6358-69-6
基本信息
8-羟基芘-1,3,6-三磺酸三钠盐
溶剂绿 7
8-羟基-1,3,6-芘三磺酸三钠
8-羟基-1,3,6-三磺酸芘
溶剂绿7
甲氧基苄腈
8-羟基-1,3,6-芘三磺酸三钠盐
VERAPAMIL INTERMEDIATES
绿 8 [CI 59040]
溶剂绿 7 [CI 59040]
溶剂绿 8
C.I.溶剂绿7
透明绿B
3,4-DIMETHOXYBENZYL CYANIDE
3,4-DIMETHOXYPHENYLACETONITIRLE
3,4-DIMETHOXYPHENYLACETONITRILE
3,4-DIMETHYLOXYPHENYLACETONITRILE
3,4-DIMETHYLOXY PHENYLACETONOTRILE
8-HYDROXY-1,3,6-PYRENETRISULFONIC ACID TRISODIUM SALT
8-HYDROXYPYRENE-1,3,6-TRISULFONIC ACID, TRISODIUM SALT
CI 59040
CYANOMETHYL-3,4-DIMETHOXYBENZENE
D AND C GREEN NO 8
HOMOVERATRONITRIL
HOMOVERATRONITRILE
HPTS
HPTS TRISODIUM SALT
LABOTEST-BB LT00159917
PYRANINE
PYRANINE 108
PYRANINE GREEN
PYRANINE, TRISODIUM SALT
物理化学性质
| 熔点 | 62-63.5 °C(lit.) |
| 沸点 | 171-178 °C10 mm Hg(lit.) |
| 密度 | 2.15 |
| 蒸气压 | 0Pa at 25℃ |
| 闪点 | 250 °C |
| 储存条件 | Keep in dark place,Inert atmosphere,Room temperature |
| 溶解度 | methanol: 0.1 g/mL, clear |
| 色指数 | 59040 |
| 酸度系数(pKa) | 7.3, (at 22℃) |
| 形态 | 粉末 |
| 颜色 | yellow |
| 水溶解性 | 300 g/L (25 ºC) |
| 最大波长(λmax) | 403 nm (Buffer pH 4.0); 454 nm (Buffer pH 9.0) |
| Merck | 7954 |
| BRN | 4107272 |
| 生物领域应用 | Antiperspirants; bath preparations; cleansing products; cosmetics; contact lens; hair dyes; hygiene products/soaps; food products; controlled-release system for proteins; drug delivery; in ophthalmology/retinal surgery; sugar sensors (glucose, fructose, lactose, sucrose); as a substrate for measuring acetylcholinesterase (AChE) activity, carbonic anhydrase activity, esterases activity, β-glucuronidase activity, lipase activity, acidic/alkaline phosphatases activity, pyrophosphatase activity, sucrose phosphorylase (SPO) activity, phosphoglucomutase (PGM) activity; treating cancer, infection, immune/autoimmune disease, mastitis, tonsillitis, tuberculosis |
| 主要应用 | Adhesives; agrochemicals; ammonia sensor; carbon dioxide sensor; oxygen sensor; anionic surfactants sensor; measuring the size of the organoclay aggregates; detecting cracks/flaws in metallic surfaces, refrigerant leaking; detergents; correction fluid; highlighters; inks; markers; paints; pencils; toners; chemically amplified resist; color filters; chemiluminescent materials; electrophoretic display (EPD) film materials; electroluminescent displays/materials; fuel cell; lasers; liquid crystal displays; luminescent materials; nanoparticles; papers; photoresist processes; photonic ionic liquids; soils; solar cell; sol–gel materials/processes/thin films; sonophotoluminescence; water tracers; evaluating liquid water flow in wood during drying |
| LogP | -3.97 at 25℃ |
| CAS 数据库 | 6358-69-6(CAS DataBase Reference) |
| EPA化学物质信息 | C.I. Solvent Green 7 (6358-69-6) |
安全数据
| 危险性符号(GHS) |  GHS07 |
| 警示词 | 警告 |
| 危险性描述 | H315-H319-H335 |
| 防范说明 | P261-P305+P351+P338-P280a-P304+P340-P405-P501a |
| 危险品标志 | Xn,Xi |
| 危险类别码 | R36/37/38 |
| 安全说明 | S36/37-S37/39-S26-S36 |
| WGK Germany | 3 |
| RTECS号 | UR2700000 |
| TSCA | Yes |
| 海关编码 | 29089990 |
应用领域
制备方法
59572-10-0
6358-69-6
以1,3,6,8-芘四磺酸四钠盐为原料合成溶剂绿7的一般步骤如下：在2000毫升三颈烧瓶中加入1200克浓硫酸，搅拌下加入120克1,3,6,8-芘四磺酸四钠盐，轻微加热以促进完全溶解后，缓慢升温至90°C并维持1小时。反应完成后，用水浴将反应混合物冷却至40°C以下，缓慢滴加480克液体硫磺黑，滴加过程控制在3小时内完成。随后，将反应温度维持在100°C左右继续反应5小时。反应结束后，冷却至室温，将反应混合物倒入720克冰水中，得到粘稠物料，经过滤后干燥滤饼，得到芘四磺酸四钠盐。接下来，将芘四磺酸四钠盐溶于1000毫升水中，转移至2000毫升三口烧瓶中，用氢氧化钠溶液调节至中性，再加入300克片状氢氧化钠。缓慢加热至微沸状态，保持5小时。反应完成后，冷却，先用盐酸调节pH值至7左右，然后加入100克氯化钠搅拌至完全溶解，缓慢沉淀出淡黄色固体。经过滤、干燥，最终得到约245克8-羟基-1,3,6-芘三钠磺酸盐。
参考文献：
[1] Patent: CN105272886, 2016, A. Location in patent: Paragraph 0013; 0026; 0027
常见问题列表
Pyranine is capable of discriminating ranges of cations from the Cu
+
ion, even in competing environment. Pyranine displays a rapid fluorescence response (t
1/2
=1.66 min) towards the Cu
+
ion, and the micromolar detection limit enables the detection of the ion in environmental samples. The observed stoichiometry of complexation between Pyranine and Cu
+
is 2:1.
The pH-sensitive fluorescent indicator Pyranine is studied to determine its usefulness as probes for the living cornea and anterior chamber. Adequate concentrations are reached in the cornea and anterior chamber after topical administration; measurements can be made by fluorophotometry for many hours. The pH is calculated by measuring the ratio of fluorescent intensity at two excitation wavelengths, I463/I404, a measurement which is dependent on pH but independent of the concentration of the fluorophore and other variables which can alter the intensity. In the rabbit eye, Pyranine in the cornea and anterior chamber is observed to undergo easily measurable changes in fluorescent ratios associated with lid closure and contact lens wear, indicating its sensitivity to mild changes in pH.
知名试剂公司产品信息
8-Hydroxy-1,3,6-pyrenetrisulfonic acid trisodium salt, pure, 98%(6358-69-6) Acros Organics
Pyranine(6358-69-6) Alfa Aesar
Pyranine,>85.0%(E)(6358-69-6) TCI Shanghai
溶剂绿 7价格(试剂级)
| 报价日期 | 产品编号 | 产品名称 | CAS号 | 包装 | 价格 |
| 2025/09/19 | L11252 | 荧光黄 Pyranine | 6358-69-6 | 25g | 1796元 |
| 2025/09/19 | 41218 | 荧光黄 8-Hydroxy-1,3,6-pyrenetrisulfonic acid trisodium salt, 98% | 6358-69-6 | 1g | 1461元 |
| 2025/05/22 | L11252 | 荧光黄 Pyranine | 6358-69-6 | 5g | 713元 |