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(2R)-(-)-GLYCIDYL 4-NITROBENZOATE

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(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Basic information
(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Chemical Properties
  • Melting point:60-62 °C (lit.)
  • storage temp. 2-8°C
  • optical activity[α]19/D 37°, c = 1.08 in chloroform
  • BRN 5278590
  • CAS DataBase Reference106268-95-5
Safety Information
  • Hazard Codes Xi
  • Risk Statements 36/37/38
  • Safety Statements 26-36
  • WGK Germany 3
  • RTECS RR0511000
  • 10-21
MSDS
(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Usage And Synthesis
  • Uses
    (2R)-(?)-Glycidyl 4-nitrobenzoate can be used as a starting material in the total synthesis of leukotriene B4.
  • Purification MethodsPurify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.]
(2R)-(-)-GLYCIDYL 4-NITROBENZOATE(106268-95-5)Related Product Information
(2R)-(-)-GLYCIDYL 4-NITROBENZOATESupplierMore
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