Schwefelhexafluorid

Gefahreninformationscode (GHS)

• Bildanzeige (GHS)

  

• Alarmwort

  Warnung

• Gefahrenhinweise

  H280：Enthält Gas unter Druck; kann bei Erwärmung explodieren.

• Sicherheit

  P410：Vor Sonnenbestrahlung schützen.

Sulfur hexafluoride Chemische Eigenschaften,Einsatz,Produktion Methoden

• ERSCHEINUNGSBILD

  GERUCHLOSES, FARBLOSES, KOMPRIMIERTES FLüSSIGGAS.

• PHYSIKALISCHE GEFAHREN

  Das Gas ist schwerer als Luft. Es kann sich in tiefer gelegenen Bereichen sammeln und den Luftsauerstoff verdrängen.

• CHEMISCHE GEFAHREN

  Zersetzung beim Erhitzen über 500°C unter Bildung giftiger und ätzender Rauche mit Schwefeloxiden und Fluorverbindungen.

• ARBEITSPLATZGRENZWERTE

  TLV: 1000 ppm (als TWA); (ACGIH 2005).
  MAK: 1000 ppm, 6100 mg/m? Spitzenbegrenzung: überschreitungsfaktor II(8); Schwangerschaft: Gruppe D (DFG 2006).
  

• AUFNAHMEWEGE

  Aufnahme in den Körper durch Inhalation.

• INHALATIONSGEFAHREN

  Eine gesundheitsschädliche Konzentration des Gases in der Luft wird beim Entweichen aus dem Behälter sehr schnell erreicht.

• WIRKUNGEN BEI KURZZEITEXPOSITION

  WIRKUNGEN BEI KURZZEITEXPOSITION:
  Schnelle Verdampfung kann zu Erfrierungen führen.

• LECKAGE

  Gefahrenbereich verlassen! Belüftung. Wasserstrahl NIEMALS auf die Flüssigkeit richten. Persönliche Schutzausrüstung: Chemikalienschutzanzug mit umgebungsluftunabhängigem Atemschutzgerät.

• R-Sätze Betriebsanweisung:

  R37:Reizt die Atmungsorgane.

• S-Sätze Betriebsanweisung:

  S38:Bei unzureichender Belüftung Atemschutzgerät anlegen.

• Beschreibung

  Sulfur hexafluoride is a colorless, odorless, nontoxic, nonflammable gas that has a high dielectric strength and serves widely as an insulating gas in electrical equipment. At atmospheric pressures it sublimes directly from the solid to the gas phase and does not have a stable liquid phase unless under a pressure of more than 32 psia (221 kPa, abs). It is shipped as a liquefied compressed gas at its vapor pressure of 298 psig at 70°F (2050 kPa at 21.1°C).
  One of the most chemically inert gases known, it is completely stable in the presence of most materials to temperatures of about 400°F (204°C) and has shown no breakdown or reaction in quartz at 900°F (482°C). Sulfur hexafluoride is slightly soluble in water and oil. No change in pH occurs when distilled water is saturated with sulfur hexafluoride.

• Chemische Eigenschaften

  Chemical properties of sulfur hexafluoride are very stable. And compared to selenium hexafluoride, the hydrolysis rate of sulfur hexafluoride is extremely low, this is due to the small radius sulfur atom, which resulting in six fluorine atoms form a larger steric hindrance around. However, the fluorine atom radius is not big, so the repulsive force between the six fluorine atoms is not too large, S-F bond is not easy to dissociate. Enthalpy of formation of sulfur hexafluoride is-1220 kJ/mol, but enthalpy of formation of sulfur hexafluoride is-74 kJ/mol. Thus, the radius of fluorine atom and sulfur atom radius cause the very stable of sulfur hexafluoride molecule together---the molecules themselves are difficult to disconnect bond and break down and the attack group is difficult to approach to the central atom, in the thermodynamics and kinetics, they are both stable. Studies have said sulfur hexafluoride can be stably present in the atmosphere for thousands of years.

• Physikalische Eigenschaften

  Colorless, odorless gas; density 6.41 g/L; about five times heavier than air; liquefies at -50.7°C (triple point); density of liquid 1.88 g/mL at -50.7°C; sublimes at -63.8°C; critical temperature 45.54°C; critical pressure 37.13 atm; critical volume 199 cm3/mol; slightly soluble in water; soluble in ethanol.

• Verwenden

  Sulfur hexafluoride is used extensively as a gaseous dielectric in various kinds of electrical power equipment, such as switchgear, transformers, condensers, and circuit breakers. It has also been used as a dielectric at microwave frequencies and as an insulating medium for the power supplies of high-voltage machines.
  Sulfur hexafluoride is also gaining use in nonelectrical applications, including blanketing of molten magnesium, leak detection, and plasma etching in the semiconductor industry. Sulfur hexafluoride also has some limited medical applications.

• Verwenden

  Dielectric for high-voltage equipment

• Verwenden

  Sulfur hexafluoride is used extensively as a gaseous dielectric in various kinds of electrical power equipment, such as switchgear, transformers, condensers, and circuit breakers. It has also been used as a dielectric at microwave frequencies and as an insulating medium for the power supplies of high-voltage machines.
  Sulfur hexafluoride is also gaining use in nonelectrical applications, including blanketing of molten magnesium, leak detection, and plasma etching in the semiconductor industry. Sulfur hexafluoride also has some limited medical applications.

• Definition

  ChEBI: Sulfur hexafluoride is a sulfur coordination entity consisting of six fluorine atoms attached to a central sulfur atom. It is the most potent greenhouse gas currently known, with a global warming potential of 23,900 times that of CO2 over a 100 year period (SF6 has an estimated lifetime in the atmosphere of between 800 and 3,000 years). It has a role as an ultrasound contrast agent and a member of greenhouse gas.

• synthetische

  Sulfur hexachloride may be prepared by reacting fluorine with sulfur or sulfur dioxide.

• Trademarks

  SonoVue (for the microbubble formulation) (Ausimont).

• Reaktivität anzeigen

  This substance undergoes chemical reactions only under relatively severe circumstances. They are resistant to ignition, although they may become flammable at very high temperatures. They may be resistant to oxidation reduction, except in the most severe conditions. These materials may be nontoxic. They can asphyxiate. Contact of very cold liquefied gas with water may result in vigorous or violent boiling of the product and extremely rapid vaporization due to the large temperature differences involved. If the water is hot, there is the possibility that a liquid "superheat" explosion may occur. Pressures may build to dangerous levels if liquid gas contacts water in a closed container [Handling Chemicals Safely 1980].

• Hazard

  Asphyxiant.

• Health Hazard

  Vapors may cause dizziness or asphyxiation without warning. Vapors from liquefied gas are initially heavier than air and spread along ground. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating, corrosive and/or toxic gases.

• Brandgefahr

  Some may burn but none ignite readily. Containers may explode when heated. Ruptured cylinders may rocket.

• Flammability and Explosibility

  Non flammable

• Materials Uses

  Sulfur hexafluoride is noncorrosive to all metals. It may be partially decomposed if subjected to an electrical discharge. Some of the breakdown products are corrosive; this corrosion is enhanced by the presence of moisture or at high temperature. Sulfur hexafluoride decomposes very slightly in the presence of certain metals at temperatures in excess of 400°F (204°C); this effect is most pronounced with silicon and carbon steels. Such breakdown, presumably catalyzed by the metals, is only several tenths of 1 percent over 1 year. Decomposition at elevated temperatures does not occur with aluminum, copper, brass, and silver.
  Most common gasket materials, including Teflon, neoprene, and natural rubber are suitable for sulfur hexafluoride service.

• Sicherheitsprofil

  This material is chemically inert in the pure state and is considered to be physiologcally inert as well. However, as it is ordinarily obtainable, it can contain variable quantities of the lowsulfur fluorides. Some of these are toxic, very reactive chemically, and corrosive in nature. These materials can hydrolyze on contact with water to yield hydrogen fluoride, which is highly toxic and very corrosive. In high concentrations and when pure it may act as a simple asphyxiant. Incompatible with disilane. Vigorous reaction with disilane. May explode. When heated to decomposition emits highly toxic fumes of Fand SOx.

• mögliche Exposition

  May contain highly toxic sulfur pentafluoride as an impurity. SF6 is used in various electric power applications as a gaseous dielectric or insulator. The most extensive use is in high-voltage transformers. SF6 is also used in waveguides, linear particle accelerators; Van de Graaff generators; chemically pumped continuous-wave lasers; transmission lines; and power distribution substations. Nonelectrical applications include use as a protective atmosphere for casting of magnesium alloys and use as a leak detector or in tracing moving air masses. Several sources note that vitreous substitution of SF6 in owl monkeys results in a greater ocular vascular permeability than that caused by saline. This implies that SF6 could have an important use in retinal surgery.

• Physiological effects

  Sulfur hexafluoride is completely nontoxic, and in fact has been used medically with humans in cases involving pneumoperitoneum, the introduction of gas into the abdominal cavity. It can act as a simple asphyxiant by displacing the amount of oxygen in the air necessary to support life.
  Lower fluorides of sulfur, some of which are toxic, may be produced if sulfur hexafluoride is subjected to electrical discharge. Personnel must guard against the inhalation of the gas after electrical discharge.
  ACGIH recommends a Threshold Limit Value-Time-Weighted Average (TLV-TWA) of 1000 ppm (5970 mg/m3) for sulfur hexafluoride. The TLV- TWA is the time-weighted average concentration for a normal 8-hour workday and a 40-hour workweek, to which nearly all workers may be repeatedly exposed, day after day, without adverse effect.
  OSHA lists an 8-hour Time-Weighted Average-Permissible Exposure Limit (TWA-PEL) of 1000 ppm (6000 mg/m3) for sulfur hexafluoride. TWA-PEL is the exposure limit that shall not be exceeded by the 8-hour TWAin any 8-hour work shift of a 40-hour workweek.

• Lager

  All ofthe precautions necessary for the handling of any nonflammable gas must be taken.

• Versand/Shipping

  UN1080 Sulfur hexafluoride, Hazard Class: 2.2; Labels: 2.2-Nonflammable compressed gas. Cylinders must be transported in a secure upright position, in a wellventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner.

• Inkompatibilitäten

  May contain impurities that cause it to hydrolyze on contact with water, forming corrosive and toxic hydrogen fluoride. Vigorous reaction with disilane.

• Waste disposal

  Return refillable compressed gas cylinders to supplier. Seal unused cylinders and return to suppliers.

• Chemische Eigenschaften

  Sulfur pentafluoride and sulfur tetrafluoride are classified by OSHA as highly hazardous chemicals under its Process Safety Management Standard and as toxic industrial chemicals on the basis of their highly toxic nature and production in large quantities (29 CFR 1910).

• GRADES AVAILABLE

  Sulfur hexafluoride is available for commercial and industrial use in various grades (minimum 99.8 mole percent) having much the same component proportions from one producer to another.

Sulfur hexafluoride Upstream-Materialien And Downstream Produkte

Schwefelhexafluorid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global(113)Suppliers

2551-62-4, Sulfur hexafluoride Verwandte Suche: