(R)-DM-BINAP

1. Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
2. Ligand used in the enantioselective fluorination of oxindoles.
3. Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
4. Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
5. Asymmetric hydroboration of unsaturated imines.

(R)-(+)-XylBINAP is a phosphine-based ligand used in the preparation of various catalysts, such as Pd catalysts for the asymmetric dearomative alkenylation of indoles through a reductive-?Heck reaction.