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trans,trans-2,4-Heptadienal

Product Nametrans,trans-2,4-Heptadienal

CAS4313-03-5

MFC7H10O

MW110.15

EINECS224-328-0

MOL File4313-03-5.mol

Chemical Properties

Melting point	84.5 °C
Boiling point	84-84.5 °C(lit.)
Density	0.881 g/mL at 25 °C(lit.)
FEMA	3164 \| (2E,4E)-HEPTADIENAL
refractive index	n20/D 1.534(lit.)
Flash point	150 °F
storage temp.	2-8°C
Water Solubility	INSOLUBLE
JECFA Number	1179
BRN	1699244
CAS DataBase Reference	4313-03-5(CAS DataBase Reference)
NIST Chemistry Reference	2,4-Heptadienal, (E,E)-(4313-03-5)
EPA Substance Registry System	2,4-Heptadienal, (2E,4E)- (4313-03-5)

Safety Information

Hazard Codes	T,Xi
Risk Statements	22-24-38
Safety Statements	36/37-45
RIDADR	UN 2810 6.1/PG 3
WGK Germany	3
F	10-23
Hazard Note	Irritant
HazardClass	6.1
PackingGroup	III
HS Code	29121900

MSDS

Usage And Synthesis

Description

2,4-Heptadienal retards or prevents the development of "off-flavors" in auto-oxidizing fats and oils. May be prepared by reduction with LiAlH4 of the dienoic acid prepared by the Doebner synthesis, followed by oxidation with Mn02 of the resulting dienol to the corresponding dienol; by the method of Marshall and Whiting.
Chemical Properties

clear yellow liquid
Chemical Properties

2,4-Heptadienal has a fatty, green odor In auto-oxidizing fats and oils, it retards or prevents the development of “off-favors ”.
Occurrence

Reported found as a volatile component in boiled chicken, in peas by enzymatic formation from lipids, as the odorous component in Vaccinium macrocarpon; additional products in which 2,4-heptadienal has been reportedly identifed include soybean oil, black-tea aroma (trans- and cis-form); bilberry aroma (Vaccinium myrtillus); frozen peas, sunfower oil, autooxidized lard, salted salmon, sturgeon caviar and salmon roe; the trans,trans-form has been reported found among the volatile favor components of potato chips and tomato Also reported found in natural sources including cranberry, guava, melon, blackberry, avocado, cabbage, raw or cooked potato, tomato, butter, lean fsh, smoked fsh, chicken fat, cooked chicken, beef fat, tea, cooked beef, lamb and pork, peanut oil, peanut butter, mango, caulifower, broccoli, tamarind, fgs, corn tortillas, lemon balm, oysters, crayfsh, clams, mate and Virginia tobacco
Definition

ChEBI: A heptadienal in which the two double bonds are located at positions 2 and 4 (the E,E-geoisomer).
Aroma threshold values

Aroma characteristics at 0.10%: green fatty, herbal, vegetative, aldehydic oily with cucumber and fried nuances.
Taste threshold values

Taste characteristics at 0.25 ppm: green fatty, harsh chicken fat, cucumber with brothy and fshy nuances.
General Description

2,4-Heptadienal is a specific marker of oxidative rancidity. It is also a potential algal metabolite.
Chemical Synthesis

By reduction with LiAlH4 of the dienoic acid prepared by the Doebner synthesis, followed by oxidation with MnO2 of the resulting dienol to the corresponding dienol; by the method of Marshall and Whiting.

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