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(S)-(-)-LIMONENE Structure

(S)-(-)-LIMONENE

Chemical Properties

Melting point -74°C
Boiling point 175-177 °C(lit.)
alpha  -99.5 º (C=NEAT)
Density  0.844 g/mL at 25 °C(lit.)
vapor density  4.7 (vs air)
vapor pressure  <3 mm Hg ( 14.4 °C)
refractive index  n20/D 1.471(lit.)
Flash point 119 °F
storage temp.  Sealed in dry,Store in freezer, under -20°C
solubility  Chloroform (Sparingly), Ethanol (Slightly), Methanol (Slightly)
form  Liquid
color  Clear colorless to pale yellow
Odor at 100.00 %. terpene pine herbal peppery
Odor Type terpenic
explosive limit 0.7-6.1%(V)
optical activity [α]20/D 94±4°, c = 10% in ethanol
Water Solubility  Insoluble
Merck  14,5493
BRN  2323991
Stability Stable. Incompatible with strong oxidizing agents. Flammable.
LogP 4.38 at 37℃
Substances Added to Food (formerly EAFUS) L-LIMONENE
CAS DataBase Reference 5989-54-8(CAS DataBase Reference)
FDA UNII 47MAJ1Y2NE
NIST Chemistry Reference Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (S)-(5989-54-8)
EPA Substance Registry System Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (4S)- (5989-54-8)

Safety

Symbol(GHS)
Signal wordDanger
Hazard statements H226-H304-H317-H400
Precautionary statements P210-P273-P280-P301+P310+P331-P302+P352
Hazard Codes  Xi,N
Risk Statements  10-38-43-50/53
Safety Statements  24-37-60-61
RIDADR  UN 2052 3/PG 3
WGK Germany  2
RTECS  OS8350000
8-10-23
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29029090
NFPA 704:
2
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