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ChemicalBook >  Product Catalog >  Flavors and fragrances >  Synthetic fragrances >  Halogen, sulfur, nitrogen compounds >  Halogen-containing compounds >  2,2,2-Trichloro-1-phenylethyl acetate

2,2,2-Trichloro-1-phenylethyl acetate

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2,2,2-Trichloro-1-phenylethyl acetate Basic information
2,2,2-Trichloro-1-phenylethyl acetate Chemical Properties
Safety Information
  • WGK Germany 2
  • RTECS AJ8375000
  • ToxicityLD50 orl-rat: 6800 mg/kg FCTXAV 13,681,75
MSDS
2,2,2-Trichloro-1-phenylethyl acetate Usage And Synthesis
  • Chemical Propertieswhite powder
  • Chemical Properties2,2,2-Trichloro-1-phenylethyl acetate forms white crystals (mp 88 °C) and has a weak, very natural, lasting rose odor.
    The ester is prepared from ??-trichloromethylbenzyl alcohol, for example, by reaction with acetic anhydride. The alcohol can be prepared by one of the following methods:
    1) Addition of trichloroacetaldehyde (chloral) to benzene in the presence of aluminum chloride.
    2) Reaction of benzaldehyde with chloroform in the presence of potassium hydroxide.
    ??-Trichloromethylbenzyl acetate is a stable rose fragrancewith excellent fixative properties. It is preferentially used in soaps, powders, and bath salts.
  • OccurrenceHas apparently not been reported to occur in nature.
  • UsesPerfumes, fixative for essential oils and perfumes.
  • PreparationBy the reaction of benzene and chloral, in the presence of a catalyst, followed by acetylation.
  • Trade nameRosalin (Yinghai)
  • Safety ProfileMildly toxic by ingestion. A skinirritant. When heated to decomposition it emits toxicfumes of Clí.
2,2,2-Trichloro-1-phenylethyl acetate Preparation Products And Raw materials
2,2,2-Trichloro-1-phenylethyl acetate(90-17-5)Related Product Information
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