ГИДРАМЕТИЛНОН
- английское имяHydramethylnon
- CAS №67485-29-4
- CBNumberCB0296517
- ФормулаC25H24F6N4
- мольный вес494.48
- EINECS405-090-9
- номер MDLMFCD00128045
- файл Mol67485-29-4.mol
химическое свойство
| Температура плавления | 185-190°C |
| Температура кипения | 510.5±60.0 °C(Predicted) |
| плотность | 1.2816 (estimate) |
| давление пара | 2.7 x l0-6 Pa (25 °C) |
| температура хранения | 0-6°C |
| растворимость | Chloroform (Slightly), DMSO (Sparingly), Methanol (Slightly) |
| Растворимость в воде | 0.005-0.007 mg l-1(25 °C) |
| пка | 14.38±0.40(Predicted) |
| БРН | 6015162 |
| Стабильность | Light Sensitive |
| Справочник по базе данных CAS | 67485-29-4(CAS DataBase Reference) |
| FDA UNII | J265GZ7MFJ |
| Предложение 65 Список | Hydramethylnon |
| Справочник по химии NIST | 2(1H)-pyrimidinone, tetrahydro-5,5-dimethyl-, (3-(4-(trifluoromethyl)phenyl)-1-(2-(4-(trifluoromethyl)phenyl)ethenyl)-2-propenylidene)hydrazone(67485-29-4) |
| Пестициды Закон о свободе информации (FOIA) | Amdro |
| Система регистрации веществ EPA | Hydramethylnon (67485-29-4) |
| UNSPSC Code | 41116107 |
| NACRES | NA.24 |
| Коды опасности | T;N,N,T |
| Заявления о рисках | 22-36-48/25-50/53 |
| Заявления о безопасности | 1/2-22-26-36/37-45-60-61 |
| РИДАДР | UN3077 9/PG 3 |
| WGK Германия | 3 |
| RTECS | UW7583000 |
| Банк данных об опасных веществах | 67485-29-4(Hazardous Substances Data) |
рисовальное письмо(GHS)
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рисовальное письмо(GHS)
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сигнальный язык
опасность
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вредная бумага
H319：При попадании в глаза вызывает выраженное раздражение.
H302：Вредно при проглатывании.
H372：Поражает органы в результате многократного или продолжительного воздействия.
H410：Чрезвычайно токсично для водных организмов с долгосрочными последствиями.
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оператор предупредительных мер
P273：Избегать попадания в окружающую среду.
P301+P312+P330：ПРИ ПРОГЛАТЫВАНИИ: Обратиться за медицинской помощью при плохом самочувствии. Прополоскать рот.
P305+P351+P338：ПРИ ПОПАДАНИИ В ГЛАЗА: Осторожно промыть глаза водой в течение нескольких минут. Снять контактные линзы, если Вы ими пользуетесь и если это легко сделать. Продолжить промывание глаз.
P314：В случае плохого самочувствия обратиться к врачу.
ГИДРАМЕТИЛНОН химические свойства, назначение, производство
Описание
Hydramethylnon is an organic pesticide active ingredient from the trifluoromethyl aminohydrazone chemical class. It is a registered chemical alternative for chlorpyrifos for use as a termiticide and against ants, crickets, and cockroaches around the home and lawn. Hydramethylnon is also used in a wide variety of professional pesticide products and in various formulations, These include foaming products, granular products, gel baits, liquid concentrates.Химические свойства
Yellow to orange crystal, solubility (25°C): water 0.005～0.007mg/L, (20°C) acetone 360g/L, chlorobenzene 390g/L, 1,2-dichloroethane 170g/L, ethanol 72g/L, methanol 230g/L, isopropanol 12g/L, xylene 94g/L. Stable at 25°C for 2 years, stable at 45°C for 90 days, decomposition by sunlight DT50 about 1 hour; fluorantrazone aqueous suspension is stable to hydrolysis, DT50 24-33 days (pH 4.9), 10-11 days (pH 7,03), 11-12 days (pH 8.87). Decomposition of DT50 in soil took about 6 days.История
Hydramethylnon was developed by DuPont in 1975 and introduced to ornamentals industry in the 1990s. Acequinocyl was also discovered by DuPont in the 1970s and further developed by AgroKanesbo Co. Ltd. and Tomen Agro in Japan. Arysta LifeScience first introduced acequinocyl to the U.S. ornamentals market in 2005. Bifenazate was first developed by Uniroyal Chemical in 1990 and commercialized by Crompton Corporation in 1999. Bifenazate was introduced to the ornamental market in 2010.Использование
Hydramethylon is an insecticide primarily used in the form of baits for cockroaches and ants.прикладной
Hydramethylnon is used in baits for selective control of agricultural and household Formicidae (especially Camponot us, Iridomyrmex, Monomorium, Solenopsis and Pogomyrmex spp. and Pheidole megacephala). It is also used to control Blattellidae (especially Blatta, Blattella, Periplaneta and Supella spp.). It can be carried into the nest by worker ants and kill the queen because it is slow acting.Определение
ChEBI: Hydramethylnon is a member of the class of hydrazones that is used as an insecticide for control of ants and cockroaches. It has a role as a mitochondrial cytochrome-bc1 complex inhibitor and an insecticide. It is a hydrazone, a member of pyrimidines, a member of (trifluoromethyl)benzenes, an olefinic compound and a member of guanidines.Подготовка
Hydramethylnon synthesis was achieved through the coupling in alcoholic media refluxing the compound 1,5-bis[p-(trifluoromethoxy)phenyl]-1,4-pentadien-3-one afforded the desired product in 50% yield.
Synthesis of hydramethylnon
Общее описание
Hydramethylnon appears as odorless yellow crystals. Insoluble in water. Used as an insecticide.Реакции воздуха и воды
Insoluble in water. Hydrolysis occurs rapidly at low and high pHs.Профиль реактивности
Hydramethylnon is a trifluoromethyl amidinohydrazone.Профиль безопасности
Hydramethylnon is safe to use when applied according to label directions. It has been classified by the EPA as being a low threat when it comes to toxicity to humans, pets and birds.Метаболический путь
Amdro (AC 217,300) is rapidly photodegraded under borosilicate-filtered xenon arc lamps at 27 C as a suspension in distilled water. The half-life of amdro is calculated as 42 min and four degradation products are identified as 1,5-bis(a,a,a-trifluoro-p-tolyl)-1,4- pentadien-3-one, a,a,a-trifluoro-p-toluic acid, p- (trifluoromethyl)cinnamic acid, 6,7,8,9-tetrahydro-7,7- dimethyl-3-[p-(trifluoromethyl)styryl]-4H-pyrimido[2,1-c]- as-triazin-4-one. These degradation products are identical to those of the metabolites by insect.Способ действия
Hydramethylnon is a metabolic inhibitor. It works by inhibiting complex III in the mitochondrial inner membrane and leads to a halting of oxidative phosphorylation.ГИДРАМЕТИЛНОН запасные части и сырье
ГИДРАМЕТИЛНОН поставщик
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