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Chemical Reagents
Organic reagents
Phosphine ligand
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
Product Name
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
CAS
352655-61-9
MF
C74H104O6P2
MW
1151.56
EINECS
MOL File
352655-61-9.mol
Chemical Properties
Boiling point
951.5±65.0 °C(Predicted)
form
crystal
color
white
Safety Information
WGK Germany
3
HS Code
29319090
Usage And Synthesis
Reaction
Rh-catalyzed reductive coupling of acetylene to aldehydes and ketones.
Pt-catalyzed intramolecular hydroarylation of unactivated alkenes with indoles.
Enantioselective C-C bond activation of allenyl cyclobutanes.
Enantioselective ring-opening of rac-ethynyl epoxides.
Enantioselective Au-catalyzed allylic alkylation of indoles with alcohols.
Enantioselective Rh-catalyzed conjugate alkynylation with TMS-acetylene.
Enantioselective Rh-catalyzed [3+2] annulation of aromatic ketimines.
Asymmetric Rh-catalyzed Pausan-Khand reaction.
Chemical Properties
Off-white powder
Uses
Atropisomeric MeOBIPHEP ligands
Asymmetrical conjugate addition of arylboronic acids to maleimides and enones catalyzed by rhodium complexes
Intramolecular ketone hydroacylation
Desymmetrization through enantioselective C-C bond activation and ring expansion of allenyl cyclobutanols
Hydroamination of bicyclic alkenes and dienes with anilines
1,4-addition/asymmetric protonation of amino acrylates
General Description
sold in collaboration with Solvias AG
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Supplier
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com
Energy Chemical
Tel
021-021-58432009 400-005-6266
Email
sales8178@energy-chemical.com
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Email
product02@bidepharm.com
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Related Product Information
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(R)-DM-BINAP
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(S)-SunPhos
(S)-(+)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(R)-(+)-TolBINAP
R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
(R)-SEGPHOS
(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS
(R)-H8-BINAP
(R)-DIFLUORPHOS(TM)
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
Chloro[(R)-(-)5,5μ-bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4μ-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride
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