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(R)-DM-BINAP

Basic information Reaction Safety Related Supplier
(R)-DM-BINAP Basic information
(R)-DM-BINAP Chemical Properties
  • Melting point:203-206°C
  • alpha 169 º (c=1 in chloroform)
  • Boiling point:825.3±65.0 °C(Predicted)
  • form crystal
  • color white to pale yellow
  • optical activity[α]20/D +169°, c = 1 in chloroform
Safety Information
  • Risk Statements 36/37/38
  • Safety Statements 26-37
  • WGK Germany 3
  • TSCA No
(R)-DM-BINAP Usage And Synthesis
  • Reaction
    1. Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
    2. Ligand used in the enantioselective fluorination of oxindoles.
    3. Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
    4. Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
    5. Asymmetric hydroboration of unsaturated imines.
(R)-DM-BINAP(137219-86-4)Related Product Information
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