Supplier Product Identification Physical and Chemical Properties First Aid Measures Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Transport Information Stability and Reactivity
Home > (1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one > (1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one(87413-09-0)

(1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one(87413-09-0)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Transport Information Stability and Reactivity

Product Identification

Product Name
(1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one
Synonyms
1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one
Triacetoxyperiodinane
CAS
87413-09-0
Formula
C13H13IO8
Molecular Weight
424.15
Merck
13,2950
Beilstein/Gmelin
4548207

Physical and Chemical Properties

Melting Point
133
Usage
Reagent for the selective oxidation of primary and secondary alcohols.

First Aid Measures

Ingestion
Seek medical assistance.
Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
Skin
Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush with running water for at least 20 minutes.
Eyes
In case of contact with substance, immediately flush with running water for at least 20 minutes.

Hazards Identification

Ingestion
Ingestion may cause severe injury, burns, or death.
Inhalation
Vapors may cause injury, burns, death.
Skin
Contact may result in injury, burns and death.
Eyes
See Skin.
Hazards
May explode from heat or contamination. May react explosively with hydrocarbons (fuels). May ignite combustibles.
EC Risk Phrase
R 5 8 36/37/38
EC Safety Phrase
S 7/8 26 36/37/39
UN (DOT)
1479

Exposure Controls/Personal Protection

Personal Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).

Fire Fighting Measures

Fire Fighting
Small Fires: Use water. Do not use dry chemicals or foams. carbon dioxide or Halon may provide limited control. Large Fires: Flood fire area with water from a distance.
Fire Potential
These substances will accelerate burning when involved in a fire.

Accidental Release Measures

Small spills/leaks
Keep away from combustible materials. Avoid contact unless wearing appropriate protective clothing. Stop leak if you can do it without risk. With clean shovel place material into clean, dry container and cover loosely; move containers from spill area.

Transport Information

UN Number
1479

Stability and Reactivity

Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.
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