many different purposes. tert-Butyl acetate is common industrial solvent used in the making of lacquers, artificial leather, airplane dope, perfume; and as a food additive. Isobutyl acetate is used as a solvent and in perfumes and artificial flavoring materialsКанцерогенность
There are no indications of mutagenic or cytogenic effects for n-butyl acetate.хранилище
n-Butyl acetate should be kept stored in a segregated and approved area. Workers should keep the container in a cool, well-ventilated area, closed tightly, and sealed until ready for use. Workers should avoid all possible sources of ignition/spark at the workplaceПеревозки
UN1123 Butyl acetates, Hazard Class: 3; Labels: 3—Flammable liquid.Методы очистки
Distil, reflux with successive small portions of KMnO4 until the colour persists, dry with anhydrous CaSO4, filter and redistil. [Beilstein 2 IV 143.]Несовместимости
All butyl acetates are incompatible with nitrates, strong oxidizers; strong alkalies; strong acids. Butyl acetates may form explosive mixture with air; reacts with water, on standing, to form acetic acid and n-butyl alcohol. Violent reaction with strong oxidizers and potassium-tert-butoxide. Dissolves rubber, many plastics, resins and some coatings. May accumulate static electrical charges, and may cause ignition of its vaporsУтилизация отходов
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.Меры предосторожности
On exposure to Butyl acetate, immediately wash with plenty of water, also under the eyelids, for at least 15 min. Remove contact lenses. Butyl acetate is flammable in the pres ence of open flames, sparks, oxidizing materials, acids, and alkalis. It poses explosion risk in the presence of mechanical impact. For health safety, management authorities should provide exhaust ventilation facilities at the workplace to keep the airborne concentrations of vapors of Butyl acetate below TLV.Бутилацетат запасные части и сырье
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