Cyclopentan

Gefahreninformationscode (GHS)

• Bildanzeige (GHS)

  

• Alarmwort

  Achtung

• Gefahrenhinweise

  H225：Flüssigkeit und Dampf leicht entzündbar.

  H412：Schädlich für Wasserorganismen, mit langfristiger Wirkung.

• Sicherheit

  P210：Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.

  P273：Freisetzung in die Umwelt vermeiden.

Cyclopentane Chemische Eigenschaften,Einsatz,Produktion Methoden

• ERSCHEINUNGSBILD

  FARBLOSE FLüSSIGKEIT.

• PHYSIKALISCHE GEFAHREN

  Die Dämpfe sind schwerer als Luft und können sich am Boden ausbreiten. Fernzündung möglich. Fließen, Schütten o.ä. kann zu elektrostatischer Aufladung führen.

• ARBEITSPLATZGRENZWERTE

  TLV: 600 ppm (als TWA); (ACGIH 2005).
  MAK nicht festgelegt (DFG 2005).
  

• AUFNAHMEWEGE

  Aufnahme in den Körper durch Inhalation der Dämpfe.

• INHALATIONSGEFAHREN

  Beim Verdampfen bei 20°C kann schnell eine gesundheitsschädliche Kontamination der Luft eintreten.

• WIRKUNGEN BEI KURZZEITEXPOSITION

  WIRKUNGEN BEI KURZZEITEXPOSITION:
  Substanz und Dampf reizen in hohen Konzentrationen die Augen und die Atemwege. Verschlucken kann zur Aufnahme in der Lunge führen; Gefahr der Aspirationspneumonie. Exposition weit oberhalb der Arbeitsplatzgrenzwerte kann zu Bewusstlosigkeit führen.

• WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION

  Wiederholter oder andauernder Hautkontakt kann Dermatitis hervorrufen.

• LECKAGE

  Gefahrenbereich verlassen! Fachmann zu Rate ziehen! Belüftung. Ausgelaufene Flüssigkeit möglichst in abdichtbaren Behältern sammeln. Reste mit Sand oder inertem Absorptionsmittel aufnehmen und an einen sicheren Ort bringen. NICHT in die Kanalisation spülen. Persönliche Schutzausrüstung: Umgebungsluftunabhängiges Atemschutzgerät.

• R-Sätze Betriebsanweisung:

  R11:Leichtentzündlich.
  R52/53:Schädlich für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.

• S-Sätze Betriebsanweisung:

  S9:Behälter an einem gut gelüfteten Ort aufbewahren.
  S16:Von Zündquellen fernhalten - Nicht rauchen.
  S29:Nicht in die Kanalisation gelangen lassen.
  S33:Maßnahmen gegen elektrostatische Aufladungen treffen.
  S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.

• Beschreibung

  Cyclopentane is a colorless liquid. Molecularweight=70.15; Specific gravity=(H2O:1)=0.75; Boilingpoint=49℃; Freezing/Melting point=2 93.6℃; Vaporpressure=400 mmHg at 31℃; Relative vapor density (air-5 1)=2.42: Flash point=37.2℃; Autoignitiontemperature=361℃. Explosive limits in air: LEL=1.1%;UEL=8.7%. Hazard Identification (based on NFPA-704 MRating System): Health 1, Flammability 3, Reactivity 0.Insoluble in water

• Chemische Eigenschaften

  Cyclopentane is a colourless flammable acyclic hydrocarbon liquid with a petrol-like smell. It is a widely used component in preparing products like analgesics, insecticides, sedatives, antitumor agents and also finds application in pharmaceutical industry.

• Physikalische Eigenschaften

  Colorless, mobile, flammable liquid with an odor resembling cyclohexane.

• Verwenden

  As a laboratory reagent; in the manufacture of pharmaceuticals; found in solvents and in petroleum ether; propellant pressurizing agent.

• Verwenden

  Cyclopentane is a petroleum product. Itis formed from high-temperature catalyticcracking of cyclohexane or by reduction ofcyclopentadiene. It occurs in petroleum etherfractions and in many commercial solvents.It is used as a solvent for paint, in extractionsof wax and fat, and in the shoe industry.

• Verwenden

  Cyclopentane is used as green blowing agent and involved in the production of polyurethane insulating foam, which is used in refrigerators, freezers, water heaters, construction panels, insulated pipes and roofs. As a lubricant, it finds applications in computer hard drives and outer space equipment due to its low volatile nature. It is widely useful in the preparation of resin, adhesives and pharmaceutical intermediate. It is an additive in gasoline. Since it is a halogen free compound and has zero-ozone depletion potential, it replaces the conventionally used chloro fluoro carbon (CFC) in refrigeration and thermal insulation.

• Definition

  ChEBI: A cycloalkane that consists of five carbons each bonded with two hydrogens above and below the plane. The parent of the class of cyclopentanes.

• Vorbereitung Methode

  Cyclopentane occurs in petroleum ether fractions and is prepared by cracking cyclohexane in the presence of alumina at high temperature and pressure or by reduction of cyclopentadiene.

• Allgemeine Beschreibung

  A clear colorless liquid with a petroleum-like odor. Flash point of -35°F. Less dense than water and insoluble in water. Vapors are heavier than air.

• Air & Water Reaktionen

  Highly flammable. Insoluble in water.

• Reaktivität anzeigen

  CYCLOPENTANE is incompatible with strong oxidizing agents such as chlorine, bromine, fluorine. .

• Health Hazard

  Cyclopentane is a low-acute toxicant. Itsexposure at high concentrations may producedepression of the central nervous system withsymptoms of excitability, loss of equilibrium,stupor, and coma. Respiratory failure may occur in rats from 30–60 minutes’ exposureto 100,000–120,000 ppm in air. It is anirritant to the upper respiratory tract, skin,and eyes. No information is available inthe literature on the chronic effects fromprolonged exposure to cyclopentane.

• Brandgefahr

  Behavior in Fire: Containers may explode.

• Flammability and Explosibility

  Highly flammable

• Chemische Reaktivität

  Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

• Sicherheitsprofil

  Mildly toxic by ingestion and inhalation. High concentrations have narcotic action. A very dangerous fire hazard when exposed to heat or flame; can react with oxidizers. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes.

• mögliche Exposition

  Cyclopentane is used as a solvent.

• Erste Hilfe

  If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get mediing resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Do not induce vomiting, guard against aspiration. Medical observation is recommended for 24-48 hafter breathing overexposure, as pulmonary edema may bedelayed. As first aid for pulmonary edema, a doctor orauthorized paramedic may consider administering a corticosteroid spray.

• Source

  Component of high octane gasoline (quoted, Verschueren, 1983). Harley et al. (2000) analyzed the headspace vapors of three grades of unleaded gasoline where ethanol was added to replace methyl tert-butyl ether. Cyclopentane was detected at an identical concentration of 1.4 wt % in the headspace vapors for regular, mid-, and premium grades.
  Schauer et al. (1999) reported cyclopentane in a diesel-powered medium-duty truck exhaust at an emission rate of 410 μg/km.
  California Phase II reformulated gasoline contained cyclopentane at a concentration of 4.11 g/kg. Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without catalytic converters were 0.78 and 85.4 mg/km, respectively (Schauer et al., 2002).

• Environmental Fate

  Biological. Cyclopentane may be oxidized by microbes to cyclopentanol, which may oxidize to cyclopentanone (Dugan, 1972).
  Photolytic. The following rate constants were reported for the reaction of octane and OH radicals in the atmosphere: 3.7 x 10^-12 cm³/molecule?sec at 300 K (Hendry and Kenley, 1979); 5.40 x 10^-12 cm³/molecule?sec (Atkinson, 1979); 4.83 x 10^-12 cm³/molecule?sec at 298 K (DeMore and Bayes, 1999); 6.20 x 10^-12, 5.24 x 10^-12, and 4.43 x 10^-12 cm³/molecule?sec at 298, 299, and 300 K, respectively (Atkinson, 1985), 5.16 x 10^-12 cm³/molecule?sec at 298 K (Atkinson, 1990), and 5.02 x 10^-12 cm³/mol·sec at 295 K (Droege and Tilly, 1987).
  Chemical/Physical. Cyclopentane will not hydrolyze because it has no hydrolyzable functional group. Complete combustion in air yields carbon dioxide and water.
  At elevated temperatures, rupture of the ring occurs forming ethylene and presumably allene and hydrogen (Rice and Murphy, 1942).

• Lager

  Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Prior to working with cyclopentane you should be trainedon its proper handling and storage. Before entering confinedspace where cyclopentane may be present, check to makesure that an explosive concentration does not exist. Store intightly closed containers in a cool well-ventilated area awayfrom strong oxidizers (such as chlorine, bromine, and fluorine). Use only nonsparking tools and equipment, especiallywhen opening and closing containers of cyclopentane.Metal containers involving the transfer of this chemicalshould be grounded and bonded. Where possible, automatically pump liquid from drums or other storage containers toprocess containers. Drums must be equipped with selfclosing valves, pressure vacuum bungs, and flame arresters.Use only nonsparking tools and equipment, especially whenopening and closing containers of this chemical. Sources ofignition, such as smoking and open flames, are prohibitedwhere this chemical is used, handled, or stored in a mannerthat could create a potential fire or explosion hazard.Wherever this chemical is used, handled, manufactured, orstored, use explosion-proof electrical equipment andfittings.

• Versand/Shipping

  UN1146 Cyclopentane, Hazard Class: 3; Labels: 3-Flammable liquid.

• läuterung methode

  Free it from cyclopentene by two passages through a column of carefully dried and degassed activated silica gel. It occurs in petroleum and is HIGHLY FLAMMABLE. [NMR: Christl Chem Ber 108 2781 1975, Whitesides et al. 41 2882 1976, Beilstein 5 III 10, 5 IV 4.]

• Inkompatibilitäten

  May form explosive mixture with air. May accumulate static electrical charges, and may cause ignition of its vapors. Contact with strong oxidizers may cause fire and explosion.

• Waste disposal

  Dissolve or mix the material with a combustible solvent and burn in a chemical incinera- tor equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Cyclopentane Upstream-Materialien And Downstream Produkte

Cyclopentan Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global(324)Suppliers

287-92-3, Cyclopentane Verwandte Suche: