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Chemical Reagents
Organic reagents
Phosphine ligand
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
Product Name
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
CAS
352655-61-9
MF
C74H104O6P2
MW
1151.56
EINECS
MOL File
352655-61-9.mol
Chemical Properties
Boiling point
951.5±65.0 °C(Predicted)
form
crystal
color
white
Safety Information
WGK Germany
3
HS Code
29319090
Usage And Synthesis
Reaction
Rh-catalyzed reductive coupling of acetylene to aldehydes and ketones.
Pt-catalyzed intramolecular hydroarylation of unactivated alkenes with indoles.
Enantioselective C-C bond activation of allenyl cyclobutanes.
Enantioselective ring-opening of rac-ethynyl epoxides.
Enantioselective Au-catalyzed allylic alkylation of indoles with alcohols.
Enantioselective Rh-catalyzed conjugate alkynylation with TMS-acetylene.
Enantioselective Rh-catalyzed [3+2] annulation of aromatic ketimines.
Asymmetric Rh-catalyzed Pausan-Khand reaction.
Chemical Properties
Off-white powder
Uses
Atropisomeric MeOBIPHEP ligands
Asymmetrical conjugate addition of arylboronic acids to maleimides and enones catalyzed by rhodium complexes
Intramolecular ketone hydroacylation
Desymmetrization through enantioselective C-C bond activation and ring expansion of allenyl cyclobutanols
Hydroamination of bicyclic alkenes and dienes with anilines
1,4-addition/asymmetric protonation of amino acrylates
General Description
sold in collaboration with Solvias AG
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Supplier
Zhengzhou Alfa Chemical Co.,Ltd
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+8618530059196
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Suzhou Origin Specialty Chemicals Co., Ltd.
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+86-512-68662322 +86-17312436797
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hanqun@origsc.com
Aladdin Scientific
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Energy Chemical
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Related Product Information
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(R)-SEGPHOS
(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
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(R)-H8-BINAP
(R)-DIFLUORPHOS(TM)
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(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
Chloro[(R)-(-)5,5μ-bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4μ-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride
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