メチルスルフィド

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H225：引火性の高い液体および蒸気

  H303：飲み込むと有害のおそれ

  H316：軽度の皮膚刺激

  H320：眼刺激

• 注意書き

  P210：熱/火花/裸火/高温のもののような着火源から遠ざ けること。－禁煙。

  P233：容器を密閉しておくこと。

  P240：容器を接地すること/アースをとること。

  P241：防爆型の電気機器/換気装置/照明機器/．．．機器を使 用すること。

  P242：火花を発生させない工具を使用すること。

  P243：静電気放電に対する予防措置を講ずること。

  P264：取扱い後は皮膚をよく洗うこと。

  P264：取扱い後は手や顔をよく洗うこと。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P303+P361+P353：皮膚（または髪）に付着した場合：直ちに汚染された衣 類をすべて脱ぐこと/取り除くこと。皮膚を流水/シャワー で洗うこと。

  P305+P351+P338：眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

  P312：気分が悪い時は医師に連絡すること。

  P332+P313：皮膚刺激が生じた場合：医師の診断/手当てを受けるこ と。

  P337+P313：眼の刺激が続く場合：医師の診断/手当てを受けること。

  P370+P378：火災の場合：消火に．．．を使用すること。

  P403+P235：換気の良い場所で保管すること。涼しいところに 置くこと。

  P501：内容物/容器を．．．に廃棄すること。

メチルスルフィド 価格

メチルスルフィド 化学特性,用途語,生産方法

• 外観

  無色澄明の液体

• 溶解性

  水に難溶 (0.6g/100ml)。エタノール及びアセトンに溶け、水に溶けない。

• 解説

  C2H6S(62.14)．(CH3)2S．ジメチルスルフィドは，硫化ジメチルともいう．ヨウ化メチルと硫化カリウムとの反応で得られる．不快臭をもつ液体．融点－83 ℃，沸点37.34 ℃．d²⁰₄ 0.848．n²⁰_D 1.435．水に不溶，エタノール，エーテルに可溶．酸化によりDMSOを与える．多くの精油，ノリ，ワサビなどの食品にも含まれており，少量をフレーバーに使用する．悪臭防止法で指定されている悪臭物質．森北出版「化学辞典（第2版）

• 用途

  コーヒー、チョコレート、ココア系等の食品香料、LPガス着臭剤

• 説明

  Dimethyl sulfide, a sulfur ether compound, shares structural and property similarities with dimethyl ether. It is a colorless, volatile liquid that exhibits a distinct seafood-like odor. This compound is naturally generated through protein decomposition and serves as one of the culprits responsible for the fishy scent often associated with seafood.

• 化学的特性

  Methyl sulfide, also known as Dimethyl sulfide, is a clear colorless volatile liquid that has an intense, unpleasant odor, wild radish, cabbage-like. It can be tolerated as a green vegetable note only at very low levels (0.1 - 3.0 ppm). Dimethyl sulfide is soluble in ethanol and ether, but insoluble in water.

• 使用

  Dimethyl sulfide is used as a displaceable ligand in chloro(dimethyl sulfide)gold(I) and other coordination compounds, as a reducing agent in ozonolysis reactions as well as a food flavoring component. Further, it is utilized for the preparation of dimethyl sulfoxide, which is a common and important industrial solvent. It finds application in the petroleum industry.

• 製造方法

  By reaction of potassium sulfide with methyl chloride in methanol solution; from potassium methyl sulfate and potassium sulfide

• 定義

  ChEBI: Dimethyl sulfide is a methyl sulfide in which the sulfur atom is substituted by two methyl groups. It is produced naturally by some marine algae. It has a role as a bacterial xenobiotic metabolite, a marine metabolite, an EC 3.5.1.4 (amidase) inhibitor, an algal metabolite and an Escherichia coli metabolite.

• 一般的な説明

  A clear colorless to straw colored liquid with a disagreeable odor. Flash point less than 0°F. Less dense than water and slightly soluble in water. Vapors are heavier than air.

• 空気と水の反応

  Highly flammable. Slightly soluble in water.

• 反応プロフィール

  Organosulfides, such as Dimethyl sulfide, are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid. Dimethyl sulfide rapidly decomposes dibenzoyl peroxide explosively in the absence of solvent, [J. Org. Chem., 1972, 37, 2885]. The sulfide also decomposes xenon difluoride explosively at ambient temps, [J, Chem Soc., 1984, 2827]. Interaction of Dimethyl sulfide and oxygen is explosive at 210°C and above, [Atmos. Environ., 1967, 1, 491-497]. A delayed explosion occurred in a system containing nitric acid, Dimethyl sulfide, and 1, 4-dioxane, even with cooling with liquid nitrogen, [Chem. Abs., 1972, 76, 13515].

• 健康ハザード

  Inhalation causes moderate irritation of upper respiratory system. Contact of liquid with eyes causes moderate irritation. Repeated contact with skin may extract oils and result in irritation. Ingestion causes nausea and irritation of mouth and stomach.

• 安全性プロファイル

  Poison by inhalation. Moderately toxic by ingestion. A skin and severe eye irritant. A very dangerous fire hazard when exposed to heat or flame. Explosive in the form of vapor when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits highly toxic fumes of SOx and may explode. See also SULFIDES.

• 応急処置

  If Dimethyl sulfide gets into the eyes, remove anycontact lenses at once and irrigate immediately for15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

• 純化方法

  Purify dimethyl sulfide via the Hg(II) chloride complex by dissolving 1 mole of Hg(II)Cl2 in 1250mL of EtOH and slowly adding the boiling alcoholic solution of Me2S to give the right ratio for 2(CH3)2S.3HgCl2. After recrystallisation of the complex to constant melting point, 500g of complex is heated with 250mL conc HCl in 750mL of water. The sulfide is separated, washed with water, and dried with CaCl2 and CaSO4. Finally, it is distilled under reduced pressure from sodium. Precautions should be taken (efficient fume hood) because of its very UNPLEASANT ODOUR.[Beilstein 1 IV 1275.]

メチルスルフィド 上流と下流の製品情報

メチルスルフィド 生産企業

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メチルスルフィド スペクトルデータ(¹HNMR、¹³CNMR、IR1、MS、Raman)

75-18-3, メチルスルフィド キーワード