GHS是一个简称,全称是Globally Harmonized System of Classification and Labeling of Chemicals,中文名称是《全球化学品统一分类和标签制度》。目的是指导各国建立统一化学品分类和标签规范,在2003年由联合国发布第一版。
GHS包含两大部分数据:危险性说明和防范说明
GHS标签有6个基本信息,如图所示。
1. 产品标识符 - 产品名称及其CAS号
2. 信号词 -"警告"或"危险"
3. GHS 象形图 - 以直观方式描述化学品危险的符号,一共有9种
4. 危险说明 (H标签) - 简要的说明和描述产品可能发生的危害,有单独的标签或是组合标签
5. 防范说明 (P标签) - 提前告知使用者如何避免或防止产品对人或环境产生危害,以及发生危险后的处理方式。有单独的或组合标签
6. 供应商信息 - 制造商或其他供应商的名称、地址和电话
GHS标签上也可以添加供应商补充信息。
GHS危险性说明一共包含三方面,分别是:物理危害(H2**)、健康危害(H3**)、环境危害(H4**)。
H200 | 不稳定爆炸品。 | Unstable explosives |
H201 | 爆炸品;大规模爆炸危险。 | Explosive; mass explosion hazard |
H202 | 爆炸品;严重喷射危险。 | Explosive, severe projection hazard |
H203 | 爆炸品;火灾、爆炸或喷射危险。 | Explosive; fire, blast or projection hazard |
H204 | 火灾或喷射危险。 | Fire or projection hazard |
H205 | 火中可能会造成大规模爆炸。 | May mass explode in fire |
H220 | 极易燃气体。 | Extremely flammable gas |
H221 | 易燃气体。 | Flammable gas |
H222 | 极易燃气雾剂 | Extremely flammable aerosol |
H223 | 易燃气雾剂 | Flammable aerosol |
H224 | 极端易燃液体和蒸气 | Extremely flammable liquid and vapour |
H225 | 高度易燃液体和蒸气 | Highly flammable liquid and vapour |
H226 | 易燃液体和蒸气 | Flammable liquid and vapour |
H227 | 可燃液体 | Combustible liquid |
H228 | 易燃固体 | Flammable solid |
H240 | 加热可能会引起爆炸 | Heating may cause an explosion |
H241 | 加热可能会引起火灾或爆炸 | Heating may cause a fire or explosion |
H242 | 加热可能会引起火灾 | Heating may cause a fire |
H250 | 暴露于空气自发着火 | Catches fire spontaneously if exposed to air |
H251 | 自我放热:可能着火 | Self-heating: may catch fire |
H252 | 自我释放大量的热;可能着火。 | Self-heating in large quantities; may catch fire |
H260 | 与水接触时释放可燃气体,可自燃。 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | 与水接触时释放可燃气体。 | In contact with water releases flammable gas |
H270 | 可能导致或加剧燃烧;氧化剂。 | May cause or intensify fire; oxidizer |
H271 | 可能会引起火宅或爆炸;强氧化剂。 | May cause fire or explosion; strong oxidizer |
H272 | 可能加剧火势;氧化剂。 | May intensify fire; oxidizer |
H280 | 内含高压气体,遇热可能爆炸。 | Contains gas under pressure; may explode if heated |
H281 | 内含冷冻气体,可能导致低温灼伤或损伤。 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | 可能腐蚀金属。 | May be corrosive to metals |
H300 | 吞咽致命。 | Fatal if swallowed |
H301 | 吞咽会中毒 | Toxic if swallowed |
H302 | 吞咽有害 | Harmful if swallowed |
H303 | 吞咽可能有害 | May be harmful if swallowed |
H304 | 吞咽并进入呼吸道可能致命 | May be fatal if swallowed and enters airways |
H305 | 吞咽并进入呼吸道可能有害 | May be harmful if swallowed and enters airways |
H310 | 与皮肤接触致命 | Fatal in contact with skin |
H311 | 皮肤接触会中毒 | Toxic in contact with skin |
H312 | 与皮肤接触有害 | Harmful in contact with skin |
H313 | 接触皮肤可能有害 | May be harmful in contact with skin |
H314 | 造成严重的皮肤灼伤和眼睛损伤 | Causes severe skin burns and eye damage |
H315 | 引起皮肤刺激 | Causes skin irritation |
H316 | 引起轻度皮肤刺激 | Causes mild skin irritation |
H317 | 可能引起过敏性皮肤反应 | May cause an allergic skin reaction |
H318 | 造成严重眼损伤 | Causes serious eye damage |
H319 | 造成严重的眼睛刺激 | Causes serious eye irritation |
H320 | 引起眼睛刺激 | Causes eye irritation |
H330 | 吸入致死 | Fatal if inhaled |
H331 | 吸入会中毒 | Toxic if inhaled |
H332 | 吸入有害 | Harmful if inhaled |
H333 | 吸入可能有害 | May be harmful if inhaled |
H334 | 吸入可能导致过敏或哮喘症状或呼吸困难 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | 可能引起呼吸道刺激 | May cause respiratory irritation |
H336 | 可能引起嗜睡或头晕 | May cause drowsiness or dizziness |
H340 | 可能导致遗传缺陷 | May cause genetic defects |
H341 | 怀疑导致遗传缺陷 | Suspected of causing genetic defects |
H350 | 可能导致癌症 | May cause cancer |
H351 | 怀疑致癌 | Suspected of causing cancer |
H360 | 可能会损害生育能力或未出生的孩子 | May damage fertility or the unborn child |
H361 | 怀疑造成对生育能力或未出生的孩子的伤害 | Suspected of damaging fertility or the unborn child |
H361d | 怀疑对未出生的孩子造成伤害 | Suspected of damaging the unborn child |
H361e | 可能会伤害未出生的孩子 | May harm unborn children |
H361f | 怀疑生育能力受损 | Suspected of impaired Fertility |
H361g | 可能会损害生育能力 | May impair Fertility |
H362 | 可能对母乳喂养的儿童造成伤害 | May cause harm to breast-fed children |
H370 | 对器官造成伤害 | Causes damage to organs |
H371 | 可能对器官造成伤害 | May cause damage to organs |
H372 | 长期或反复接触会对器官造成伤害 | Causes damage to organs through prolonged or repeated exposure |
H373 | 长期或反复接触可能对器官造成伤害 | May cause damage to organs through prolonged or repeated exposure |
H300 + H310 | 吞咽或接触皮肤致命 | Fatal if swallowed or in contact with skin |
H300 + H330 | 吞咽或吸入致死 | Swallowing or inhaling to death |
H310 + H330 | 皮肤接触或吸入致死 | Death from skin contact or inhalation |
H300 + H310 + H330 | 吞咽,皮肤接触或吸入致死 | Swallowing, skin contact or inhalation to death |
H301 + H311 | 吞咽或皮肤接触会中毒 | Poisoning if swallowed or in contact with skin |
H301 + H331 | 吞咽或吸入会中毒 | Poisoning if swallowed or inhaled |
H311 + H331 | 皮肤接触或吸入会中毒 | Skin contact or inhalation can cause poisoning |
H301 + H311 + H331 | 吞咽,皮肤接触或吸入会中毒 | Swallowing, skin contact or inhalation can cause poisoning |
H302 + H312 | 吞咽或接触皮肤有害 | Harmful if swallowed or in contact with skin |
H302 + H332 | 吞咽或吸入有害 | Harmful if swallowed or inhaled |
H312 + H332 | 皮肤接触或吸入有害 | Harmful in skin contact or inhalation |
H302 + H312 + H332 | 吞咽,皮肤接触或吸入有害 | Harmful if swallowed, in contact with skin or inhaled |
H303 + H313 | 吞咽或接触皮肤可能有害 | May be harmful if swallowed or in contact with skin |
H303 + H333 | 吞咽或吸入可能有害 | May be harmful if swallowed or inhaled |
H313 + H333 | 接触皮肤或吸入可能有害 | May be harmful in contact with skin or inhalation |
H303 + H313 + H333 | 吞咽,皮肤接触或吸入可能有害 | Swallowing, skin contact or inhalation may be harmful |
H315 + H320 | 引起皮肤和眼睛刺激 | Cause skin and eye irritation |
H400 | 对水生生物毒性非常大。 | Very toxic to aquatic organisms. |
H401 | 对水生生物有毒。 | Toxic to aquatic organisms |
H402 | 对水生生物有害。 | Harmful to aquatic organisms. |
H410 | 对水生生物毒性非常大并具有长期影响。 | Very toxic to aquatic organisms and has long-term effects. |
H411 | 对水生生物有毒性并具有长期影响。 | Toxic to aquatic organisms and has long-term effects. |
H412 | 对水生生物有害并具有长期影响。 | Harmful to aquatic organisms and has long-term effects. |
H413 | 可能对水生生物造成长期持续有害影响。 | May cause long-term and sustained harmful effects on aquatic organisms. |
H420 | 通过破坏上层大气臭氧层而危害公众健康和环境。 | Harming public health and the environment by destroying the upper atmospheric ozone layer |
GHS防范说明一共包含五方面,分别是:普通防范说明(P1**)、预防防范说明(P2**)、回应防范说明(P3**)、存储防范说明(P4**)和处理防范说明(P5**)。
P101 | 如果你想要医药方面的建议,记得随手带上药瓶和标签 | If medical advice is needed,have product container or label at hand. |
P102 | 请将此药品放在儿童不能接触的地方。 | Keep out of reach of children. |
P103 | 使用前阅读标签 | Read label before use. |
P201 | 使用前获取专门指示。 | Obtain special instructions before use. |
P202 | 已阅读并理解所有的安全预防措施之前,切勿操作。 | Do not handle until all safety precautions have been read and understood. |
P210 | 远离热源/火花/明火/热的表面。——禁止吸烟。 | Keep away from heat/sparks/open flames/hot surfaces. — No smoking. |
P211 | 不要喷洒在明火或其他点火源。 | Do not spray on an open flame or other ignition source. |
P220 | 保持远离/贮存远离服装/....../可燃材料。 | Keep/Store away from clothing/…/combustible materials. |
P221 | 采取一切防范措施,避免与可燃物混合/... | Take any precaution to avoid mixing with combustibles/… |
P222 | 不要与空气接触。 | Do not allow contact with air. |
P223 | 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。 | Keep away from any possible contact with water, because of violent reaction and possible flash fire. |
P230 | 保持湿润 | Keep wetted with … |
P231 | 在惰性气体中操作。 | Handle under inert gas. |
P232 | 防止受潮。 | Protect from moisture. |
P233 | 保持容器密闭。 | Keep container tightly closed. |
P234 | 只保留在原来的容器中。 | Keep only in original container. |
P235 | 保持凉爽。 | Keep cool. |
P240 | 与地面接触/连接集装箱和接受设备。 | Ground/bond container and receiving equipment. |
P241 | 使用防爆电气/通风/照明/ .../设备。 | Use explosion-proof electrical/ventilating/lighting/…/equipment. |
P242 | 只能使用无火花工具。 | Use only non-sparking tools. |
P243 | 采取预防措施,防止静电放电。 | Take precautionary measures against static discharge. |
P244 | 保持减压阀无油,无油脂。 | Keep reduction valves free from grease and oil. |
P250 | 不要受研磨/冲击/....../摩擦。 | Do not subject to grinding/shock/…/friction. |
P251 | 压力容器:不要刺破或焚烧,即使在使用后。 | Pressurized container: Do not pierce or burn, even after use. |
P260 | 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 | Do not breathe dust/fume/gas/mist/vapours/spray. |
P261 | 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 | Avoid breathing dust/fume/gas/mist/vapours/spray. |
P262 | 不要接触眼睛,皮肤或衣服。 | Do not get in eyes, on skin, or on clothing. |
P263 | 怀孕/哺乳期间避免接触。 | Avoid contact during pregnancy/while nursing. |
P264 | 处理后要彻底洗净双手。 | Wash hands thoroughly after handling. |
P264 | 处理要彻底洗净皮肤。 | Wash skin thouroughly after handling. |
P270 | 使用本产品时不要吃东西,喝水或吸烟。 | Do not eat, drink or smoke when using this product. |
P271 | 只能在室外或通风良好的地方使用。 | Use only outdoors or in a well-ventilated area. |
P272 | 污染的工作服不得带出工作场所。 | Contaminated work clothing should not be allowed out of the workplace. |
P273 | 避免释放到环境中。 | Avoid release to the environment. |
P280 | 戴防护手套/防护服/眼睛的保护物/面部保护物。 | Wear protective gloves/protective clothing/eye protection/face protection. |
P281 | 使用所需的个人防护装备。 | Use personal protective equipment as required. |
P282 | 戴防寒手套/面罩/眼睛保护装备。 | Wear cold insulating gloves/face shield/eye protection. |
P283 | 穿防火/阻燃/耐阻燃服。 | Wear fire/flame resistant/retardant clothing. |
P284 | 佩戴呼吸保护装置。 | Wear respiratory protection. |
P285 | 在通风不足的情况下,戴呼吸防护。 | In case of inadequate ventilation wear respiratory protection. |
P231+P232 | 在惰性气体中。防止受潮。 | Handle under inert gas. Protect from moisture. |
P235+P410 | 保持冷静。避免阳光直射。 | Keep cool. Protect from sunlight. |
P301 | 如果吞下去 | IF SWALLOWED: |
P304 | 如果吸入 | IF INHALED: |
P305 | 如果进入眼睛 | IF IN EYES: |
P306 | 如果在衣服上 | IF ON CLOTHING: |
P307 | 如果接触 | IF exposed: |
P308 | 如果接触或涉及 | IF exposed or concerned: |
P309 | 如果接触或如果感到不适 | IF exposed or if you feel unwell: |
P310 | 立即呼救解毒中心或医生/医师。 | Immediately call a POISON CENTER or doctor/physician. |
P311 | 呼叫解毒中心或医生/医师。 | Call a POISON CENTER or doctor/physician. |
P312 | 如果你感觉不适,呼叫解毒中心或医生/医师。 | Call a POISON CENTER or doctor/physician if you feel unwell. |
P313 | 获取医疗咨询/就医 | Get medical advice/attention. |
P314 | 获取医疗咨询/就医,如果你觉得不舒服 | Get medical advice/attention if you feel unwell. |
P315 | 获取医疗咨询/就医 | Get immediate medical advice/attention. |
P320 | 紧急具体治疗(见本标签上的)。 | Specific treatment is urgent (see … on this label). |
P321 | 具体治疗(见本标签上的)。 | Specific treatment (see … on this label). |
P322 | 具体治疗(见本标签上的)。 | Specific measures (see …on this label). |
P330 | 漱口 | Rinse mouth. |
P331 | 不要催吐。 | Do NOT induce vomiting.. |
P332 | 如果发生皮肤刺激: | IF SKIN irritation occurs: |
P333 | 如果发生皮肤刺激或皮疹: | If skin irritation or rash occurs: |
P334 | 浸入冷水中/湿绷带包裹。 | Immerse in cool water/wrap n wet bandages. |
P335 | 刷掉皮肤松散颗粒。 | Brush off loose particles from skin. |
P336 | 解冻冻住的部位,用温水洗净。不要擦患处。 | Thaw frosted parts with lukewarm water. Do not rub affected area. |
P337 | 如果眼睛刺激持续 | If eye irritation persists: |
P338 | 如果戴隐形眼睛并容易摘掉的话,取出隐形眼镜,继续冲洗。 | Remove contact lenses, if present and easy to do. Continue rinsing. |
P340 | 将患者转移到空气清新,并保持在一个适合呼吸的姿势休息。 | Remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P341 | 如果出现呼吸困难,将患者转移到空气清新,并保持在一个适合呼吸的姿势休息。 | If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P342 | 如果出现呼吸症状: | If experiencing respiratory symptoms: |
P350 | 轻轻地用大量肥皂和水 | Gently wash with plenty of soap and water. |
P351 | 小心地用水冲洗几分钟。 | Rinse cautiously with water for several minutes. |
P352 | 用大量肥皂和水清洗。 | Wash with plenty of soap and water. |
P353 | 水洗/淋浴冲洗皮肤 | Rinse skin with water/shower. |
P360 | 立即冲洗污染的衣着,用大量水冲洗皮肤,然后脱掉衣服。 | Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. |
P361 | 立即去除/脱掉所有被污染的衣服。 | Remove/Take off immediately all contaminated clothing. |
P362 | 脱掉污染的衣服,清洗后方可重新使用 | Take off contaminated clothing and wash before reuse. |
P363 | 被污染的衣服洗净后方可重新使用。 | Wash contaminated clothing before reuse. |
P370 | 在发生火灾的情况下: | In case of fire: |
P371 | 在重大火灾和大量的情况下: | In case of major fire and large quantities: |
P372 | 在火中有灾爆炸的危险。 | Explosion risk in case of fire. |
P373 | 火烧到爆炸物时,切勿救火。 | DO NOT fight fire when fire reaches explosives. |
P374 | 在合适的距离采取正常安全预防措施灭火。 | Fight fire with normal precautions from a reasonable distance. |
P376 | 如果安全的话使泄露停止。氧化性气体。 | Stop leak if safe to do so. Oxidising gases (section 2.4) 1 |
P377 | 漏气着火:切勿灭火,除非漏气能够被安全地制止。 | Leaking gas fire: Do not extinguish, unless leak can be stopped safely. |
P378 | 使用...灭火。 | Use … for extinction. |
P380 | 疏散该地区。 | Evacuate area. |
P381 | 如果安全的话,消除所有点火源。 | Eliminate all ignition sources if safe to do so. |
P390 | 吸收溢出物,防止重大损害。 | Absorb spillage to prevent material damage. |
P391 | 收集对水环境有危害的泄漏物。 | Collect spillage. Hazardous to the aquatic environment |
P301+P310 | 如果食入:立即呼叫中毒控制中心或医生/医师。 | IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. |
P301+P312 | 如果吞下去了:如果你觉得不适,呼叫解毒中心或医生/医师。 | IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. |
P301+P330+P331 | 如果吞咽:漱口。不要催吐。 | IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. |
P302+P334 | 如果皮肤沾染:浸入冷水中/用湿绷带包扎 | IF ON SKIN: Immerse in cool water/wrap in wet bandages. |
P302+P350 | 如果在皮肤上:轻轻地用大量肥皂和水清洗 | IF ON SKIN: Gently wash with plenty of soap and water. |
P302+P352 | 如皮肤接触:用大量肥皂和水清洗。 | IF ON SKIN: wash with plenty of soap and water. |
P303+P361+P353 | 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。 | IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. |
P304+P312 | 如果吸入:如果你感觉不适,呼叫解毒中心或医生/医师。 | IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell. |
P304+P340 | 如果吸入:转移到空气新鲜处,休息,保持一个适合呼吸的姿势。 | IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. |
P304+P341 | 如果吸入:如呼吸困难,将受害人转移到空气新鲜处,保持一个适合呼吸的姿势休息。 | IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P305+P351+P338 | 如接触到眼睛小心地用水冲洗眼睛数分钟 | IF IN EYES: Rinse cautiously with water for several minutes. |
P306+P360 | 如果沾在衣服上:立即将被污染的衣服和皮肤用大量的水冲洗,然后脱掉衣服。 | IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. |
P307+P311 | 如果接触:呼叫解毒中心或医生/医师。 | IF exposed: call a POISON CENTER or doctor/physician. |
P308+P313 | 如接触到或有疑虑:求医/就诊。 | IF exposed or concerned: Get medical advice/attention. |
P309+P311 | 如果接触或感到不适:呼叫解毒中心或医生/医师。 | IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. |
P332+P313 | 如果发生皮肤刺激:获取医疗咨询/就医。 | IF SKIN irritation occurs: Get medical advice/attention. |
P333+P313 | 如果发生皮肤刺激或皮疹:获取医疗咨询/就医。 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335+P334 | 刷掉皮肤松散颗粒。浸入冷水中/用湿绷带包扎 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337+P313 | 如果眼睛刺激持续:获取医疗咨询/就医。 | IF eye irritation persists: Get medical advice/attention. |
P342+P311 | 如果出现呼吸道症状:呼叫解毒中心或医生/医师。 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370+P376 | 如果发生火灾,在安全的情况下阻止泄漏。 | in case of fire: Stop leak if safe to Do so. |
P370+P378 | 如果发生火灾:使用...灭火。 | In case of fire: Use … for extinction. |
P370+P380 | 在发生火灾时:撤离现场。 | in case of fire: Evacuate area. |
P370+P380+P375 | 在发生火灾时:撤离现场。远距离救火,因为有发生爆炸的危险。 | in case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371+P380+P375 | 在有重大火灾和数量较多的情况下;撤离现场考虑到有爆炸的危险,应远距离救火。 | in case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
P401 | 存储 | Store |
P402 | 存放在干燥的地方。 | Store in a dry place. |
P403 | 存放在通风良好的地方。 | Store in a well-ventilated place. |
P404 | 贮存于密闭容器中。 | Store in a closed container. |
P305+P351+P338 | 小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
P405 | 上锁保管。 | Store locked up. |
P406 | 存放在耐腐蚀/具有耐性的内衬容器。 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | 在堆叠/货板间保持气隙。 | Maintain air gap between stacks/pallets. |
P410 | 防止阳光照射。 | Protect from sunlight. |
P411 | 储存在温度不超过oC /oF。 | Store at temperatures not exceeding oC/oF. |
P412 | 不要暴露在超过50 oC / 122 oF的温度。 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | 商店散装超过kg/lbs 时温度不应超过oC/oF. | Store bulk masses greater than kg/lbs at temperatures not exceeding oC/oF. |
P420 | 远离其他材料存放。 | Store away from other materials. |
P422 | 存储目录在之下。 | Store contents under |
P402+P404 | 存放在干燥的地方。贮存于密闭容器中。 | Store in a dry place. Store in a closed container. |
P403+P233 | 存放在通风良好的地方。保持容器密闭。 | Store in a well-ventilated place. Keep container tightly closed. |
P403+P235 | 存放在通风良好的地方。保持凉爽。 | Store in a well-ventilated place. Keep cool. |
P410+P403 | 避免阳光直射。存放在通风良好的地方。 | Protect from sunlight. Store in a well-ventilated place. |
P410+P412 | 避免阳光直射。不要暴露在超过50 oC/122oF的温度。 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411+P235 | 储存温度不超过 oC/oF.保持凉爽。 | Store at temperatures not exceeding oC/oF. Keep cool |
P501 | Dispose of contents/container to..… | 处理内容物/容器..... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling | 回收/循环再生产的信息,请参阅制造商/供应商 |
1 | 干燥时有爆炸性; | Explosive when dry. |
2 | 受冲击、摩擦、着火或其他引燃源有爆炸危险; | Risk of explosion by shock, friction, fire or other sources of ignition. |
3 | 受冲击、摩擦、着火或其他引燃源有极高爆炸危险; | Extreme risk of explosion by shock, friction, fire or other sources of ignition. |
4 | 生成极敏感的爆炸性金属化合物; | Forms very sensitive explosive metallic compounds. |
5 | 受热可能引起爆炸; | Heating may cause an explosion. |
6 | 与空气或未与空气接触发生爆炸; | Explosive with or without contact with air. |
7 | 可能引起火灾; | May cause fire. |
8 | 与可燃物料接触可能引起火灾; | Contact with combustible material may cause fire. |
9 | 与可燃物料混合时发生爆炸; | Explosive when mixed with combustible material. |
10 | 易燃的; | Flammable. |
11 | 高度易燃的; | Highly flammable. |
12 | 极易燃的; | Extremely flammable. |
14 | 与水猛烈反应; | Reacts violently with water. |
14/15 | 与水猛烈反应,释放出极易燃气体; | Reacts violently with water, liberating highly flammable gases. |
15 | 与水接触释放出极易燃气体; | Contact with water liberates extremely flammable gases. |
15/29 | 与水接触释放出有毒的,极易燃气体; | Contact with water liberates toxic, highly flammable gas. |
16 | 与氧化性物质混合时发生爆炸; | Explosive when mixed with oxidizing substances. |
17 | 在空气中易自燃; | Spontaneously flammable in air. |
18 | 使用中可能形成易燃/爆炸性蒸气空气混合物; | In use, may form flammable/explosive vapour-air mixture. |
19 | 可能生成爆炸性过氧化物; | May form explosive peroxides. |
20 | 吸入有害; | Harmful by inhalation. |
20/21 | 吸入和与皮肤接触是有害的; | Harmful by inhalation and in contact with skin. |
20/21/22 | 吸入、与皮肤接触和吞食是有害的; | Harmful by inhalation, in contact with skin and if swallowed. |
20/22 | 吸入和吞食是有害的; | Harmful by inhalation and if swallowed. |
21 | 与皮肤接触是有害的; | Harmful in contact with skin. |
21/22 | 与皮肤接触和吞食是有毒的; | Harmful in contact with skin and if swallowed. |
22 | 吞食是有害的; | Harmful if swallowed. |
23 | 吸入有害; | Toxic by inhalation. |
23/24 | 吸入和与皮肤接触是有毒的; | Toxic by inhalation and in contact with skin. |
23/24/25 | 吸入、与皮肤接触和吞食是有毒的; | Toxic by inhalation, in contact with skin and if swallowed. |
23/25 | 吸入和吞食是有毒的; | Toxic by inhalation and if swallowed. |
24 | 与皮肤接触有毒; | Toxic in contact with skin. |
24/25 | 与皮肤接触和吞食是有毒的; | Toxic in contact with skin and if swallowed. |
25 | 吞食有毒; | Toxic if swallowed. |
26 | 吸入有极高毒性; | Very toxic by inhalation. |
26/27 | 吸入和与皮肤接触有极高毒性; | Very toxic by inhalation and in contact with skin. |
26/27/28 | 吸入、与皮肤接触和吞食有极高毒性; | Very toxic by inhalation, in contact with skin and if swallowed. |
26/28 | 吸入和吞食有极高毒性; | Very toxic by inhalation and if swallowed. |
27 | 与皮肤接触有极高毒性; | Very toxic in contact with skin. |
27/28 | 与皮肤接触和吞食有极高毒性; | Very toxic in contact with skin and if swallowed. |
28 | 吞食有极高毒性; | Very toxic if swallowed. |
29 | 与水接触释放出有毒气体; | Contact with water liberates toxic gas. |
30 | 使用会变为高度易燃的; | Can become highly flammable in use. |
31 | 与酸接触释放出有毒气体; | Contact with acids liberates toxic gas. |
32 | 与酸接触释放出极高毒性气体; | Contact with acids liberates very toxic gas. |
33 | 有累积作用危险; | Danger of cumulative effects. |
34 | 引起灼伤; | Causes burns. |
35 | 引起严重灼伤; | Causes severe burns. |
36 | 刺激眼睛; | Irritating to eyes. |
36/37 | 刺激眼睛和呼吸系统; | Irritating to eyes and respiratory system. |
36/37/38 | 刺激眼睛、呼吸系统和皮肤; | Irritating to eyes, respiratory system and skin. |
36/38 | 刺激眼睛和皮肤; | Irritating to eyes and skin. |
37 | 刺激呼吸系统; | Irritating to respiratory system. |
37/38 | 刺激呼吸系统和皮肤; | Irritating to respiratory system and skin. |
38 | 刺激皮肤; | Irritating to skin. |
39 | 有极严重不可逆作用危险; | Danger of very serious irreversible effects. |
39/23 | 有毒的:经吸入有极严重不可逆作用危险; | Toxic : danger of very serious irreversible effects through inhalation. |
39/23/24 | 有毒的:经吸入和与皮肤接触有极严重不可逆作用危险; | Toxic : danger of very serious irreversible effects through inhalation and in contact with skin. |
39/23/24/25 | 有毒的:经吸入、与皮肤接触和吞食有极严重不可逆作用危险; | Toxic : danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. |
39/23/25 | 有毒的:经吸入和吞食有极严重不可逆作用危险; | Toxic : danger of very serious irreversible effects through inhalation and if swallowed. |
39/24 | 有毒的:与皮肤接触有极严重不可逆作用危险; | Toxic : danger of very serious irreversible effects in contact with skin. |
39/24/25 | 有毒的:与皮肤接触和吞食有极严重不可逆作用危险; | Toxic : danger of very serious irreversible effects in contact with skin and if swallowed. |
39/25 | 有毒的:吞食有极严重不可逆作用危险; | Toxic : danger of very serious irreversible effects if swallowed. |
39/26 | 极高毒性:经吸入有极严重不可逆作用危险; | Very toxic : danger of very serious irreversible effects through inhalation. |
39/26/27 | 极高毒性:经吸入和与皮肤接触有极严重不可逆作用危险; | Very toxic : danger of very serious irreversible effects through inhalation and in contact with skin. |
39/26/27/28 | 极高毒性:经吸入、与皮肤接触和吞食有极严重不可逆作用危险; | Very toxic : danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. |
39/26/28 | 极高毒性:经吸入和吞食有极严重不可逆作用危险; | Very toxic : danger of very serious irreversible effects through inhalation and if swallowed. |
39/27 | 极高毒性:与皮肤接触有极严重不可逆作用危险; | Very toxic : danger of very serious irreversible effects in contact with skin. |
39/27/28 | 极高毒性:与皮肤接触和吞食有极严重不可逆作用危险; | Very toxic : danger of very serious irreversible effects in contact with skin and if swallowed. |
39/28 | 极高毒性:吞食有极严重不可逆作用危险; | Very toxic : danger of very serious irreversible effects if swallowed. |
40 | 可能有不可逆作用的风险; | Possible risks of irreversible effects. |
R40/20 | 有害的:经吸入可能有不可逆作用的风险; | Harmful : possible risk of irreversible effects through inhalation. |
R40/20/21 | 有害的:经吸入和与皮肤接触可能有不可逆作用的风险; | Harmful : possible risk of irreversible effects through inhalation and in contact with skin. |
R40/20/21/22 | 有害的:经吸入、与皮肤接触和吞食可能有不可逆作用的风险; | Harmful : possible risk of irreversible effects through inhalation, in contact with skin and if swallowed. |
R40/20/22 | 有害的:经吸入和吞食可能有不可逆作用的风险; | Harmful : possible risk of irreversible effects through inhalation and if swallowed. |
R40/21 | 有害的:与皮肤接触可能有不可逆作用的风险; | Harmful : possible risk of irreversible effects in contact with skin. |
R40/21/22 | 有害的:与皮肤接触和吞食可能有不可逆作用的风险; | Harmful : possible risk of irreversible effects in contact with skin and if swallowed. |
R40/22 | 有害的:吞食可能有不可逆作用的风险; | Harmful : possible risk of irreversible effects if swallowed |
R41 | 对眼睛有严重损害的风险; | Risk of serious damage to eyes. |
R42 | 吸入可能引起过敏; | May cause sensitization by inhalation. |
R42/43 | 吸入和皮肤接触可能引起过敏; | May cause sensitization by inhalation and skin contact. |
R43 | 皮肤接触可能引起过敏; | May cause sensitization by skin contact. |
R44 | 在封闭情况下加热有爆炸危险; | Risk of explosion if heated under confinement. |
R45 | 可能致癌; | May cause cancer. |
R46 | 可能造成不可逆的遗传损害 | May cause heritable genetic damage. |
R47 | 可能引起出生缺陷; | May cause birth defects. |
R48 | 长期接触有严重损害健康的危险; | Danger of serious damage to health by prolonged exposure. |
R48/20 | 有害的:经吸入长期接触有严重损害健康的危险; | Harmful : danger of serious damage to health by prolonged exposure through inhalation. |
R48/20/21 | 有害的:经吸入和与皮肤长期接触有严重损害健康的危险; | Harmful : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin. |
R48/20/21/22 | 有害的:经吸入、皮肤和吞食长期接触有严重损害健康的危险; | Harmful : danger of serious damage to health by prolonged exposure through inh.,in contact with skin and if swallowed |
R48/20/22 | 有害的:经吸入和吞食长期接触有严重损害健康的危险; | Harmful : danger of serious damage to health by prolonged exposure through inhalation and if swallowed. |
R48/21 | 有害的:经皮肤长期接触有严重损害健康的危险; | Harmful : danger of serious damage to health by prolonged exposure in contact with skin. |
R48/21/22 | 有害的:经皮肤和吞食长期接触有严重损害健康的危险; | Harmful : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed. |
R48/22 | 有害的:吞食长期接触有严重损害健康的危险; | Harmful : danger of serious damage to health by prolonged exposure if swallowed. |
R48/23 | 有毒的:经吸入长期接触有严重损害健康的危险; | Toxic : danger of serious damage to health by prolonged exposure through inhalation. |
R48/23/24 | 有毒的:经吸入和与皮肤长期接触有严重损害健康的危险; | Toxic : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin. |
R48/23/24/25 | 有毒的:经吸入、皮肤和吞食长期接触有严重损害健康的危险; | Toxic : danger of serious damage to health by prolonged exposure through inh.,in contact with skin and if swallowed |
R48/23/25 | 有毒的:经吸入和吞食长期接触有严重损害健康的危险; | Toxic : danger of serious damage to health by prolonged exposure through inhalation and if swallowed. |
R48/24 | 有毒的:经皮肤长期接触有严重损害健康的危险; | Toxic : danger of serious damage to health by prolonged exposure in contact with skin. |
R48/24/25 | 有毒的:经皮肤和吞食长期接触有严重损害健康的危险; | Toxic : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed. |
R48/25 | 有毒的:吞食长期接触有严重损害健康的危险; | Toxic : danger of serious damage to health by prolonged exposure if swallowed. |
R49 | 吸入可能致癌; | May cause cancer by inhalation. |
R50 | 对水生生物有极高毒性; | Very toxic to aquatic organisms. |
R50/53 | 对水生生物有极高毒性,可能在水生环境中造成长期不利影响; | Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
R51 | 对水生生物是有毒的; | Toxic to aquatic organisms. |
R51/53 | 对水生生物有毒,可能在水生环境中造成长期不利影响; | Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
R52 | 对水生生物是有害的; | Harmful to aquatic organisms. |
R52/53 | 对水生生物有害,可能在水生环境中造成长期不利影响; | Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
R53 | 可能在水生环境中造成长期不利影响; | May cause long-term adverse effects in aquatic environment. |
R54 | 对植物群有毒; | Toxic to flora. |
R55 | 对动物群有毒; | Toxic to fauna. |
R56 | 对土壤中生物有毒; | Toxic to soil organisms. |
R57 | 对蜜蜂有毒; | Toxic to bees. |
R58 | 可能在环境中造成长期不利影响; | May cause long-term adverse effects in the environment. |
R59 | 对臭氧层有危害; | Dangerous for the ozon layer. |
R60 | 可能损伤生育力; | May impair fertility. |
R61 | 可能对未出生婴儿造成危害; | May cause harm to the unborn child. |
R62 | 可能有损伤生育力的危险; | Possible risk of impaired fertility. |
R63 | 可能有损害未出生婴儿的危险; | Possible risk of harm to the unborn child. |
R64 | 可能对哺乳婴儿造成危害; | May cause harm to breastfed babies. |
R65 | 如果吞下了可能导致肺损伤 | Harmfull may cause lung damage if swallowed |
S1 | 保持封闭。 | Keep locked up. |
S2 | 存放在儿童接触不到的地方。 | Keep out of the reach of children. |
S3 | 存放在凉爽的地方。 | Keep in a cool place. |
S4 | 存放在远离居住区的地方。 | Keep away from living quarters. |
S5 | 保存在...中(一种液体的名称)。 | Keep contents under … (appropriate liquid to be specified by the manufacturer). |
S6 | 保存在...气氛下(一种惰性气体的名字)。 | Keep under … (inert gas to be specified by the manufacturer). |
S7 | 保持容器紧密封闭。 | Keep container tightly closed. |
S8 | 保持容器干燥。 | Keep container dry. |
S9 | 保持容器在一个有良好通风放的场所。 | Keep container in a well-ventilated place. |
S12 | 不要将容器封死。 | Do not keep container sealed. |
S13 | 远离食品、饮料和动物饲料。 | Keep away from food, drink and animal feeding stuffs. |
S14 | 远离 ... (列出不相容的物质)。 | Keep away from … (incompatible materials to be indicated by the manufacturer). |
S15 | 远离热源。 | Keep away from heat. |
S16 | 远离火源。 | Keep away from sources of ignition – No smoking. |
S17 | 远离可燃物质。 | Keep away from combustible material. |
S18 | 搬运及打开容器时要当心。 | Handle and open container with care. |
S20 | 使用时,不得同时饮食。 | When using do not eat or drink. |
S21 | 使用时不得吸烟。 | When using do not smoke. |
S22 | 不要吸入粉尘。 | Do not breathe dust. |
S23 | 不要吸入蒸汽。 | Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer). |
S24 | 避免接触皮肤。 | Avoid contact with skin. |
S25 | 避免接触眼睛。 | Avoid contact with eyes. |
S26 | 万一接触眼睛,立即使用大量清水冲洗并送医诊治。 | In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
S27 | 立刻除去所有污染衣物。 | Take off immediately all contaminated clothing. |
S28 | 接触皮肤之后,立即使用大量皂液洗涤。 | After contact with skin, wash immediately with plenty of … (to be specified by the manufacturer). |
S29 | 不要将残余物倾入排水口。 | Do not empty into drains. |
S30 | 千万不可将水加入此产品。 | Never add water to this product. |
S33 | 采取防护措施防止静电发生。 | Take precautionary measures against static discharges. |
S35 | 本物质残余以及它的容器必须用安全方式处置。 | This material and its container must be disposed of in a safe way. |
S36 | 穿戴合适的防护服装。 | Wear suitable protective clothing. |
S37 | 使用合适的防护手套。 | Wear suitable gloves. |
S38 | 在通风不良的场所,佩戴合适的呼吸装置。 | In case of insufficient ventilation, wear suitable respiratory equipment. |
S39 | 佩戴眼 / 面防护装置。 | Wear eye/face protection. |
S40 | 清理被该物质污染的地面和物体,使用(合适的清洁材料名称)。 | To clean the floor and all objects contaminated by this material, use … (to be specified by the manufacturer). |
S41 | 当发生火灾和 / 或爆炸时,不要吸入烟雾。 | In case of fire and/or explosion, do not breathe fumes. |
S42 | 灭火时佩戴合适的呼吸装置。 | During fumigation/spraying, wear suitable respiratory equipment (appropriate wording to be specified by the manufacturer). |
S43 | 灭火时使用 ...(某种合适的灭火装置名称)。 | In case of fire, use … (indicate in the space the precise type of fire-fighting equipment. If water increases the risk, add – Never use water). |
S45 | 出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。 | In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). |
S46 | 万一发生不慎吞咽,立刻寻求医生的建议(展示产品容器或者标签)。 | If swallowed, seek medical advice immediately and show this container or label. |
S47 | 保持温度不要超过... 。 | Keep at temperature not exceeding …°C (to be specified by the manufacturer). |
S48 | 用…保持其湿润(一种物质的名称)。 | Keep wetted with … (appropriate material to be specified by the manufacturer). |
S49 | 只能保存在原来的容器当中。 | Keep only in the original container. |
S50 | 不要与...混合。 | Do not mix with … (to be specified by the manufacturer). |
S51 | 只能在通风良好的场所使用。 | Use only in well-ventilated areas. |
S52 | 不建议在大面积内部空间使用。 | Not recommended for interior use on large surface areas. |
S53 | 避免暴露——使用前先阅读专门的说明。 | Avoid exposure – obtain special instructions before use. |
S56 | 在专门指定的废物收集点丢弃该残余物及包装容器。 | Dispose of this material and its container at hazardous or special waste collection point. |
S57 | 使用合适容器避免环境被污染。 | Use appropriate container to avoid environmental contamination. |
S59 | 回收时参考生产商和供应商提供的信息。 | Refer to manufacturer/supplier for information on recovery/recycling. |
S60 | 本物质残余物和容器必须作为危险废物处理。 | This material and its container must be disposed of as hazardous waste. |
S61 | 避免排放到环境中。参考专门的说明 / 安全数据表。 | Avoid release to the environment. Refer to special instructions/Safety data sheets. |
S62 | 如果不慎吞咽,不要催吐;立刻找医生诊治并出示产品容器或标签。 | If swallowed do not induce vomiting:seek medical advice immediately and show this container or label. |
S1/2 | 保持密封,保存在远离儿童的地点。 | Keep locked up and out of reach of children. |
S24/25 | 防止皮肤和眼睛接触。 | Avoid contact with skin and eyes. |
S36/37 | 穿戴合适的防护服和手套。 | Wear suitable protective clothing and gloves. |
S36/37/39 | 穿戴合适的防护服、手套并使用防护眼镜或者面罩。 | Wear suitable protective clothing, gloves and eye/face protection. |
S37/39 | 使用合适的手套和防护眼镜或者面罩。 | Very toxic by inhalation and if swallowed. |
S47/49: | 只能在温度不超过…°C(由制造商指定)的原始容器中保存。 | Keep only in the original container at temperature not exceeding …°C (to be specified by the manufacturer). |
S3/7: | 将容器密闭在阴凉处。 | Keep container tightly closed in a cool place. |
S29/56: | 不要倒进下水道,在危险或特殊废物收集点处理这种材料及其容器。 | Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. |
描述(Description) | 象形符号(Pictogram) | 危险种类和危险类别 | Hazard class and hazard category |
GHS01 爆炸炸弹 爆炸物 Exploding Bomb |
不稳定的炸药 | Unstable explosives | |
炸药类别1.1, 1.2, 1.3, 1.4 | Explosives of Divisions 1.1, 1.2, 1.3, 1.4 | ||
自反应物质和混合物,类别A、B | Self reactive substances and mixtures, Types A,B | ||
有机过氧化物,类别A、B | Organic peroxides, Types A,B | ||
GHS02 火焰 易燃物 Flammables |
易燃气体类别1 | Flammable gases, category 1 | |
易燃气溶胶,第1,2类 | Flammable aerosols, categories 1,2 | ||
易燃液体,类别1,2,3 | Flammable liquids, categories 1,2,3 | ||
易燃固体,类别1,2 | Flammable solids, categories 1,2 | ||
自反应物质和混合物,类型B,C,D,E,F | Self-reactive substances and mixtures, Types B,C,D,E,F | ||
自燃液体类别1 | Pyrophoric liquids, category 1 | ||
自燃固体类别1 | Pyrophoric solids, category 1 | ||
自我放热物质和混合物,categories 1,2 | Self-heating substances and mixtures, | ||
与水接触的物质和混合物,放出易燃气体类别1,2,3 | Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3 | ||
有机过氧化物,类别B,C,D,E,F | Organic peroxides, Types B,C,D,E,F | ||
GHS03 圆圈上的火焰 氧化劑 Flame Over Circle |
氧化性气体,1类 | Oxidizing gases, category 1 | |
氧化性液体,类别1,2,3 | Oxidizing liquids, categories 1,2,3 | ||
GHS04 气体钢筒 压缩气体 Gas Cylinder |
压力下的气体: | Gases under pressure: | |
压缩气体 | Compressed gases | ||
液化气 | Liquefied gases | ||
冷冻液化气体 | Refrigerated Liquefied gases | ||
溶解气体 | Dissolved gases | ||
GHS05 腐蚀 腐蚀性物质 Corrosion |
腐蚀金属,类别1 | Corrosive to metals, category 1 | |
腐蚀皮肤,类别1A,1B,1C | Skin corrosion, categories 1A,1B,1C | ||
严重眼损伤,类别1 | Serious eye damage, category 1 | ||
GHS06 骷髅 急性毒性 Skull and Crossbones |
急性毒性(口服,皮肤接触,吸入),类别1,2,3 | Acute toxicity (oral, dermal, inhalation), categories 1,2,3 | |
GHS07 感叹号 刺激性,有害品 Exclamation Mark |
急性毒性(口服,皮肤接触,吸入),类别4 | Acute toxicity (oral, dermal, inhalation), category 4 | |
皮肤刺激,类别2 | Skin irritation, category 2 | ||
眼刺激,类别2 | Eye irritation, category 2 | ||
皮肤过敏,类别1 | Skin sensitisation, category 1 | ||
特定目标器官毒性 -一次接触,类别3 | Specific Target Organ Toxicity – Single exposure, category 3 | ||
GHS08 健康危害 Health Hazard |
呼吸道过敏,类别1 | Respiratory sensitization, category 1 | |
生殖细胞突变,类别1A,1B,2 | Germ cell mutagenicity, categories 1A,1B,2 | ||
致癌性,类别1A,1B,2 | Carcinogenicity, categories 1A,1B,2 | ||
生殖毒性,类别1A,1B,2 | Reproductive toxicity, categories 1A,1B,2 | ||
特定目标器官毒性 – 一次接触,类别1,2 | Specific Target Organ Toxicity – Single exposure, categories 1,2 | ||
特定目标器官毒性 - 反复接触,第1,2类 | Specific Target Organ Toxicity – Repeated exposure, categories 1,2 | ||
吸入危险,类别1 | Aspiration Hazard, category 1 | ||
GHS09 环境 Environment |
对水环境的危害 | Hazardous to the aquatic environment | |
急性危害,类别1 | Acute hazard, category1 | ||
慢性危害,类别1,2 | Chronic hazard, categories 1,2 |