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Titanium ethoxide

Product NameTitanium ethoxide
CAS3087-36-3
MFC8H20O4Ti
MW228.11
EINECS221-410-8
MOL File3087-36-3.mol

Chemical Properties

Melting point	54°C
Boiling point	150-152 °C10 mm Hg(lit.)
Density	1.088 g/mL at 25 °C(lit.)
vapor pressure	57.26hPa at 19.6℃
refractive index	n20/D 1.505(lit.)
Flash point	84 °F
storage temp.	2-8°C
solubility	Soluble in organic solvents.
form	Liquid
color	Pale yellow
Specific Gravity	1.107 (20℃)
Water Solubility	reacts
Sensitive	Moisture Sensitive
BRN	3678992
Exposure limits	ACGIH: TWA 200 ppm; STEL 400 ppm OSHA: TWA 400 ppm(980 mg/m3) NIOSH: IDLH 2000 ppm; TWA 400 ppm(980 mg/m3); STEL 500 ppm(1225 mg/m3)
Stability	Stability Incompatible with strong oxidizing agents, strong acids. May decompose upon exposure to air or moisture.
InChIKey	JMXKSZRRTHPKDL-UHFFFAOYSA-N
LogP	-0.3 at 25℃
CAS DataBase Reference	3087-36-3(CAS DataBase Reference)
NIST Chemistry Reference	Ti(OEt)4(3087-36-3)
EPA Substance Registry System	Ethanol, titanium(4+) salt (3087-36-3)

Safety Information

Hazard Codes	Xi
Risk Statements	10-36/37/38-67
Safety Statements	26-37/39-16
RIDADR	UN 1993 3/PG 3
WGK Germany	3
F	3-10-21
TSCA	Yes
HazardClass	4.1
PackingGroup	III
HS Code	29051900

MSDS

Provider	Language
Ethyl titanate	English
SigmaAldrich	English
ACROS	English
ALFA	English

Usage And Synthesis

Chemical Properties

colourless liquid

Uses

Titanium(IV) ethoxide can be used:

As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
As a Ti⁴⁺ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.

Uses

Titanium ethoxide is used widely as a precursor for the synthesis of Ti⁴⁺ ions titania nanoparticles by various techniques such as :

in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.

Uses

Titanium(IV) ethoxide is used in organic synthesis and material science. It is involved in the synthesis of anti-perspirants and antifungal agents. Furthermore, it is used to prepare carbon films in association with silicon dioxide. It is also used as a precursor for the synthesis of Ti4+ ions titanium nanoparticles by various methods.

Application

Titanium(IV) ethoxide can be used:
As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.

Flammability and Explosibility

Flammable

Materials Uses

Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.

Titanium ethoxide

Chemical Properties

Safety Information

MSDS

Usage And Synthesis

Preparation Products And Raw materials

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