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GHS--化学品安全信息

GHS标签

GHS是什么?

GHS是一个简称,全称是Globally Harmonized System of Classification and Labeling of Chemicals,中文名称是《全球化学品统一分类和标签制度》。目的是指导各国建立统一化学品分类和标签规范,在2003年由联合国发布第一版。

GHS包含两大部分数据:危险性说明和防范说明

GHS标签有6个基本信息,如图所示。GHS标签6要素
1. 产品标识符 - 产品名称及其CAS号
2. 信号词 -"警告"或"危险"
3. GHS 象形图 - 以直观方式描述化学品危险的符号,一共有9种
4. 危险说明 (H标签) - 简要的说明和描述产品可能发生的危害,有单独的标签或是组合标签
5. 防范说明 (P标签) - 提前告知使用者如何避免或防止产品对人或环境产生危害,以及发生危险后的处理方式。有单独的或组合标签
6. 供应商信息 - 制造商或其他供应商的名称、地址和电话
GHS标签上也可以添加供应商补充信息。

GHS危险性说明

GHS危险性说明一共包含三方面,分别是:物理危害(H2**)、健康危害(H3**)、环境危害(H4**)。

物理危害

H200 不稳定爆炸品。 Unstable explosives
H201 爆炸品;大规模爆炸危险。 Explosive; mass explosion hazard
H202 爆炸品;严重喷射危险。 Explosive, severe projection hazard
H203 爆炸品;火灾、爆炸或喷射危险。 Explosive; fire, blast or projection hazard
H204 火灾或喷射危险。 Fire or projection hazard
H205 火中可能会造成大规模爆炸。 May mass explode in fire
H220 极易燃气体。 Extremely flammable gas
H221 易燃气体。 Flammable gas
H222 极易燃气雾剂 Extremely flammable aerosol
H223 易燃气雾剂 Flammable aerosol
H224 极端易燃液体和蒸气 Extremely flammable liquid and vapour
H225 高度易燃液体和蒸气 Highly flammable liquid and vapour
H226 易燃液体和蒸气 Flammable liquid and vapour
H227 可燃液体 Combustible liquid
H228 易燃固体 Flammable solid
H240 加热可能会引起爆炸 Heating may cause an explosion
H241 加热可能会引起火灾或爆炸 Heating may cause a fire or explosion
H242 加热可能会引起火灾 Heating may cause a fire
H250 暴露于空气自发着火 Catches fire spontaneously if exposed to air
H251 自我放热:可能着火 Self-heating: may catch fire
H252 自我释放大量的热;可能着火。 Self-heating in large quantities; may catch fire
H260 与水接触时释放可燃气体,可自燃。 In contact with water releases flammable gases which may ignite spontaneously
H261 与水接触时释放可燃气体。 In contact with water releases flammable gas
H270 可能导致或加剧燃烧;氧化剂。 May cause or intensify fire; oxidizer
H271 可能会引起火宅或爆炸;强氧化剂。 May cause fire or explosion; strong oxidizer
H272 可能加剧火势;氧化剂。 May intensify fire; oxidizer
H280 内含高压气体,遇热可能爆炸。 Contains gas under pressure; may explode if heated
H281 内含冷冻气体,可能导致低温灼伤或损伤。 Contains refrigerated gas; may cause cryogenic burns or injury
H290 可能腐蚀金属。 May be corrosive to metals
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健康危害

H300 吞咽致命。  Fatal if swallowed
H301 吞咽会中毒  Toxic if swallowed
H302 吞咽有害  Harmful if swallowed
H303 吞咽可能有害  May be harmful if swallowed
H304 吞咽并进入呼吸道可能致命  May be fatal if swallowed and enters airways
H305 吞咽并进入呼吸道可能有害  May be harmful if swallowed and enters airways
H310 与皮肤接触致命  Fatal in contact with skin
H311 皮肤接触会中毒  Toxic in contact with skin
H312 与皮肤接触有害  Harmful in contact with skin
H313 接触皮肤可能有害  May be harmful in contact with skin
H314 造成严重的皮肤灼伤和眼睛损伤  Causes severe skin burns and eye damage
H315 引起皮肤刺激  Causes skin irritation
H316 引起轻度皮肤刺激  Causes mild skin irritation
H317 可能引起过敏性皮肤反应  May cause an allergic skin reaction
H318 造成严重眼损伤  Causes serious eye damage
H319 造成严重的眼睛刺激  Causes serious eye irritation
H320 引起眼睛刺激  Causes eye irritation
H330 吸入致死  Fatal if inhaled
H331 吸入会中毒  Toxic if inhaled
H332 吸入有害  Harmful if inhaled
H333 吸入可能有害  May be harmful if inhaled
H334 吸入可能导致过敏或哮喘症状或呼吸困难  May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 可能引起呼吸道刺激  May cause respiratory irritation
H336 可能引起嗜睡或头晕  May cause drowsiness or dizziness
H340 可能导致遗传缺陷  May cause genetic defects
H341 怀疑导致遗传缺陷  Suspected of causing genetic defects
H350 可能导致癌症  May cause cancer
H351 怀疑致癌  Suspected of causing cancer
H360 可能会损害生育能力或未出生的孩子  May damage fertility or the unborn child
H361 怀疑造成对生育能力或未出生的孩子的伤害  Suspected of damaging fertility or the unborn child
H361d 怀疑对未出生的孩子造成伤害  Suspected of damaging the unborn child
H361e 可能会伤害未出生的孩子  May harm unborn children
H361f 怀疑生育能力受损 Suspected of impaired Fertility
H361g 可能会损害生育能力 May impair Fertility
H362 可能对母乳喂养的儿童造成伤害 May cause harm to breast-fed children
H370 对器官造成伤害 Causes damage to organs
H371 可能对器官造成伤害  May cause damage to organs
H372 长期或反复接触会对器官造成伤害  Causes damage to organs through prolonged or repeated exposure
H373 长期或反复接触可能对器官造成伤害  May cause damage to organs through prolonged or repeated exposure
H300 + H310 吞咽或接触皮肤致命 Fatal if swallowed or in contact with skin
H300 + H330 吞咽或吸入致死 Swallowing or inhaling to death
H310 + H330 皮肤接触或吸入致死 Death from skin contact or inhalation
H300 + H310 + H330 吞咽,皮肤接触或吸入致死 Swallowing, skin contact or inhalation to death
H301 + H311 吞咽或皮肤接触会中毒 Poisoning if swallowed or in contact with skin
H301 + H331 吞咽或吸入会中毒 Poisoning if swallowed or inhaled
H311 + H331 皮肤接触或吸入会中毒 Skin contact or inhalation can cause poisoning
H301 + H311 + H331 吞咽,皮肤接触或吸入会中毒 Swallowing, skin contact or inhalation can cause poisoning
H302 + H312 吞咽或接触皮肤有害 Harmful if swallowed or in contact with skin
H302 + H332 吞咽或吸入有害 Harmful if swallowed or inhaled
H312 + H332 皮肤接触或吸入有害 Harmful in skin contact or inhalation
H302 + H312 + H332 吞咽,皮肤接触或吸入有害 Harmful if swallowed, in contact with skin or inhaled
H303 + H313 吞咽或接触皮肤可能有害 May be harmful if swallowed or in contact with skin
H303 + H333 吞咽或吸入可能有害 May be harmful if swallowed or inhaled
H313 + H333 接触皮肤或吸入可能有害 May be harmful in contact with skin or inhalation
H303 + H313 + H333 吞咽,皮肤接触或吸入可能有害 Swallowing, skin contact or inhalation may be harmful
H315 + H320 引起皮肤和眼睛刺激 Cause skin and eye irritation
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环境危害

H400 对水生生物毒性非常大。 Very toxic to aquatic organisms.
H401 对水生生物有毒。 Toxic to aquatic organisms
H402 对水生生物有害。 Harmful to aquatic organisms.
H410 对水生生物毒性非常大并具有长期影响。 Very toxic to aquatic organisms and has long-term effects.
H411 对水生生物有毒性并具有长期影响。 Toxic to aquatic organisms and has long-term effects.
H412 对水生生物有害并具有长期影响。 Harmful to aquatic organisms and has long-term effects.
H413 可能对水生生物造成长期持续有害影响。 May cause long-term and sustained harmful effects on aquatic organisms.
H420 通过破坏上层大气臭氧层而危害公众健康和环境。 Harming public health and the environment by destroying the upper atmospheric ozone layer
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GHS防范说明

GHS防范说明一共包含五方面,分别是:普通防范说明(P1**)、预防防范说明(P2**)、回应防范说明(P3**)、存储防范说明(P4**)和处理防范说明(P5**)。

普通防范说明

P101 如果你想要医药方面的建议,记得随手带上药瓶和标签 If medical advice is needed,have product container or label at hand.
P102 请将此药品放在儿童不能接触的地方。 Keep out of reach of children.
P103 使用前阅读标签 Read label before use.

预防防范说明

P201 使用前获取专门指示。 Obtain special instructions before use.
P202 已阅读并理解所有的安全预防措施之前,切勿操作。 Do not handle until all safety precautions have been read and understood.
P210 远离热源/火花/明火/热的表面。——禁止吸烟。 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P211 不要喷洒在明火或其他点火源。 Do not spray on an open flame or other ignition source. 
P220 保持远离/贮存远离服装/....../可燃材料。 Keep/Store away from clothing/…/combustible materials.
P221 采取一切防范措施,避免与可燃物混合/... Take any precaution to avoid mixing with combustibles/…
P222 不要与空气接触。 Do not allow contact with air.
P223 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230 保持湿润 Keep wetted with …
P231 在惰性气体中操作。 Handle under inert gas.
P232 防止受潮。 Protect from moisture.
P233  保持容器密闭。 Keep container tightly closed.
P234 只保留在原来的容器中。 Keep only in original container.
P235 保持凉爽。 Keep cool.
P240 与地面接触/连接集装箱和接受设备。 Ground/bond container and receiving equipment.
P241 使用防爆电气/通风/照明/ .../设备。 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 只能使用无火花工具。 Use only non-sparking tools.
P243 采取预防措施,防止静电放电。 Take precautionary measures against static discharge.
P244 保持减压阀无油,无油脂。 Keep reduction valves free from grease and oil. 
P250 不要受研磨/冲击/....../摩擦。 Do not subject to grinding/shock/…/friction.
P251 压力容器:不要刺破或焚烧,即使在使用后。 Pressurized container: Do not pierce or burn, even after use.
P260 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 不要接触眼睛,皮肤或衣服。 Do not get in eyes, on skin, or on clothing.
P263 怀孕/哺乳期间避免接触。 Avoid contact during pregnancy/while nursing.
P264 处理后要彻底洗净双手。 Wash hands thoroughly after handling.
P264 处理要彻底洗净皮肤。 Wash skin thouroughly after handling.
P270 使用本产品时不要吃东西,喝水或吸烟。 Do not eat, drink or smoke when using this product.
P271 只能在室外或通风良好的地方使用。 Use only outdoors or in a well-ventilated area. 
P272 污染的工作服不得带出工作场所。 Contaminated work clothing should not be allowed out of the workplace.
P273 避免释放到环境中。 Avoid release to the environment.
P280 戴防护手套/防护服/眼睛的保护物/面部保护物。 Wear protective gloves/protective clothing/eye protection/face protection.
P281 使用所需的个人防护装备。 Use personal protective equipment as required.
P282 戴防寒手套/面罩/眼睛保护装备。 Wear cold insulating gloves/face shield/eye protection.
P283 穿防火/阻燃/耐阻燃服。 Wear fire/flame resistant/retardant clothing.
P284 佩戴呼吸保护装置。 Wear respiratory protection. 
P285 在通风不足的情况下,戴呼吸防护。 In case of inadequate ventilation wear respiratory protection.
P231+P232 在惰性气体中。防止受潮。 Handle under inert gas. Protect from moisture.
P235+P410 保持冷静。避免阳光直射。 Keep cool. Protect from sunlight.
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回应防范说明

P301 如果吞下去 IF SWALLOWED:
P304 如果吸入 IF INHALED:
P305 如果进入眼睛 IF IN EYES:
P306 如果在衣服上 IF ON CLOTHING:
P307 如果接触 IF exposed:
P308 如果接触或涉及 IF exposed or concerned:
P309 如果接触或如果感到不适 IF exposed or if you feel unwell:
P310 立即呼救解毒中心或医生/医师。 Immediately call a POISON CENTER or doctor/physician.
P311 呼叫解毒中心或医生/医师。 Call a POISON CENTER or doctor/physician.
P312 如果你感觉不适,呼叫解毒中心或医生/医师。 Call a POISON CENTER or doctor/physician if you feel unwell.
P313 获取医疗咨询/就医 Get medical advice/attention.
P314 获取医疗咨询/就医,如果你觉得不舒服 Get medical advice/attention if you feel unwell.
P315 获取医疗咨询/就医 Get immediate medical advice/attention.
P320 紧急具体治疗(见本标签上的)。 Specific treatment is urgent (see … on this label).
P321 具体治疗(见本标签上的)。 Specific treatment (see … on this label).
P322 具体治疗(见本标签上的)。 Specific measures (see …on this label).
P330 漱口 Rinse mouth.
P331 不要催吐。 Do NOT induce vomiting..
P332 如果发生皮肤刺激: IF SKIN irritation occurs:
P333 如果发生皮肤刺激或皮疹: If skin irritation or rash occurs:
P334 浸入冷水中/湿绷带包裹。 Immerse in cool water/wrap n wet bandages.
P335 刷掉皮肤松散颗粒。 Brush off loose particles from skin.
P336 解冻冻住的部位,用温水洗净。不要擦患处。 Thaw frosted parts with lukewarm water. Do not rub affected area.
P337 如果眼睛刺激持续 If eye irritation persists:
P338 如果戴隐形眼睛并容易摘掉的话,取出隐形眼镜,继续冲洗。 Remove contact lenses, if present and easy to do. Continue rinsing.
P340 将患者转移到空气清新,并保持在一个适合呼吸的姿势休息。 Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341 如果出现呼吸困难,将患者转移到空气清新,并保持在一个适合呼吸的姿势休息。 If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342 如果出现呼吸症状: If experiencing respiratory symptoms:
P350 轻轻地用大量肥皂和水 Gently wash with plenty of soap and water.
P351 小心地用水冲洗几分钟。 Rinse cautiously with water for several minutes.
P352 用大量肥皂和水清洗。 Wash with plenty of soap and water.
P353 水洗/淋浴冲洗皮肤 Rinse skin with water/shower.
P360 立即冲洗污染的衣着,用大量水冲洗皮肤,然后脱掉衣服。 Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361 立即去除/脱掉所有被污染的衣服。 Remove/Take off immediately all contaminated clothing.
P362 脱掉污染的衣服,清洗后方可重新使用 Take off contaminated clothing and wash before reuse.
P363 被污染的衣服洗净后方可重新使用。 Wash contaminated clothing before reuse.
P370 在发生火灾的情况下: In case of fire:
P371 在重大火灾和大量的情况下: In case of major fire and large quantities:
P372 在火中有灾爆炸的危险。 Explosion risk in case of fire.
P373 火烧到爆炸物时,切勿救火。 DO NOT fight fire when fire reaches explosives.
P374 在合适的距离采取正常安全预防措施灭火。 Fight fire with normal precautions from a reasonable distance.
P376 如果安全的话使泄露停止。氧化性气体。 Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377 漏气着火:切勿灭火,除非漏气能够被安全地制止。 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378 使用...灭火。 Use … for extinction.
P380 疏散该地区。 Evacuate area.
P381 如果安全的话,消除所有点火源。 Eliminate all ignition sources if safe to do so.
P390 吸收溢出物,防止重大损害。 Absorb spillage to prevent material damage.
P391 收集对水环境有危害的泄漏物。 Collect spillage. Hazardous to the aquatic environment
P301+P310 如果食入:立即呼叫中毒控制中心或医生/医师。 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301+P312 如果吞下去了:如果你觉得不适,呼叫解毒中心或医生/医师。 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301+P330+P331 如果吞咽:漱口。不要催吐。 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P334 如果皮肤沾染:浸入冷水中/用湿绷带包扎 IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302+P350 如果在皮肤上:轻轻地用大量肥皂和水清洗 IF ON SKIN: Gently wash with plenty of soap and water.
P302+P352 如皮肤接触:用大量肥皂和水清洗。 IF ON SKIN: wash with plenty of soap and water.
P303+P361+P353 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P312 如果吸入:如果你感觉不适,呼叫解毒中心或医生/医师。 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304+P340 如果吸入:转移到空气新鲜处,休息,保持一个适合呼吸的姿势。 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304+P341 如果吸入:如呼吸困难,将受害人转移到空气新鲜处,保持一个适合呼吸的姿势休息。 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338 如接触到眼睛小心地用水冲洗眼睛数分钟 IF IN EYES: Rinse cautiously with water for several minutes.
P306+P360 如果沾在衣服上:立即将被污染的衣服和皮肤用大量的水冲洗,然后脱掉衣服。 IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307+P311 如果接触:呼叫解毒中心或医生/医师。 IF exposed: call a POISON CENTER or doctor/physician.
P308+P313 如接触到或有疑虑:求医/就诊。 IF exposed or concerned: Get medical advice/attention.
P309+P311 如果接触或感到不适:呼叫解毒中心或医生/医师。 IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332+P313 如果发生皮肤刺激:获取医疗咨询/就医。 IF SKIN irritation occurs: Get medical advice/attention.
P333+P313 如果发生皮肤刺激或皮疹:获取医疗咨询/就医。 IF SKIN irritation or rash occurs: Get medical advice/attention.
P335+P334 刷掉皮肤松散颗粒。浸入冷水中/用湿绷带包扎 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337+P313 如果眼睛刺激持续:获取医疗咨询/就医。 IF eye irritation persists: Get medical advice/attention.
P342+P311 如果出现呼吸道症状:呼叫解毒中心或医生/医师。 IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370+P376 如果发生火灾,在安全的情况下阻止泄漏。 in case of fire: Stop leak if safe to Do so.
P370+P378 如果发生火灾:使用...灭火。 In case of fire: Use … for extinction.
P370+P380 在发生火灾时:撤离现场。 in case of fire: Evacuate area.
P370+P380+P375 在发生火灾时:撤离现场。远距离救火,因为有发生爆炸的危险。 in case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371+P380+P375 在有重大火灾和数量较多的情况下;撤离现场考虑到有爆炸的危险,应远距离救火。 in case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
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存储防范说明

P401 存储 Store
P402 存放在干燥的地方。 Store in a dry place.
P403 存放在通风良好的地方。 Store in a well-ventilated place.
P404 贮存于密闭容器中。 Store in a closed container.
P305+P351+P338 小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P405 上锁保管。 Store locked up.
P406 存放在耐腐蚀/具有耐性的内衬容器。 Store in corrosive resistant/ container with a resistant inner liner.
P407 在堆叠/货板间保持气隙。 Maintain air gap between stacks/pallets.
P410 防止阳光照射。 Protect from sunlight.
P411 储存在温度不超过oC /oF。 Store at temperatures not exceeding  oC/oF.
P412 不要暴露在超过50 oC / 122 oF的温度。 Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413 商店散装超过kg/lbs 时温度不应超过oC/oF. Store bulk masses greater than  kg/lbs at temperatures not exceeding  oC/oF.
P420 远离其他材料存放。 Store away from other materials.
P422 存储目录在之下。 Store contents under
P402+P404 存放在干燥的地方。贮存于密闭容器中。 Store in a dry place. Store in a closed container.
P403+P233 存放在通风良好的地方。保持容器密闭。 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 存放在通风良好的地方。保持凉爽。 Store in a well-ventilated place. Keep cool.
P410+P403 避免阳光直射。存放在通风良好的地方。 Protect from sunlight. Store in a well-ventilated place.
P410+P412 避免阳光直射。不要暴露在超过50 oC/122oF的温度。 Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411+P235 储存温度不超过 oC/oF.保持凉爽。 Store at temperatures not exceeding  oC/oF. Keep cool

处理防范说明

P501 Dispose of contents/container to..… 处理内容物/容器.....
P502 Refer to manufacturer/supplier for information on recovery/recycling 回收/循环再生产的信息,请参阅制造商/供应商
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危险性类别

GHS危险性类别

1 干燥时有爆炸性; Explosive when dry.
2 受冲击、摩擦、着火或其他引燃源有爆炸危险; Risk of explosion by shock, friction, fire or other sources of ignition.
3 受冲击、摩擦、着火或其他引燃源有极高爆炸危险; Extreme risk of explosion by shock, friction, fire or other sources of ignition.
4 生成极敏感的爆炸性金属化合物; Forms very sensitive explosive metallic compounds.
5 受热可能引起爆炸; Heating may cause an explosion.
6 与空气或未与空气接触发生爆炸; Explosive with or without contact with air.
7 可能引起火灾; May cause fire.
8 与可燃物料接触可能引起火灾; Contact with combustible material may cause fire.
9 与可燃物料混合时发生爆炸; Explosive when mixed with combustible material.
10 易燃的; Flammable.
11 高度易燃的; Highly flammable.
12 极易燃的; Extremely flammable.
14 与水猛烈反应; Reacts violently with water.
14/15 与水猛烈反应,释放出极易燃气体; Reacts violently with water, liberating highly flammable gases.
15 与水接触释放出极易燃气体; Contact with water liberates extremely flammable gases.
15/29 与水接触释放出有毒的,极易燃气体; Contact with water liberates toxic, highly flammable gas.
16 与氧化性物质混合时发生爆炸; Explosive when mixed with oxidizing substances.
17 在空气中易自燃; Spontaneously flammable in air.
18 使用中可能形成易燃/爆炸性蒸气空气混合物; In use, may form flammable/explosive vapour-air mixture.
19 可能生成爆炸性过氧化物; May form explosive peroxides.
20 吸入有害; Harmful by inhalation.
20/21 吸入和与皮肤接触是有害的; Harmful by inhalation and in contact with skin.
20/21/22 吸入、与皮肤接触和吞食是有害的; Harmful by inhalation, in contact with skin and if swallowed.
20/22 吸入和吞食是有害的; Harmful by inhalation and if swallowed.
21 与皮肤接触是有害的; Harmful in contact with skin.
21/22 与皮肤接触和吞食是有毒的; Harmful in contact with skin and if swallowed.
22 吞食是有害的; Harmful if swallowed.
23 吸入有害; Toxic by inhalation.
23/24 吸入和与皮肤接触是有毒的; Toxic by inhalation and in contact with skin.
23/24/25 吸入、与皮肤接触和吞食是有毒的; Toxic by inhalation, in contact with skin and if swallowed.
23/25 吸入和吞食是有毒的; Toxic by inhalation and if swallowed.
24 与皮肤接触有毒; Toxic in contact with skin.
24/25 与皮肤接触和吞食是有毒的; Toxic in contact with skin and if swallowed.
25 吞食有毒; Toxic if swallowed.
26 吸入有极高毒性; Very toxic by inhalation.
26/27 吸入和与皮肤接触有极高毒性; Very toxic by inhalation and in contact with skin.
26/27/28 吸入、与皮肤接触和吞食有极高毒性; Very toxic by inhalation, in contact with skin and if swallowed.
26/28 吸入和吞食有极高毒性; Very toxic by inhalation and if swallowed.
27 与皮肤接触有极高毒性; Very toxic in contact with skin.
27/28 与皮肤接触和吞食有极高毒性; Very toxic in contact with skin and if swallowed.
28 吞食有极高毒性; Very toxic if swallowed.
29 与水接触释放出有毒气体; Contact with water liberates toxic gas.
30 使用会变为高度易燃的; Can become highly flammable in use.
31 与酸接触释放出有毒气体; Contact with acids liberates toxic gas.
32 与酸接触释放出极高毒性气体; Contact with acids liberates very toxic gas.
33 有累积作用危险; Danger of cumulative effects.
34 引起灼伤; Causes burns.
35 引起严重灼伤; Causes severe burns.
36 刺激眼睛; Irritating to eyes.
36/37 刺激眼睛和呼吸系统; Irritating to eyes and respiratory system.
36/37/38 刺激眼睛、呼吸系统和皮肤; Irritating to eyes, respiratory system and skin.
36/38 刺激眼睛和皮肤; Irritating to eyes and skin.
37 刺激呼吸系统; Irritating to respiratory system.
37/38 刺激呼吸系统和皮肤; Irritating to respiratory system and skin.
38 刺激皮肤; Irritating to skin.
39 有极严重不可逆作用危险; Danger of very serious irreversible effects.
39/23 有毒的:经吸入有极严重不可逆作用危险; Toxic : danger of very serious irreversible effects through inhalation.
39/23/24 有毒的:经吸入和与皮肤接触有极严重不可逆作用危险; Toxic : danger of very serious irreversible effects through inhalation and in contact with skin.
39/23/24/25 有毒的:经吸入、与皮肤接触和吞食有极严重不可逆作用危险; Toxic : danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
39/23/25 有毒的:经吸入和吞食有极严重不可逆作用危险; Toxic : danger of very serious irreversible effects through inhalation and if swallowed.
39/24 有毒的:与皮肤接触有极严重不可逆作用危险; Toxic : danger of very serious irreversible effects in contact with skin.
39/24/25 有毒的:与皮肤接触和吞食有极严重不可逆作用危险; Toxic : danger of very serious irreversible effects in contact with skin and if swallowed.
39/25 有毒的:吞食有极严重不可逆作用危险; Toxic : danger of very serious irreversible effects if swallowed.
39/26 极高毒性:经吸入有极严重不可逆作用危险; Very toxic : danger of very serious irreversible effects through inhalation.
39/26/27 极高毒性:经吸入和与皮肤接触有极严重不可逆作用危险; Very toxic : danger of very serious irreversible effects through inhalation and in contact with skin.
39/26/27/28 极高毒性:经吸入、与皮肤接触和吞食有极严重不可逆作用危险; Very toxic : danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
39/26/28 极高毒性:经吸入和吞食有极严重不可逆作用危险; Very toxic : danger of very serious irreversible effects through inhalation and if swallowed.
39/27 极高毒性:与皮肤接触有极严重不可逆作用危险; Very toxic : danger of very serious irreversible effects in contact with skin.
39/27/28 极高毒性:与皮肤接触和吞食有极严重不可逆作用危险; Very toxic : danger of very serious irreversible effects in contact with skin and if swallowed.
39/28 极高毒性:吞食有极严重不可逆作用危险; Very toxic : danger of very serious irreversible effects if swallowed.
40 可能有不可逆作用的风险; Possible risks of irreversible effects.
R40/20 有害的:经吸入可能有不可逆作用的风险; Harmful : possible risk of irreversible effects through inhalation.
R40/20/21 有害的:经吸入和与皮肤接触可能有不可逆作用的风险; Harmful : possible risk of irreversible effects through inhalation and in contact with skin.
R40/20/21/22 有害的:经吸入、与皮肤接触和吞食可能有不可逆作用的风险; Harmful : possible risk of irreversible effects through inhalation, in contact with skin and if swallowed.
R40/20/22 有害的:经吸入和吞食可能有不可逆作用的风险; Harmful : possible risk of irreversible effects through inhalation and if swallowed.
R40/21 有害的:与皮肤接触可能有不可逆作用的风险; Harmful : possible risk of irreversible effects in contact with skin.
R40/21/22 有害的:与皮肤接触和吞食可能有不可逆作用的风险; Harmful : possible risk of irreversible effects in contact with skin and if swallowed.
R40/22 有害的:吞食可能有不可逆作用的风险; Harmful : possible risk of irreversible effects if swallowed
R41 对眼睛有严重损害的风险; Risk of serious damage to eyes.
R42 吸入可能引起过敏; May cause sensitization by inhalation.
R42/43 吸入和皮肤接触可能引起过敏; May cause sensitization by inhalation and skin contact.
R43 皮肤接触可能引起过敏; May cause sensitization by skin contact.
R44 在封闭情况下加热有爆炸危险; Risk of explosion if heated under confinement.
R45 可能致癌; May cause cancer.
R46 可能造成不可逆的遗传损害 May cause heritable genetic damage.
R47 可能引起出生缺陷; May cause birth defects.
R48 长期接触有严重损害健康的危险; Danger of serious damage to health by prolonged exposure.
R48/20 有害的:经吸入长期接触有严重损害健康的危险; Harmful : danger of serious damage to health by prolonged exposure through inhalation.
R48/20/21 有害的:经吸入和与皮肤长期接触有严重损害健康的危险; Harmful : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.
R48/20/21/22 有害的:经吸入、皮肤和吞食长期接触有严重损害健康的危险; Harmful : danger of serious damage to health by prolonged exposure through inh.,in contact with skin and if swallowed
R48/20/22 有害的:经吸入和吞食长期接触有严重损害健康的危险; Harmful : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
R48/21 有害的:经皮肤长期接触有严重损害健康的危险; Harmful : danger of serious damage to health by prolonged exposure in contact with skin.
R48/21/22 有害的:经皮肤和吞食长期接触有严重损害健康的危险; Harmful : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
R48/22 有害的:吞食长期接触有严重损害健康的危险; Harmful : danger of serious damage to health by prolonged exposure if swallowed.
R48/23 有毒的:经吸入长期接触有严重损害健康的危险; Toxic : danger of serious damage to health by prolonged exposure through inhalation.
R48/23/24 有毒的:经吸入和与皮肤长期接触有严重损害健康的危险; Toxic : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.
R48/23/24/25 有毒的:经吸入、皮肤和吞食长期接触有严重损害健康的危险; Toxic : danger of serious damage to health by prolonged exposure through inh.,in contact with skin and if swallowed
R48/23/25 有毒的:经吸入和吞食长期接触有严重损害健康的危险; Toxic : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
R48/24 有毒的:经皮肤长期接触有严重损害健康的危险; Toxic : danger of serious damage to health by prolonged exposure in contact with skin.
R48/24/25 有毒的:经皮肤和吞食长期接触有严重损害健康的危险; Toxic : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
R48/25 有毒的:吞食长期接触有严重损害健康的危险; Toxic : danger of serious damage to health by prolonged exposure if swallowed.
R49 吸入可能致癌; May cause cancer by inhalation.
R50 对水生生物有极高毒性; Very toxic to aquatic organisms.
R50/53 对水生生物有极高毒性,可能在水生环境中造成长期不利影响; Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51 对水生生物是有毒的; Toxic to aquatic organisms.
R51/53 对水生生物有毒,可能在水生环境中造成长期不利影响; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R52 对水生生物是有害的; Harmful to aquatic organisms.
R52/53 对水生生物有害,可能在水生环境中造成长期不利影响; Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R53 可能在水生环境中造成长期不利影响; May cause long-term adverse effects in aquatic environment.
R54 对植物群有毒; Toxic to flora.
R55 对动物群有毒; Toxic to fauna.
R56 对土壤中生物有毒; Toxic to soil organisms.
R57 对蜜蜂有毒; Toxic to bees.
R58 可能在环境中造成长期不利影响; May cause long-term adverse effects in the environment.
R59 对臭氧层有危害; Dangerous for the ozon layer.
R60 可能损伤生育力; May impair fertility.
R61 可能对未出生婴儿造成危害; May cause harm to the unborn child.
R62 可能有损伤生育力的危险; Possible risk of impaired fertility.
R63 可能有损害未出生婴儿的危险; Possible risk of harm to the unborn child.
R64 可能对哺乳婴儿造成危害; May cause harm to breastfed babies.
R65 如果吞下了可能导致肺损伤 Harmfull may cause lung damage if swallowed
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安全代码

GHS安全代码

S1 保持封闭。 Keep locked up.
S2 存放在儿童接触不到的地方。 Keep out of the reach of children.
S3 存放在凉爽的地方。 Keep in a cool place.
S4 存放在远离居住区的地方。 Keep away from living quarters.
S5 保存在...中(一种液体的名称)。 Keep contents under … (appropriate liquid to be specified by the manufacturer).
S6 保存在...气氛下(一种惰性气体的名字)。 Keep under … (inert gas to be specified by the manufacturer).
S7 保持容器紧密封闭。 Keep container tightly closed.
S8 保持容器干燥。 Keep container dry.
S9 保持容器在一个有良好通风放的场所。 Keep container in a well-ventilated place.
S12 不要将容器封死。 Do not keep container sealed.
S13 远离食品、饮料和动物饲料。 Keep away from food, drink and animal feeding stuffs.
S14 远离 ... (列出不相容的物质)。 Keep away from … (incompatible materials to be indicated by the manufacturer).
S15 远离热源。 Keep away from heat.
S16 远离火源。 Keep away from sources of ignition – No smoking.
S17 远离可燃物质。 Keep away from combustible material.
S18 搬运及打开容器时要当心。 Handle and open container with care.
S20 使用时,不得同时饮食。 When using do not eat or drink.
S21 使用时不得吸烟。 When using do not smoke.
S22 不要吸入粉尘。 Do not breathe dust.
S23 不要吸入蒸汽。 Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer).
S24 避免接触皮肤。 Avoid contact with skin.
S25 避免接触眼睛。 Avoid contact with eyes.
S26 万一接触眼睛,立即使用大量清水冲洗并送医诊治。 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27 立刻除去所有污染衣物。 Take off immediately all contaminated clothing.
S28 接触皮肤之后,立即使用大量皂液洗涤。 After contact with skin, wash immediately with plenty of … (to be specified by the manufacturer).
S29 不要将残余物倾入排水口。 Do not empty into drains.
S30 千万不可将水加入此产品。 Never add water to this product.
S33 采取防护措施防止静电发生。 Take precautionary measures against static discharges.
S35 本物质残余以及它的容器必须用安全方式处置。 This material and its container must be disposed of in a safe way.
S36 穿戴合适的防护服装。 Wear suitable protective clothing.
S37 使用合适的防护手套。 Wear suitable gloves.
S38 在通风不良的场所,佩戴合适的呼吸装置。 In case of insufficient ventilation, wear suitable respiratory equipment.
S39 佩戴眼 / 面防护装置。 Wear eye/face protection.
S40 清理被该物质污染的地面和物体,使用(合适的清洁材料名称)。 To clean the floor and all objects contaminated by this material, use … (to be specified by the manufacturer).
S41 当发生火灾和 / 或爆炸时,不要吸入烟雾。 In case of fire and/or explosion, do not breathe fumes.
S42 灭火时佩戴合适的呼吸装置。 During fumigation/spraying, wear suitable respiratory equipment (appropriate wording to be specified by the manufacturer).
S43 灭火时使用 ...(某种合适的灭火装置名称)。 In case of fire, use … (indicate in the space the precise type of fire-fighting equipment. If water increases the risk, add – Never use water).
S45 出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S46 万一发生不慎吞咽,立刻寻求医生的建议(展示产品容器或者标签)。 If swallowed, seek medical advice immediately and show this container or label.
S47 保持温度不要超过... 。 Keep at temperature not exceeding …°C (to be specified by the manufacturer).
S48 用…保持其湿润(一种物质的名称)。 Keep wetted with … (appropriate material to be specified by the manufacturer).
S49 只能保存在原来的容器当中。 Keep only in the original container.
S50 不要与...混合。 Do not mix with … (to be specified by the manufacturer).
S51 只能在通风良好的场所使用。 Use only in well-ventilated areas.
S52 不建议在大面积内部空间使用。 Not recommended for interior use on large surface areas.
S53 避免暴露——使用前先阅读专门的说明。 Avoid exposure – obtain special instructions before use.
S56 在专门指定的废物收集点丢弃该残余物及包装容器。 Dispose of this material and its container at hazardous or special waste collection point.
S57 使用合适容器避免环境被污染。 Use appropriate container to avoid environmental contamination.
S59 回收时参考生产商和供应商提供的信息。 Refer to manufacturer/supplier for information on recovery/recycling.
S60 本物质残余物和容器必须作为危险废物处理。 This material and its container must be disposed of as hazardous waste.
S61 避免排放到环境中。参考专门的说明 / 安全数据表。 Avoid release to the environment. Refer to special instructions/Safety data sheets.
S62 如果不慎吞咽,不要催吐;立刻找医生诊治并出示产品容器或标签。 If swallowed do not induce vomiting:seek medical advice immediately and show this container or label.
S1/2 保持密封,保存在远离儿童的地点。 Keep locked up and out of reach of children.
S24/25 防止皮肤和眼睛接触。 Avoid contact with skin and eyes.
S36/37 穿戴合适的防护服和手套。 Wear suitable protective clothing and gloves.
S36/37/39 穿戴合适的防护服、手套并使用防护眼镜或者面罩。 Wear suitable protective clothing, gloves and eye/face protection.
S37/39 使用合适的手套和防护眼镜或者面罩。 Very toxic by inhalation and if swallowed.
S47/49: 只能在温度不超过…°C(由制造商指定)的原始容器中保存。 Keep only in the original container at temperature not exceeding …°C (to be specified by the manufacturer).
S3/7: 将容器密闭在阴凉处。 Keep container tightly closed in a cool place.
S29/56: 不要倒进下水道,在危险或特殊废物收集点处理这种材料及其容器。 Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point.
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象形符号和危险品标志

象形符号和危险品标志

描述(Description) 象形符号(Pictogram) 危险种类和危险类别 Hazard class and hazard category
GHS01
爆炸炸弹
爆炸物
Exploding Bomb
爆炸物 不稳定的炸药 Unstable explosives
炸药类别1.1, 1.2, 1.3, 1.4 Explosives of Divisions 1.1, 1.2, 1.3, 1.4
自反应物质和混合物,类别A、B Self reactive substances and mixtures, Types A,B
有机过氧化物,类别A、B Organic peroxides, Types A,B
GHS02
火焰
易燃物
Flammables
GHS易燃物 易燃气体类别1 Flammable gases, category 1
易燃气溶胶,第1,2类 Flammable aerosols, categories 1,2
易燃液体,类别1,2,3 Flammable liquids, categories 1,2,3
易燃固体,类别1,2 Flammable solids, categories 1,2
自反应物质和混合物,类型B,C,D,E,F Self-reactive substances and mixtures, Types B,C,D,E,F
自燃液体类别1 Pyrophoric liquids, category 1
自燃固体类别1 Pyrophoric solids, category 1
自我放热物质和混合物,categories 1,2 Self-heating substances and mixtures,
与水接触的物质和混合物,放出易燃气体类别1,2,3 Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
有机过氧化物,类别B,C,D,E,F Organic peroxides, Types B,C,D,E,F
GHS03
圆圈上的火焰
氧化劑
Flame Over Circle
氧化劑 氧化性气体,1类 Oxidizing gases, category 1
氧化性液体,类别1,2,3 Oxidizing liquids, categories 1,2,3
GHS04
气体钢筒
压缩气体
Gas Cylinder
压缩气体 压力下的气体: Gases under pressure:
压缩气体 Compressed gases
液化气 Liquefied gases
冷冻液化气体 Refrigerated Liquefied gases
溶解气体 Dissolved gases
GHS05
腐蚀
腐蚀性物质
Corrosion
腐蚀性物质 腐蚀金属,类别1 Corrosive to metals, category 1
腐蚀皮肤,类别1A,1B,1C Skin corrosion, categories 1A,1B,1C
严重眼损伤,类别1 Serious eye damage, category 1
GHS06
骷髅
急性毒性
Skull and Crossbones
急性毒性 急性毒性(口服,皮肤接触,吸入),类别1,2,3 Acute toxicity (oral, dermal, inhalation), categories 1,2,3
GHS07
感叹号
刺激性,有害品 Exclamation Mark
刺激性,有害品 急性毒性(口服,皮肤接触,吸入),类别4 Acute toxicity (oral, dermal, inhalation), category 4
皮肤刺激,类别2 Skin irritation, category 2
眼刺激,类别2 Eye irritation, category 2
皮肤过敏,类别1 Skin sensitisation, category 1
特定目标器官毒性 -一次接触,类别3 Specific Target Organ Toxicity – Single exposure, category 3
GHS08
健康危害
Health Hazard
健康危害 呼吸道过敏,类别1 Respiratory sensitization, category 1
生殖细胞突变,类别1A,1B,2 Germ cell mutagenicity, categories 1A,1B,2
致癌性,类别1A,1B,2 Carcinogenicity, categories 1A,1B,2
生殖毒性,类别1A,1B,2 Reproductive toxicity, categories 1A,1B,2
特定目标器官毒性 – 一次接触,类别1,2 Specific Target Organ Toxicity – Single exposure, categories 1,2
特定目标器官毒性 - 反复接触,第1,2类 Specific Target Organ Toxicity – Repeated exposure, categories 1,2
吸入危险,类别1 Aspiration Hazard, category 1
GHS09
环境
Environment
对环境的危害 对水环境的危害 Hazardous to the aquatic environment
急性危害,类别1 Acute hazard, category1
慢性危害,类别1,2 Chronic hazard, categories 1,2
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