87413-09-0

Name Dess-Martin periodinane
CAS 87413-09-0
EINECS(EC#) 672-328-8
Molecular Formula C13H13IO8
MDL Number MFCD00130127
Molecular Weight 424.14
MOL File 87413-09-0.mol
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Chemical Properties

Appearance White Crystalline powder
Melting point  130-133 °C (lit.)
Boiling point  40 °C
density  1.369 g/mL at 25 °C
Fp  >221 °F
storage temp.  0-6°C
solubility  Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
form  Liquid
color  Colorless to light yellow
Sensitive  Light Sensitive
Merck  14,2933
BRN  4548207
Stability: Light Sensitive
InChI InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
InChIKey NKLCNNUWBJBICK-UHFFFAOYSA-N
SMILES I1(OC(=O)C)(OC(=O)C)(OC(=O)C)OC(=O)C2C=CC=CC1=2
CAS DataBase Reference 87413-09-0(CAS DataBase Reference)
Storage Precautions Air sensitive;Store under inert gas;Moisture sensitive

Safety Data

Symbol(GHS)  Flame Over Circle (GHS03)Exclamation Mark (GHS07)
GHS03,GHS07
Signal word  Danger
Hazard statements  H272-H315-H319-H335
Precautionary statements  P210-P220-P261-P264-P302+P352-P305+P351+P338
Hazard Codes  Xn,O,Xi
Risk Statements 
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R40:Limited evidence of a carcinogenic effect.
R8:Contact with combustible material may cause fire.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37:Wear suitable protective clothing and gloves .
S24/25:Avoid contact with skin and eyes .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S17:Keep away from combustible material .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
RIDADR  UN 1593 6.1/PG 3
WGK Germany  3
Hazard Note  Harmful/Light sensitive
TSCA  No
HazardClass  5.1
PackingGroup  Ⅲ
HS Code  29349900

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