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LINALYL ISOBUTYRATE

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LINALYL ISOBUTYRATE Basic information
LINALYL ISOBUTYRATE Chemical Properties
LINALYL ISOBUTYRATE Usage And Synthesis
  • DescriptionLinalyl isobutyrate has a light, fruity odor with a lavender note and a sweet flavor reminiscent of black currant. May be synthe sized by esterification of linalool with isobutyric anhydride.
  • Chemical PropertiesLinalyl isobutyrate has a light, fruity odor with a lavender note and a sweet flavor reminiscent of black currant.
  • Chemical PropertiesLinalyl Isobutyrate has a fresh, fruity lavender odor,which is more refined than that of the butyrate. It is used in lavender compositions and in several floral notes.
  • OccurrenceReported found in the essential oil of Ceylon cinnamon and in lavender oil; a dextrorotatory form has been reported in the oil from leaves of Agathosoma gnidioides and sour cherry.
  • UsesLinalyl Isobutyrate is a flavoring agent that is a liquid, slightly yellow in color with a fruity odor. it is miscible in alcohol, ether, and chloroform, and insoluble in water. it is obtained by chemical synthesis. it is also termed 3,7-dimethyl-2,6-octadien-3-yl isobutrate.
  • PreparationBy esterification of linalool with isobutyric anhydride.
  • Taste threshold valuesTaste characteristics at 20 ppm: floral, fruity, sweet, berry and citrus.
  • Toxicity evaluationIn the rat, the acute oral LD 50 was reported to be > 36.3 g/kg (Jenner, Hagan, Taylor, Cook & Fitzhugh, 1964). At this dose, the highest tested, toxic signs included depression, wet fur and diarrhoea, but the surviving animals appeared normal after 1 wk. In the mouse, the acute oral LD 50 was 151 g/kg (Jenner et al. 1964); animals were depressed soon after treatment and excitable after 1 hr, with rough fur, and death occurred between 4 hr and 3 days. The acute dermal LD 50 in rabbits was reported as > 5 g/kg (Moreno, 1974).
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