2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin

Bezeichnung:2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin

CAS-Nr14098-44-3

Englisch Name:Benzo-15-crown-5

CBNumberCB5223772

SummenformelC14H20O5

Molgewicht268.31

MOL-Datei14098-44-3.mol

Synonyma

2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin

2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin physikalisch-chemischer Eigenschaften

Schmelzpunkt	78-80 °C (lit.)
Siedepunkt	371.47°C (rough estimate)
Dichte	1.1846 (rough estimate)
Brechungsindex	1.4825 (estimate)
storage temp.	Inert atmosphere,Room Temperature
Aggregatzustand	Powder or Flakes
Farbe	Almost white to light gray
Wasserlöslichkeit	partially soluble
Sensitive	Hygroscopic
BRN	1624106
InChI	InChI=1S/C14H20O5/c1-2-4-14-13(3-1)18-11-9-16-7-5-15-6-8-17-10-12-19-14/h1-4H,5-12H2
InChIKey	DSFHXKRFDFROER-UHFFFAOYSA-N
SMILES	O1C2=CC=CC=C2OCCOCCOCCOCC1
CAS Datenbank	14098-44-3(CAS DataBase Reference)
NIST chemische Informationen	Bis(1,4,7,10,13-benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-)(14098-44-3)

Sicherheit

Kennzeichnung gefährlicher	Xi
R-Sätze:	36/37/38
S-Sätze:	22-24/25-36-26
WGK Germany	3
RTECS-Nr.	DI5400000
F	3-10
Hazard Note	Irritant
HS Code	29329995

Gefahreninformationscode (GHS)

Benzo-15-crown-5 Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
ALMOST WHITE TO LIGHT GREY POWDER OR FLAKES
Verwenden
Benzo-15-crown-5 is used in synthetic chemistry. It plays a major role and involved in complexation through ether oxygen. It is used in phase-transfer catalyst system. It is involved in 'Host-Guest' chemistry to identify the move of essential elements in the body. It can play the part of very complicated biological reactions such as enzyme functions, which finds application in the development of new pharmaceuticals.
Application
Benzo-15-crown-5 can be used for sol-gel material extraction to separate lithium isotopes, for making static detection sensors for formic acid gases, and as metal ion complexing agent and phase transfer reagent.
synthetische
synthesis of Benzo-15-crown-5: benzo-15-crown-5 can be produced using Williamson synthesis reaction, featured by interaction between catechol (orto-dihydroxybenzene) and tetraethylene glycol dichloride (1,10-dichloro-3,6,9-trioxadecane) over sodium hydroxide in the n-butanol media (30-h inertatmosphere boiling). The yield of benzo-15-crown-5 produced by this method is 62%, with the basic substance's mass fraction of 95%.
Production of Macrocyclic Polyether Benzo-15-Crown-5 and its Functional Derivatives
Definition
ChEBI: Benzo-15-crown-5 is a crown ether that is 15-crown-5 ortho-fused to a benzene ring.

Benzo-15-crown-5 Upstream-Materialien And Downstream Produkte

2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

14098-44-3, Benzo-15-crown-5 Verwandte Suche:

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