Thiophosphorsäure-O,O-dimethyl-O-(3,5,6-trichlor-2-pyridinyl)ester

Bezeichnung:Thiophosphorsäure-O,O-dimethyl-O-(3,5,6-trichlor-2-pyridinyl)ester

CAS-Nr5598-13-0

Englisch Name:Chlorpyrifos-methyl

CBNumberCB8332228

SummenformelC7H7Cl3NO3PS

Molgewicht322.53

MOL-Datei5598-13-0.mol

Synonyma

Chlorpyrifos-methyl

Thiophosphorsäure-O,O-dimethyl-O-(3,5,6-trichlor-2-pyridinyl)ester

Thiophosphorsäure-O,O-dimethyl-O-(3,5,6-trichlor-2-pyridinyl)ester physikalisch-chemischer Eigenschaften

Schmelzpunkt	45.5-46.5°C
Siedepunkt	347.3±52.0 °C(Predicted)
Dichte	1.64 g/cm3(Temp: 23 °C)
Flammpunkt	>100 °C
storage temp.	APPROX 4°C
Löslichkeit	Chloroform: Slightly Soluble
pka	-5.59±0.10(Predicted)
Aggregatzustand	Crystalline Solid
Farbe	Amber
Wasserlöslichkeit	4mg/L(25 ºC)
Merck	13,2208
BRN	1541078
CAS Datenbank	5598-13-0(CAS DataBase Reference)
NIST chemische Informationen	o,o-Dimethyl-o-(3,5,6-trichloro-2-pyridyl)phosphorothioate(5598-13-0)
EPA chemische Informationen	Chlorpyrifos-methyl (5598-13-0)

Sicherheit

Kennzeichnung gefährlicher	Xi;N,N,Xi,Xn,F
R-Sätze:	43-50/53-36-20/21/22-11
S-Sätze:	36/37-60-61-36-26-16
RIDADR	UN 3077
WGK Germany	2
RTECS-Nr.	TG0700000
HS Code	29333990
Giftige Stoffe Daten	5598-13-0(Hazardous Substances Data)

Gefahreninformationscode (GHS)

Chlorpyrifos-methyl Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R43:Sensibilisierung durch Hautkontakt möglich.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R36:Reizt die Augen.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.
S-Sätze Betriebsanweisung:
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S16:Von Zündquellen fernhalten - Nicht rauchen.
Beschreibung
Chlorpyrifos-methyl is a general use organophosphate insecticide registered in 1985. It is used for the control of stored grain pests, weevils, moths, borers, beetles and mealworms, red flour beetle, and grain moth; for seed treatment; and for warehouse. It is effective against rice stem borer, aphids, cutworms, plant and leaf hoppers, mole crickets and some moths, and stored grain pests. It is poorly soluble in water, moderately soluble in hexane and alcohols, and readily soluble in other organic solvents such as acetone, benzene, and chloroform.
Chemische Eigenschaften
Chlorpyrifos-methyl is a general use organophosphate insecticide registered in 1985. It is used for the control of stored grain pests, weevils, moths, borers, beetles and mealworms, red fl our beetle, grain moth, for seed treatment. It is effective against rice stem borer, aphids, cutworms, plant and leaf hoppers, mole crickets, moths and stored grain pests. It is poorly soluble in water, moderately soluble in hexane and alcohols, and readily soluble in other organic solvents, such as acetone, benzene, and chloroform
Chemische Eigenschaften
White or amber crystalline solid. May be dissolved in a flammable or combustible carrier solvent.
Verwenden
Chlorpyriphos-methyl is an derivative of Chlorpyrifos (C425300), an insecticide that acts on the nervous system of insects by inhibiting acetylcholinesterase.
Definition
ChEBI: An organic thiophosphate that is O,O-dimethyl hydrogen phosphorothioate in which the hydrogen of the hydroxy group has been replaced by a 3,5,6-trichloropyridin-2-yl group.
Allgemeine Beschreibung
Colorless crystals. Corrosive to copper, brass, iron, and tin plate. Used as an insecticide.
Air & Water Reaktionen
Hydrolyzed by strong acid and base.
Reaktivität anzeigen
A chlorinated organophosphate derivative. Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. Chlorpyrifos-methyl is incompatible with strong acids and bases.
Health Hazard
Exposures to chlorpyrifos-methyl cause excessive salivation, sweating, rhinorrhea and tearing, muscle twitching, blurred vision/dark vision, slurred speech, weakness, tremor, incoordination, headache, dizziness, nausea, vomiting, abdominal cramps, diarrhea, respiratory depression, tightness in chest, wheezing, productive cough, fl uid in lungs, and pin-point pupils. In cases of severe exposure and poisoning, chlorpyrifos-methyl causes seizures, incontinence, respiratory depression, loss of consciousness, respiratory paralysis, and death. Exposures to chlorpyrifos-methyl cause cholinesterase inhibition in workers, and the systemic toxicity includes body weight loss, decreased food consumption, and liver, kidney, and adrenal pathology
Landwirtschaftliche Anwendung
Insecticide: Chlorpyrifos-methyl is used on stored grain (for protection of stored food, feed oil, and seed grains against injury from stored grain weevils, moths, borers, beetles and mealworms including granary weevil, rice weevil, red flour beetle, confused flour beetle, saw-toothed grain beetle, Indian meal moth, and Angoumois grain moth, lessor grain borers), seed treatment, grain bin and warehouse. [14] In 2000, the registrants of chlorpyrifos-methyl requested voluntary cancellation of their products rather than committing to develop additional data for reregistration
Handelsname
DOWCO-217®; NOLTRAN®; RELDAN®; RELDANE® , STORCIDE®; ZERTELL®
Sicherheitsprofil
Moderately toxic by ingestion, intraperitoneal, and skin contact routes. A skin irritant. Experimental reproductive effects. When heated to decomposition it emits very toxic fumes of Cl-, NOx POx and SOxA pesticide.
mögliche Exposition
Chlorpyrifos-methyl is a general use organophosphate insecticide for use on stored grain (for protection of stored food, feed oil, and seed grains against injury from stored grain weevils, moths, borers, beetles, and mealworms including granary weevil, rice weevil, red flour beetle, confused flour beetle, saw-toothed grain beetle, Indian meal moth, and Angoumois grain moth, lessor grain borers), seed treatment, grain bin, and warehouse.
Versand/Shipping
UN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
Inkompatibilitäten
Strong oxidizers, strong acids, and alkalies. In the presence of strong reducing agents such as hydrides, organophosphates form highly toxic and flammable phosphine gas. Contact with oxidizers can cause the release of toxic oxides of phosphorus. Corrosive to copper, brass, iron, and tin plate.
Waste disposal
This compound is 50% hydrolyzed in aqueous methanol solution @ pH 6 in 1930 days; and in 7.2 days at pH 9.96. Spray mixtures of <1% concentration are destroyed with an excess of 5.25% sodium hypochlorite in ,30 minutes @ 100°C; and in 24 hours @ 30°C. Concentrated (61.5%) mixtures are essentially destroyed by treatment with 100:1 volumes of the above sodium hypochlorite solution and steam in 10 minutes. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office
Vorsichtsmaßnahmen
Workplaces should have adequate washing facilities at all times during handling and these should be close to the site of handling. Eating, drinking, and smoking should be prohibited during handling and before washing after handling. Containers of chlorpyrifosmethyl should be kept away from foodstuffs, animal feed and their containers, and out of reach of children

Chlorpyrifos-methyl Upstream-Materialien And Downstream Produkte

Thiophosphorsäure-O,O-dimethyl-O-(3,5,6-trichlor-2-pyridinyl)ester Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

5598-13-0, Chlorpyrifos-methyl Verwandte Suche:

Send Inquriy