Tetramethylammoniumhydroxid

Bezeichnung:Tetramethylammoniumhydroxid

CAS-Nr75-59-2

Englisch Name:Tetramethylammonium hydroxide

CBNumberCB2854236

SummenformelC4H13NO

Molgewicht91.15

MOL-Datei75-59-2.mol

Synonyma

Tetramethylammoniumhydroxid

Tetramethylammoniumhydroxid physikalisch-chemischer Eigenschaften

Schmelzpunkt	°C
Siedepunkt	110 °C
Dichte	0.866 g/mL at 25 °C
Dampfdruck	17.5 mm Hg ( 20 °C)
Brechungsindex	n20/D 1.384
Flammpunkt	80 °F
storage temp.	Store below +30°C.
Löslichkeit	Methanol (Sparingly), Water (Slightly)
Aggregatzustand	Solution
Farbe	APHA: ≤10
Geruch (Odor)	strong ammonia-like odor
PH	>13 (H2O, 20°C)
Wasserlöslichkeit	Soluble in water.
Sensitive	Air Sensitive
Merck	14,9224
BRN	3558708
Henry's Law Constant	2.3×10¹⁰ mol/(m³Pa) at 25℃, HSDB (2015)
Stabilität	Stable. Flammable. Incompatible with strong oxidizing agents, strong acids.
InChI	1S/C4H12N.H2O/c1-5(2,3)4;/h1-4H3;1H2/q+1;/p-1
InChIKey	WGTYBPLFGIVFAS-UHFFFAOYSA-M
SMILES	[OH-].C[N+](C)(C)C
CAS Datenbank	75-59-2(CAS DataBase Reference)
EPA chemische Informationen	Tetramethylammonium hydroxide (75-59-2)

Sicherheit

Kennzeichnung gefährlicher	C,T,F,T+,Xn
R-Sätze:	24/25-34-20/21/22-39/23/24/25-23/24/25-10-21/22-25-21-11-67-36-52-48/24-27/28-23-35-36/38
S-Sätze:	45-36/37/39-26-16-36/37-28
RIDADR	UN 1835 8/PG II (TETRAMETHYLAMMONIUM HYDROXIDE AQUEOUS SOLUTION with more than 2.5 % but less than 25 % tetramethylammonium hydroxide)
RIDADR	UN 1835 8/PG III (TETRAMETHYLAMMONIUM HYDROXIDE AQUEOUS SOLUTION with not more than 2.5 % tetramethylammonium hydroxide)
RIDADR	UN 3423 6.1/PG I (TETRAMETHYLAMMONIUM HYDROXIDE, SOLID)
WGK Germany	1
RTECS-Nr.	PA0875000
F	4.4-10-34
TSCA	TSCA listed
HazardClass	3
PackingGroup	II
HS Code	29239000
Speicherklasse	3 - Flammable liquids
Hazard Classifications	Acute Tox. 2 Dermal Acute Tox. 2 Oral Acute Tox. 3 Inhalation Aquatic Chronic 3 Eye Dam. 1 Flam. Liq. 3 Skin Corr. 1B STOT RE 1 Dermal STOT SE 1
Giftige Stoffe Daten	75-59-2(Hazardous Substances Data)

Gefahreninformationscode (GHS)

Tetramethylammonium hydroxide Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R24/25:Giftig bei Berührung mit der Haut und beim Verschlucken.
R34:Verursacht Verätzungen.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R39/23/24/25:Giftig: ernste Gefahr irreversiblen Schadens durch Einatmen, Berührung mit der Haut und durch Verschlucken.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
R10:Entzündlich.
R21/22:Gesundheitsschädlich bei Berührung mit der Haut und beim Verschlucken.
R25:Giftig beim Verschlucken.
R21:Gesundheitsschädlich bei Berührung mit der Haut.
R11:Leichtentzündlich.
R67:Dämpfe können Schläfrigkeit und Benommenheit verursachen.
R36:Reizt die Augen.
S-Sätze Betriebsanweisung:
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S16:Von Zündquellen fernhalten - Nicht rauchen.
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
Beschreibung
Tetramethylammonium hydroxide is a solid in the hydrated form or a colorless liquid with a strong ammonia-like odor. It is soluble in water, and corrosive to metals and tissue.
Chemische Eigenschaften
colourless to yellow liquid
Verwenden
Tetramethylammonium hydroxide is used to produce tetramethyl-ammonium azide. It is used as an anisotropic etchant of silicon, basic solvent in the development of acidic photoresist in photolithography process, as surfactant in the synthesis of ferrofluid and as a polarographic reagent. It finds application in the production of organic silicon, where it is used for computer silicon wafer surface brightener and cleaning agent. It is also involved in the purification of some metallic elements.
Tetramethylammonium hydroxide solution (25 wt.% solution in water) may be used as a base for pH adjustment to obtain hexagonal mesoporous aluminophosphate (TAP).
Verwenden

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Industry

Application

Role/benefit

Organic silicon

Production of dimethyl silicone oil, organic silicon resin, silicon rubber, etc.

Catalyst/removed easily; no pollution to the products

Chemical analysis

Polarography experiment

Polarographic reagent

Thermochemolysis to study fungal degradation of wood

Analytical reagent

Chemical purification

Removal of metal elements

Ash free alkali/source of base; make the metal elements precipitated

Electron

Production of computer silicon chip

Brightening agent; anisotropic etching agent; cleaning agent; photoresist developer

Printing of circuit board

Cleaning agent

Semiconductor manufacturing

Chemical stripper

Others

Synthesis of ferrofluid

Surfactant/ inhibit nanoparticle aggregation

Synthesis of zeolite

Structure directing agent
Allgemeine Beschreibung
Tetramethylammonium hydroxide is a quaternary ammonium salt generally used as an anisotropic etchant for silicon due to its high silicon etching rate.
Reaktivität anzeigen
Tetramethylammonium hydroxide acts like a base. Bases are chemically similar to sodium hydroxide (NaOH) or sodium oxide (Na2O). They neutralize acids exothermically to form salts plus water. When soluble in water they give solutions having a pH greater than 7.0. Mixing these materials with water can generate troublesome amounts of heat as the base is dissolved or diluted. Bases react with certain metals (such as aluminum and zinc) to form oxides or hydroxides of the metal and generate gaseous hydrogen. Bases may initiate polymerization reactions in polymerizable organic compounds, especially epoxides). They may generate flammable and/or toxic gases with ammonium salts, nitrides, halogenated organics, various metals, peroxides, and hydroperoxides. Materials of this group often serve as catalysts.
Health Hazard
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Brandgefahr
Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
reaction suitability
reaction type: Acid-base reactions
reaction type: Redox Reactions
Sicherheitsprofil
Poison by subcutaneous route. A powerful caustic. A corrosive irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of NOx and NH3.
läuterung methode
It is freed from chloride ions by passage through an ion-exchange column (e.g. Amberlite IRA-400, prepared in its OH-form by passing 2M NaOH until the effluent is free from chloride ions, then washed with distilled H2O until neutral). A modification, to obtain carbonate-free hydroxide, uses the method of Davies and Nancollas [Nature 165 237 1950]. [Beilstein 4 IV 145.]
Einzelnachweise
1.https://en.wikipedia.org/wiki/Tetramethylammonium_hydroxide#Uses
2.http://sacheminc.com/other-chemicals/tetramethylammonium-hydroxide-tmah/
3.https://www.fs.usda.gov/treesearch/pubs/15506
4.https://www.concordia.ca/content/dam/concordia/services/safety/docs/EHS-DOC-020_TMAHGuidelines.pdf
5.https://www.chemicalbook.com/ChemicalProductProperty_EN_CB2854236.htm

Tetramethylammonium hydroxide Upstream-Materialien And Downstream Produkte

Tetramethylammoniumhydroxid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

75-59-2, Tetramethylammonium hydroxide Verwandte Suche:

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