ChemicalBook CAS DataBase List 7787-60-2

7787-60-2

Name	Bismuth trichloride
CAS	7787-60-2
EINECS(EC#)	232-123-2
Molecular Formula	BiCl3
MDL Number	MFCD00003461
Molecular Weight	315.34
MOL File	7787-60-2.mol

Synonyms

BISMUTH(+3)CHLORIDE BISMUTH CHLORIDE BISMUTH(III) CHLORIDE BISMUTH TRICHLORIDE BiCl3 Bismuthine, trichloro- Trichlorobismuth trichloro-bismuthin Trichlorobismuthine trichloro-Bismuthine BISMUTH(III) CHLORIDE, ANHYDROUS, POWDER , 99.999% BISMUTH(III) CHLORIDE, 98+% BISMUTH(III) CHLORIDE, 99.99% BISMUTH(III) CHLORIDE REAGENT GRADE >& BISMUTH(III) CHLORIDE, ANHYDROUS, BEADS,-10 MESH, 99.999% Bismuth(III) chloride anhydrous, 99.999% Bismuth(III)chloride,anhydrous,99+%(metalsbasis) Bismuth(III)chloride,anhydrous,99.999%(metalsbasis) Bismuth(III) chloride, 99.999% Bismuth(III) chloride, anhydrous, 98+%

Chemical Properties

Appearance	White crystal and crystalline powder
Melting point	230-232 °C(lit.)
Boiling point	447 °C(lit.)
density	4.75
Fp	430°C
storage temp.	no restrictions.
solubility	Soluble in hydrochloric acid, nitric acid, diethyl ether, ethyl acetate and acetone. Insoluble in alcohol.
form	powder
color	White to beige or gray
Specific Gravity	4.75
Odor	Hydrochloric acid odor
Stability:	Stable, but reacts with water, moisture.
Water Solubility	decomposes
Specific Heat Capacity	Cp(crystal):0.332974J/(g·K);Cp(gas):0.252743J/(g·K),at 25℃
Sensitive	Hygroscopic
Merck	14,1262
Sublimation	430 ºC
Major Application	electroplating material synthesis precursor perovskite solar cells
InChI	1S/Bi.3ClH/h;3*1H/q+3;;;/p-3
InChIKey	JHXKRIRFYBPWGE-UHFFFAOYSA-K
SMILES	Cl[Bi](Cl)Cl
CAS DataBase Reference	7787-60-2(CAS DataBase Reference)
NIST Chemistry Reference	Bismuth trichloride(7787-60-2)
EPA Substance Registry System	7787-60-2(EPA Substance)

Safety Data

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319
Precautionary statements	P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
Hazard Codes	Xi
Risk Statements	R36/38:Irritating to eyes and skin . R36/37/38:Irritating to eyes, respiratory system and skin . less more
Safety Statements	S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . S37/39:Wear suitable gloves and eye/face protection . less more
RIDADR	3260
WGK Germany	2
RTECS	EB2690000
TSCA	Yes
HazardClass	8
PackingGroup	III
HS Code	28273990
Storage Class	11 - Combustible Solids
Hazard Classifications	Eye Irrit. 2 Skin Irrit. 2
Toxicity	LD50 orally in Rabbit: 3334 mg/kg less more

Raw materials And Preparation Products

Hazard Information

Chemical Properties

Bismuth trichloride is white crystal and crystalline powder

Physical properties

Yellowish-white crystalline solid; cubic crystals; hygroscopic; density 4.75g/cm³; melts at 230°C; vaporizes at 447°C; vapor pressure 5 torr at 242°C; reacts with water; soluble in acids, alcohol and acetone.

Uses

Bismuth chloride (Bi³⁺ + 3Cl^1- → BiCl3) reacts with water to produce what is known as “bismuth white” pigment.

Uses

Bismuth trichloride used as catalyst for organic reactions.

Uses

In the manufacture of other bismuth salts; as catalyst for organic reactions.

Definition

Bismuth trichloride is a white deliquescent solid. It can be prepared by direct combination of bismuth and chlorine. Bismuth(III) chloride dissolves in excess dilute hydrochloric acid to form a clear liquid, but if diluted it produces a white precipitate of bismuth(III) chloride oxide (bismuthyl chloride, BiOCl): BiCl₃+ H₂O = BiOCl + 2HCl This reaction is often used as an exam ple of a reversible reaction and as a confirmatory test for bismuth during quantitative analysis. Bismuth(V) chloride does not form.

Preparation

Bismuth chloride may be synthesized directly by passing chlorine over bismuth. Alternatively, the chloride salt may be prepared by adding hydrochloric acid to basic bismuth chloride and evaporating the solution:
Bi(OH)₂Cl + 2HCl → BiCl₃ + 2H₂O
Also, the compound can be prepared by dissolving bismuth in concentrated nitric acid and then adding solid sodium chloride into this solution. Another method of preparation is treating the metal with concentrated hydrochloric acid:
2Bi + 6HCl → 2BiCl₃ + 3H₂.

General Description

Bismuth(III) chloride is an inorganic salt that can be prepared by the reaction of bismuth with chlorine.

reaction suitability

reagent type: catalyst
core: bismuth

Purification Methods

Sublime the trichloride under high vacuum, or dry it under a current of HCl gas, followed by fractional distillation, once under HCl and once under argon. It is deliquescent. [Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 621 1963.]

Material Safety Data Sheet(MSDS)

Spectrum Detail

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