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网站主页CAS数据库列表 122-39-4更多图谱二苯胺(122-39-4)红外图谱(IR1)

二苯胺

产品名称 二苯胺

CAS号122-39-4

分子式C12H11N

分子量169.22

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  • Mass

    MS-NW-0485          
    diphenylamine
    C12H11N             (Mass of molecular ion:    169)
    

       Source Temperature: 150 °C
       Sample Temperature: 120 °C
       Direct, 75 eV
    

          27.0       3.0
          28.0       1.1
          37.0       1.2
          38.0       3.6
          39.0      13.2
          40.0       1.9
          41.0       1.1
          50.0       6.6
          51.0      22.5
          52.0       4.4
          58.5       1.0
          62.0       1.6
          63.0       5.6
          64.0       3.8
          65.0      10.6
          66.0      12.2
          67.0       1.0
          70.5       1.3
          71.5       1.6
          74.0       2.1
          75.0       1.7
          76.0       1.8
          77.0      15.4
          78.0       2.9
          83.5       5.9
          84.0       1.3
          84.5       1.7
          89.0       2.0
          90.0       1.3
          91.0       2.0
          92.0       1.7
          93.0       1.2
         104.0       2.0
         115.0       5.5
         116.0       1.3
         128.0       1.5
         139.0       2.7
         140.0       2.2
         141.0       4.5
         142.0       2.8
         143.0       1.8
         154.0       2.5
         166.0       3.1
         167.0      19.1
         168.0      35.9
         169.0     100.0
         170.0      13.1
    

in DMSO-d6

400 MHz in CDCl3

90 MHz in CDCl3




  • 1H NMR 399.65 MHz
    C12 H11 N 0.040 g : 0.5 ml CDCl3
    diphenylamine
    ChemicalStructure
        Assign.     Shift(ppm)
    A 7.241 B 7.041 C 6.910 D 5.63

         Hz     ppm     Int.
    

       2906.74   7.274     37
       2904.42   7.268    112
       2902.34   7.263    581
       2900.39   7.258    231
       2897.22   7.250    163
       2895.02   7.244    843
       2893.80   7.241    897
       2891.85   7.236    169
       2888.43   7.228    293
       2886.47   7.223    790
       2884.40   7.218    131
       2820.68   7.058    196
       2818.85   7.054    836
       2817.63   7.051   1000
       2815.55   7.046    297
       2812.13   7.037    301
       2811.16   7.035    490
       2810.18   7.032    814
       2809.08   7.029    721
       2806.76   7.024    117
       2769.65   6.931    228
       2768.55   6.928    377
       2767.46   6.925    209
       2762.21   6.912    324
       2761.23   6.910    631
       2760.25   6.907    310
       2757.32   6.900     35
       2755.00   6.894    191
       2753.91   6.891    307
       2752.69   6.888    170
       2251.59   5.634    104
    


  • 1H NMR 89.56 MHz
    C12 H11 N 0.039 g : 0.5 ml CDCl3
    diphenylamine
    ChemicalStructure
        Assign.     Shift(ppm)
    A 7.22 B 7.04 C 6.92 D 5.6

         Hz     ppm     Int.
    

        658.06   7.348    123
        657.00   7.336    193
        655.19   7.316    105
        650.81   7.267    323
        649.44   7.252    451
        648.31   7.239    406
        647.25   7.228    158
        644.56   7.197    194
        642.44   7.174    609
        642.00   7.169    517
        641.63   7.165    539
        640.25   7.149    202
        637.81   7.122     50
        635.00   7.091    543
        633.63   7.075    839
        633.13   7.070   1000
        630.75   7.043    207
        628.06   7.013    185
        627.63   7.008    199
        627.06   7.002    208
        626.19   6.992    559
        624.75   6.976    439
        623.00   6.957    160
        621.44   6.939     58
        619.94   6.923    156
        618.63   6.908    181
        617.75   6.898    357
        615.25   6.870     97
        612.44   6.839     93
        610.81   6.821    145
        609.31   6.804     75
    

in DMSO-d6

in CDCl3





CCl4 solution



KBr disc



nujol mull



4880 A,200 M,powder



HEATING WITH DI-T-BUTYLPEROXIDE

AIBN CATALYZED OXIDATION