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テメホス

テメホス 化学構造式
3383-96-8
  • CAS番号.3383-96-8
  • 化学名:テメホス
  • 别名:O,O,O',O'-テトラメチル-O,O'-チオジ-p-フェニレンホスホロチオエート;ネフィス;テメホス;ネフィス1G;ビチオン;4,4'-チオビスフェノールビス(チオりん酸O,O-ジメチル);(チオジ-4,1-フェニレンビスオキシ)ビスホスホノチオ酸O,O,O',O'-テトラメチル;プロシダ;実験殺虫剤52160;アバチオン;ジフェンホス;[チオジ(1,4-フェニレンオキシ)]ビス(チオホスホン酸)O,O,O',O'-テトラメチル;エコプロ-1707;ビオチオン;アバート;ジホス(殺虫剤);テメホス標準品;O,O,O',O'-テトラメチル-O,O'-チオジ-p-フェニレンホス;チオジ(p-フェニレン)-ジオキシ-ビス(チオホスホン酸)O,O,O’,O’-テトラメチル;チオジ(パラ-フェニレン)-ジオキシ-ビス(チオホスホン酸) O,O,O',O'-テトラメチル (別名テメホス)
  • 英語化学名:Temephos
  • 英語别名:Abat;Difos;lypor;ABATE;Ecopro;oms786;swebat;Bithion;cl52160;ei52160
  • CBNumber:CB7265792
  • Molecular Formula:C16H20O6P2S3
  • Formula Weight:466.47
  • MOL File:3383-96-8.mol
テメホス 物理性質
  • 融点  :30-31°C
  • 沸点  :518.5±60.0 °C(Predicted)
  • 比重(密度)  :1.3200
  • 蒸気圧 :9.5×10-6Pa (20-25 °C)
  • 貯蔵温度  : 2-8°C
  • 外見  :solid
  • 水溶解度  :0.003 g/100 mL
  • Merck  :13,9214
  • BRN  :1896901
  • CAS データベース :3383-96-8(CAS DataBase Reference)
  • NISTの化学物質情報 :Temefos(3383-96-8)
  • EPAの化学物質情報 :Temephos (3383-96-8)
安全性情報
  • 主な危険性  :Xn,N
  • Rフレーズ  :21/22-51/53
  • Sフレーズ  :22-37-61-60
  • RIDADR  :UN 3077
  • WGK Germany  :3
  • RTECS 番号 :TF6890000
  • 国連危険物分類  :6.1
  • 容器等級  :III
  • 有毒物質データの :3383-96-8(Hazardous Substances Data)
  • 毒性 :LD50 in male, female rats (mg/kg): 8600, 13000 orally (Gaines)
危険有害性情報のコード(GHS)
  • 絵表示(GHS)
  • 注意喚起語Danger
  • 危険有害性情報
  • H302:飲み込むと有害
  • H311:皮膚に接触すると有毒
  • H410:長期的影響により水生生物に非常に強い毒性
  • 注意書き
  • P280:保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
テメホス 価格 もっと(10)
  • メーカー: 富士フイルム和光純薬株式会社(wako)
  • 製品番号: W01ACSP-101N
  • 製品説明 : アバテ標準品
  • 純度: Abate Standard
  • 包装: 10mg
  • 価格: ¥8100
  • 更新時間: 2021/03/23
  • 購入: 購入
  • メーカー: 富士フイルム和光純薬株式会社(wako)
  • 製品番号: W01ACSP-101NB-100
  • 製品説明 : アバテ
  • 純度: Abate
  • 包装: 100mg
  • 価格: ¥25900
  • 更新時間: 2021/03/23
  • 購入: 購入
  • メーカー: 関東化学株式会社(KANTO)
  • 製品番号: 49803-50
  • 製品説明 : テメホス標準品
  • 純度: Temephos standard
  • 包装: 100mg
  • 価格: ¥17000
  • 更新時間: 2021/03/23
  • 購入: 購入
  • メーカー: Sigma-Aldrich Japan
  • 製品番号: 31526
  • 製品説明 : テメホス
  • 純度: TemephosPESTANAL?, analytical standard
  • 包装: 250mg
  • 価格: ¥19600
  • 更新時間: 2021/03/23
  • 購入: 購入
  • メーカー: 林純薬工業株式会社
  • 製品番号: R1816100
  • 製品説明 : 
  • 純度: Temephosテメホス---
  • 包装: 100mg
  • 価格: ¥14100
  • 更新時間: 2021/03/22
  • 購入: 購入

テメホス MSDS


O,O,O',O'-Tetramethyl O,O'-(thiodi-4,1-phenylene) phosphorothioate

Temephos 化学特性,用途語,生産方法

  • 用途 農薬?殺虫剤
  • 効能 外寄生生物駆除薬 (獣医薬), アセチルコリンエステラーゼ阻害薬
  • 説明 Abate is the trade name for Temephos, the known organophosphate larvicide. Abate is used to treat water infested with disease-carrying fleas and control mosquito, midge, and black fly larvae. Abate quickly controls mosquito and other insect populations because it kills insect larvae before they mature, and the residual activity of abate prevents insect populations. On decomposition, abate produces oxides of carbon, phosphorous, and sulphur. Exposures to abate in workplaces cause adverse health effects (refer to Temephos for details).
  • 化学的特性 Abate is the trade name for Temephos, the known organophosphate larvicide. Abate is used to treat water infested with disease-carrying fl eas, to control mosquito, midge, and black fl y larvae. Abate quickly controls mosquito and other insect populations because it kills insect larvae before they mature, and the residual activity of abate prevents further insect populations. On decomposition, abate produces oxides of carbon, phosphorous, and sulfur.
  • 化学的特性 Temephos is a solid at room temperature and is composed of colorless crystals. As a liquid, it is brown and viscous. Temephos is a non-systemic insecticide. It is insoluble in water, hexane, and methyl cyclohexane, but soluble in common organic solvents. It is combustible and the liquid formulations contain organic solvents that may be flammable. Temophos decomposes on heating or burning, producing toxic fumes such as phosphorus oxides and sulfur oxides. Temephos reacts with strong acids and strong bases. The US EPA has grouped temephos as a GUP. Temephos is used for the control of mosquito, midge, and black fl y larvae. It is used in lakes, ponds, and wetlands. It may also be used to control fl eas on dogs and cats and to control lice on humans.
  • 使用 Temephos is used to control mosquito and black fly larvae in aqueous environments and as a human and veterinary ectoparasiticide.
  • 使用 Temephos is an organophosphate larvicide used to treat water infested with disease-carrying insects.
  • 使用 Insecticide.
  • 一般的な説明 White crystalline solid or liquid. Boiling point 87°F. Used as an insecticide. Technical grade is a viscous brown liquid.
  • 反応プロフィール Organothiophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
  • 危険性 Cholinesterase inhibitor. Questionable carcinogen.
  • 健康ハザード Exposures to high concentrations of temephos for a prolonged period of time cause poisoning to occupational workers. The symptoms include, but are not limited to, nausea, salivation, headache, loss of muscle coordination, and diffi culty breathing. Workers exposed to a combination of temephos and malathion suffer potentiation of toxicity of temephos. Exposures to granules of temephos formulation may cause irritation. Prolonged and repeated skin contact may cause irritation. Inhalation may cause respiratory irritation and chemical pneumonities. There are no reports on the prolonged effects of temephos.
  • 健康ハザード to avoid contamination of water, food, or feed, abate should be stored in a secure, dry,
  • 健康ハザード Abate is less toxic in comparison to withmost other organophosphorus pesticides.Among the test animals, rats showedalmost 10 times greater resistance to thiscompound than did mice and rabbits.In humans, ingestion can cause nausea,vomiting, diarrhea, and convulsions. Intakeof large amounts can result in respiratoryfailure.
    LD50 value, oral (rats): 8600 mg/kg.
  • 农业用途 Insecticide, Larvicide: Temephos is one of the few organophosphates that is registered to control mosquito larvae. It is a non-systemic insecticide for use on wetlands, ponds, lakes and other moist areas to control mosquito, gnat, black fly, midge, pinkie and sandfly larvae. Banned for use in EU countries[ 115]. Registered for use in the U.S.
  • 製品名 27165®; ABAT®; ABATE®; ABATE® 1-SG; ABATE® 2-CG; ABATE® 4-E; ABATE® 5CG; ABATHION®; AI3-27165®; AC 52160®; AMERICAN CYANAMID AC-52,160®; AMERICAN CYANAMID CL-52160®; AMERICAN CYANAMID E. I.52,160®; BIOTHION®; BITHION®; CL 52160®; DIFENPHOS®; DIFENTHOS®; DIFOS®; DIPHOS®; ECOPRO®; ECOPRO® 1707; EI 52160®; NEPHIS®; NEPHIS® 1G; NIMITEX®; NIMITOX®
  • 安全性プロファイル Posion by ingestion Moderately toxic by intraperitoneal, subcutaneous, and skin contact routes. An experimental teratogen. A skin irritant. A cholinesterase inhibitor type of insecticide. When heated to decomposition it emits toxic fumes of POx and SOx. See also PARATHION,
  • Carcinogenicity The EPA noted a chronic dog study (period of exposure not specified) in which significant inhibition of plasma and RBC cholinesterase occurred at dietary exposures equivalent to 12.5 mg/kg/day but not at 0.46 mg/kg/day .
    No evidence of carcinogenicity or other treatment-related effects occurred in rats fed a diet that contained 0, 10, 100, or 300 ppm temephos (equivalent to about 0.5, 5.0, or 15 mg/kg/ day) for 2 years . The animals in the treated groups were exposed in utero from gestation day 12 through parturition to 100 ppm of the test material, and at weaning pups were randomly allocated to the three treatment groups and the treatment initiated.
  • 代謝経路 Temephos is comparatively stable to metabolic degradation in both animals and plants. The main pathway is via thiooxidation to the sulfoxide and through hydrolysis to yield 4,4’-thiodiphenol and its thiooxidised derivatives which are conjugated as glucosides in plants and as sulfate esters in rats. Oxidative desulfuration to temephos oxon is apparently a minor pathway.
  • 貯蔵 During use and handling of abate, occupational workers/applicators should wear long- sleeved shirts, long pants, shoes, and socks, chemical-resistant gloves, and protective eyewear, goggles, or safety glasses. Flaggers must wear chemical-resistant headgear and protective eyewear.
  • Degradation Temephos is hydrolysed by strong acids and alkalis; its maximum stability is at pH 5-7 (PM). When a methanolic solution of temephos was exposed to sunlight it was rapidly decomposed resulting in the formation of at least eight photoproducts of which only temephos sulfoxide (2) and temephos sulfone (3) were identified. The sulfoxide was the major initial product but it was further photolysed to the sulfone (3) which was apparently refractory to further degradation suggesting that the other unidentified photoproducts arose directly from temephos or from the sulfoxide (2) (Rosen, 1972) (Scheme 1).
  • Toxicity evaluation Temephos has a very low mammalian toxicity; acute oral LD50 for male and female rats is 4204 and >10,000 mg/kg, respectively. NOEL (2 yr) for rats is 300 mg/kg diet (15 mg/kg/d). Temephos administered orally to rats is eliminated in the feces and urine. The major elimination compound is unchanged temephos. Other urinary metabolites are sulfate ester conjugates of 4,4 -thiodiphenol, its sulfoxide, and sulfone.
テメホス 上流と下流の製品情報
原材料
準備製品
テメホス 生産企業
Global(106)Suppliers
  • 名前:Henan DaKen Chemical CO.,LTD.
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  • ファックス番号:
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  • 国籍:China
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  • 電話番号:0371-55170693
  • ファックス番号:0371-55170693
  • 電子メール:info@tianfuchem.com
  • 国籍:CHINA
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  • 電話番号:+8619139973225
  • ファックス番号:
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  • 優位度:58
3383-96-8, テメホス キーワード:
  • 3383-96-8
  • bis-p-(o,o-dimethylo-phenylphosphorothioate)sulfide
  • Bithion
  • CL 52160
  • cl52160
  • Difenphos
  • Difenthos
  • Difos
  • Diphos (Pesticide)
  • diphos(pesticide)
  • diphos[pesticide]
  • Ecopro
  • ecopro1707
  • EI 52160
  • ei52160
  • ENT 27,165
  • ent27,165
  • Experimental Insecticide 52,160
  • Experimental Insecticide 52160
  • experimentalinsecticide52,160
  • experimentalinsecticide52160
  • lypor
  • Nephis 1G
  • nephis1g
  • Nimitex
  • Nimitox
  • O,O'-(Thiodi-4,1-phenylene)bis(O,O-dimethyl phosphorothioate)
  • O,O'-(Thiodi-4,1-phenylene)phosphorothioic acid O,O,O',O'-tetramethyl ester
  • O,O'-(Thiodi-p-phenylene) O,O,O',O'-tetramethyl bis(phosphorothioate)
  • o,o,o’,o’-tetramethylo,o’-thiodi-p-phenylenebis(phosphorothioate)
  • o,o’-(thiodi-4,1-phenylene)bis(o,o-dimethylphosphorothioate)
  • O,O,O',O'-テトラメチル-O,O'-チオジ-p-フェニレンホスホロチオエート
  • ネフィス
  • テメホス
  • ネフィス1G
  • ビチオン
  • 4,4'-チオビスフェノールビス(チオりん酸O,O-ジメチル)
  • (チオジ-4,1-フェニレンビスオキシ)ビスホスホノチオ酸O,O,O',O'-テトラメチル
  • プロシダ
  • 実験殺虫剤52160
  • アバチオン
  • ジフェンホス
  • [チオジ(1,4-フェニレンオキシ)]ビス(チオホスホン酸)O,O,O',O'-テトラメチル
  • エコプロ-1707
  • ビオチオン
  • アバート
  • ジホス(殺虫剤)
  • テメホス標準品
  • O,O,O',O'-テトラメチル-O,O'-チオジ-p-フェニレンホス
  • チオジ(p-フェニレン)-ジオキシ-ビス(チオホスホン酸)O,O,O’,O’-テトラメチル
  • チオジ(パラ-フェニレン)-ジオキシ-ビス(チオホスホン酸) O,O,O',O'-テトラメチル (別名テメホス)
  • CS_N-10996-100MG_テメホス
  • アバテ
  • アバテ STANDARD
  • アバテ標準品
  • アバテ Standard, 100 µg/mL in MeOH
  • 防疫用殺虫剤
  • 有機リン系殺虫剤