ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organomagnesium > METHYLMAGNESIUM BROMIDE
METHYLMAGNESIUM BROMIDE
- Product Name:METHYLMAGNESIUM BROMIDE
- CAS:75-16-1
- MF:CH3BrMg
- MW:119.24
- EINECS:200-844-1
- Mol File:75-16-1.mol
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METHYLMAGNESIUM BROMIDE Chemical Properties
- Boiling point:78-80℃
- Density 1.035 g/mL at 25 °C
- Flash point:77 °F
- storage temp. water-free area
- form Solution, may develop some turbidity precipitate
- color Pale brown
- Water Solubility Reacts with water.
- Sensitive Air & Moisture Sensitive
- BRN 3535220
- InChIKeyAVFUHBJCUUTGCD-UHFFFAOYSA-M
- CAS DataBase Reference75-16-1(CAS DataBase Reference)
- EPA Substance Registry SystemMagnesium, bromomethyl- (75-16-1)
- Hazard Codes C,F+,F
- Risk Statements 12-14-19-22-34-66-67-52/53-10-65-63-48/20-14/15-11-37
- Safety Statements 9-16-26-45-61-36/37/39-62-43-36/37-23
- RIDADR UN 3399 4.3/PG 1
- WGK Germany 2
- RTECS OM3700000
- F 1-3-10
- TSCA Yes
- HazardClass 4.3
- PackingGroup I
- HS Code 29319090
- Language:EnglishProvider:SigmaAldrich
- Language:EnglishProvider:ACROS
- Language:EnglishProvider:ALFA
METHYLMAGNESIUM BROMIDE Usage And Synthesis
- Chemical PropertiesClear brown solution when properly stored
- UsesGrignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)
- DefinitionAvailable in solution inether.
- General DescriptionA colorless cloudy solution in diethyl ether. Flash point -49°F. Vapors heavier than air.
- Air & Water ReactionsHighly flammable. Reacts with water or moisture in the air to form flammable methane gas. The heat from this reaction may be sufficient to ignite the produced methane [AAR 1991]. Unstable peroxides may form with exposure of the ether to air. This is a slow process.
- Reactivity ProfileOrganometallics, such as METHYL MAGNESIUM BROMIDE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases.
- HazardFlammable, dangerous fire and explosionrisk.
- Health HazardFire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.
- Fire HazardFlammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated.
- Safety ProfileMay ignite spontaneously in air. A very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. When heated to decomposition it emits acrid smoke and irritating fumes.
METHYLMAGNESIUM BROMIDE Preparation Products And Raw materials
- Vinylmagnesium bromide ISOBUTYLMAGNESIUM BROMIDE METHYLMAGNESIUM BROMIDE 4-TERT-BUTYLPHENYLMAGNESIUM BROMIDE 4-FLUOROPHENYLMAGNESIUM BROMIDE ISOPROPENYLMAGNESIUM BROMIDE ETHYNYLMAGNESIUM BROMIDE (1,3-DIOXAN-2-YLETHYL)MAGNESIUM BROMIDE ETHYLMAGNESIUM BROMIDE 2,4,6-TRIMETHYLPHENYLMAGNESIUM BROMIDE O-TOLYLMAGNESIUM BROMIDE PHENYLETHYNYLMAGNESIUM BROMIDE 4-Methoxyphenylmagnesium bromide 4-FLUORO-3-METHYLPHENYLMAGNESIUM BROMIDE 1-NAPHTHYLMAGNESIUM BROMIDE 4-CHLOROPHENYLMAGNESIUM BROMIDE DODECYLMAGNESIUM BROMIDE 2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE
METHYLMAGNESIUM BROMIDESupplierMore
- Company Name:Shaoxing Shangyu Hualun Chemical Co. Ltd. Gold
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- Company Name:Adamas Reagent, Ltd. Gold
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- Company Name:Lianyungang Yilong Chemical Co., Ltd. Gold
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