チオジカルブ

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H301：飲み込むと有毒

  H330：吸入すると生命に危険

  H400：水生生物に強い毒性

• 注意書き

  P260：粉じん/煙/ガス/ミスト/蒸気/スプレーを吸入しないこ と。

  P264：取扱い後は皮膚をよく洗うこと。

  P264：取扱い後は手や顔をよく洗うこと。

  P270：この製品を使用する時に、飲食または喫煙をしないこ と。

  P271：屋外または換気の良い場所でのみ使用すること。

  P273：環境への放出を避けること。

チオジカルブ 価格

チオジカルブ 化学特性,用途語,生産方法

• 外観

  白色, 結晶性粉末〜粉末

• 溶解性

  水に難溶 (0.035g/L)。多くの有機溶媒に可溶。水35mg/l(25℃)。ジクロロメタン150,アセトン8, メタノール5, キシレン3(全てg/kg 25℃)。エタノールに溶け、水にほとんど溶けない。

• 用途

  氨基甲酸酯类殺虫

• 説明

  Thiodicarb, 3,7,9,13-tetramethyl-5,11- dioxa-2,8,14-trithia-4,7,9,12-tetra-azapentadeca-3,12-di ene-6,10-dione (IUPAC), consists of colorless crystals, which are sparingly soluble in water, readily soluble in dichloromethane, acetone, methanol, and xylene. Thiodicarb is produced by reaction of N,N -thiobis(methylcarbamic acid fluoride) with 2-methylthioacetaldoxim in the presence of a base.

• 使用

  Thiodicarb is used as an insecticide.

• 一般的な説明

  Colorless to pale tan crystals. Non corrosive. Used as an insecticide.

• 空気と水の反応

  Hydrolyzed by strong acid or base.

• 反応プロフィール

  A carbamate derivative. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

• 农业用途

  Insecticide, Molluscicide, Ovicide: Not approved for use in EU countries. Registered for use in the U.S. Thiodicarb is used primarily on cotton, sweet corn, and soybeans. The remaining usage is spread among leafy vegetables, cole crops, ornamentals, and other minor use sites. Thiodicarb acts as an ovicide against cotton bollworms and budworms.

• 製品名

  CGA® 45156; CHIPCO[C]; DICARBOSULF®; DICARBASULF®; LARVIN®; LEPICRON®; SEMEVIN®; NIVRAL®; UC-51762®; UC 51769®; UC 80502®

• 環境運命予測

  Soil. Under aerobic and anaerobic soil conditions, thiodicarb degrades to methomyl and methomyl oxime (Hartley and Kidd, 1987). The reported half-life in various soils is 3–8 days (Hartley and Kidd, 1987).

• 代謝経路

  The initial metabolic reaction of thiodicarb in soils, plants and animals is the hydrolytic or thiolytic cleavage of the N-S bond to methomyl. The subsequent metabolic pathway of methomyl involves hydrolysis / elimination reactions to yield S-methyl-N-hydroxythioacetimidate and ultimately acetonitrile and CO₂ as the major terminal products. The metabolic pathways of thiodicarb are presented in Scheme l. See also the methomyl entry.

チオジカルブ 上流と下流の製品情報

59669-26-0, チオジカルブ キーワード