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Diethylene Glycol Monoethyl Ether Structure

Diethylene Glycol Monoethyl Ether

Chemical Properties

Melting point −76 °C (−105 °F; 197 K)
Boiling point 196 to 202 °C (385 to 396 °F; 469 to 475 K)
Density  0.99
vapor density  4.63 (vs air)
vapor pressure  0.12 mm Hg ( 20 °C)
refractive index  1.43
Flash point 96 °C (205 °F; 369 K)
storage temp.  Store below +30°C.
solubility  water: soluble
pka 14.37±0.10(Predicted)
form  clear liquid
color  Colorless to Almost colorless
Odor Weakly fruity; mild and characteristic.
biological source synthetic
explosive limit 1.8-12.2%(V)
Water Solubility  Miscible
Thermal Conductivity 0.188 W/(m·K) at 50 ℃
Specific Heat Capacity Cp(liquid): 2.24 J/(g·K), at 25℃
Sensitive  Hygroscopic
Merck  14,1800
BRN  1736441
Henry's Law Constant 4.4×102 mol/(m3Pa) at 25℃, Duchowicz et al. (2020)
Stability Stable. Combustible. Note wide explosion limits. Incompatible with strong oxidizing agents, strong acids, acid chlorides, acid anhydrides. Hygroscopic.
Cosmetics Ingredients Functions HUMECTANT
PERFUMING
SOLVENT
Cosmetic Ingredient Review (CIR) Diethylene Glycol Monoethyl Ether (111-90-0)
InChI 1S/C6H14O3/c1-2-8-5-6-9-4-3-7/h7H,2-6H2,1H3
InChIKey XXJWXESWEXIICW-UHFFFAOYSA-N
SMILES CCOCCOCCO
LogP -0.54 at 20℃
CAS DataBase Reference 111-90-0(CAS DataBase Reference)
NIST Chemistry Reference Ethanol, 2-(2-ethoxyethoxy)-(111-90-0)
EPA Substance Registry System Diethylene glycol monoethyl ether (111-90-0)

Safety Information

Hazard Codes  Xn,Xi
Risk Statements  36-20-36/37/38
Safety Statements  23-24/25-39-26-36
WGK Germany  1
RTECS  KK8750000
Autoignition Temperature 204 °C
TSCA  TSCA listed
HS Code  29094400
Storage Class 10 - Combustible liquids
Hazardous Substances Data 111-90-0(Hazardous Substances Data)
Toxicity LD50 orally in rats: 8.69 g/kg (Smyth, Carpenter)

MSDS

Usage And Synthesis

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