(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

Reaction

1. Rh-catalyzed reductive coupling of acetylene to aldehydes and ketones.
2. Pt-catalyzed intramolecular hydroarylation of unactivated alkenes with indoles.
3. Enantioselective C-C bond activation of allenyl cyclobutanes.
4. Enantioselective ring-opening of rac-ethynyl epoxides.
5. Enantioselective Au-catalyzed allylic alkylation of indoles with alcohols.
6. Enantioselective Rh-catalyzed conjugate alkynylation with TMS-acetylene.
7. Enantioselective Rh-catalyzed [3+2] annulation of aromatic ketimines.
8. Asymmetric Rh-catalyzed Pausan-Khand reaction. 

Chemical Properties

Uses

• Asymmetrical conjugate addition of arylboronic acids to maleimides and enones catalyzed by rhodium complexes
• Intramolecular ketone hydroacylation
• Desymmetrization through enantioselective C-C bond activation and ring expansion of allenyl cyclobutanols
• Hydroamination of bicyclic alkenes and dienes with anilines
• 1,4-addition/asymmetric protonation of amino acrylates

General Description