ChemicalBook CAS DataBase List 3006-86-8

3006-86-8

Name	1,1-Di(tert-butylperoxy)cyclohexane
CAS	3006-86-8
EINECS(EC#)	221-111-2
Molecular Formula	C14H28O4
MDL Number	MFCD00084800
Molecular Weight	260.37
MOL File	3006-86-8.mol

Synonyms

1,1-BIS(TERT-BUTYLPEROXY)CYCLOHEXANE 1,1-DI(TERT-BUTYLPEROXY)CYCLOHEXANE cyclohexylidenebis(tert-butyl)peroxide Luperox 331M80 LUPEROX(TM) 331M80 Trigonox 22 TRIGONOX(R) 22 Peroxide,cyclohexylidenebis[(1,1-dimethylethyl) 1,1-bis(T-butylperoxy)cyclohexane 1,1-Bis(tert-butylperoxy)cyclohexane solution DP275B 1,1-BIS(T-BUPEROXY)CYCLOHEXANE, 80 WT. % 1 1-BIS(T-BUTYLPEROXY)CYCLOHEXANE TECH& 50%solutioninmineraloil 1,1-Di(tert-butylperoxy)cyclohexane, 50% solution in mineral oil 1,1-Di-(tert.-butylperoxy)-cyclohexan Cyclohexylidenebis[(1,1-dimethylethyl)peroxide] Dibutyl peroxycyclohexanone paste Initiating agent DP275B 1,1-Bis(tert-butylperoxy)cyclohexane (Luperox(R) 331M80) solution

Chemical Properties

Appearance	clear liquid
Melting point	65 °C (SADT)
Boiling point	52-54 °C (0.1 mmHg)
density	0.891 g/mL at 25 °C
vapor pressure	4.88hPa at 25℃
refractive index	n20/D 1.435
Fp	155 °F
storage temp.	Refrigerator (+4°C)
form	Liquid
color	Clear
Water Solubility	miscible
InChI	InChI=1S/C14H28O4/c1-12(2,3)15-17-14(10-8-7-9-11-14)18-16-13(4,5)6/h7-11H2,1-6H3
InChIKey	HSLFISVKRDQEBY-UHFFFAOYSA-N
SMILES	C1(CCCCC1)(OOC(C)(C)C)OOC(C)(C)C
LogP	7.2 at 25℃
CAS DataBase Reference	3006-86-8(CAS DataBase Reference)
EPA Substance Registry System	3006-86-8(EPA Substance)

Safety Data

Hazard Codes	O,N,T
Risk Statements	R7:May cause fire. R62:Possible risk of impaired fertility. R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . R36/37/38:Irritating to eyes, respiratory system and skin . R61:May cause harm to the unborn child. less more
Safety Statements	S17:Keep away from combustible material . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S3/7:Keep container tightly closed in a cool place . S61:Avoid release to the environment. Refer to special instructions safety data sheet . S60:This material and/or its container must be disposed of as hazardous waste . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S14:Keep away from ... (incompatible materials to be indicated by the manufacturer) . S53:Avoid exposure-obtain special instruction before use . less more
RIDADR	UN 3103 5.2
WGK Germany	2
TSCA	TSCA listed
HazardClass	5.2
PackingGroup	II
HS Code	29096000
Storage Class	4.1A - Other explosive hazardous materials
Hazard Classifications	Asp. Tox. 1 Carc. 1B Eye Irrit. 2 Muta. 1B Org. Perox. C Skin Irrit. 2 STOT SE 3

Hazard Information

Reactivity Profile

The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. 1,1-DI-(TERT-BUTYLPEROXY)CYCLOHEXANE, [<= 50% WITH PHLEGMATIZER] is unlikely that this derivative would be particularly unstable compared to other peroxides in it's class, Bretherick 2nd ed., p 44 1979.

Chemical Properties

clear liquid

Uses

Polymerization initiator.

Definition

1,1-Di (tert-butylperoxy) cyclohexane (DTBPH) is a commercial liquid organic peroxide that is to be in aliphatic hydrocarbon solvent and transported and stored under limited temperature[1].

Flammability and Explosibility

Notclassified

Toxics Screening Level

The initial threshold screening level (ITSL) for 1,1-Di-(tert-butylperoxy)cyclohexane is set at trace, 0.1 μg/m3 based on an annual averaging time.

References

[1] Jo-Ming Tseng . “The thermal hazard evaluation of 1,1-di (tert-butylperoxy) cyclohexane by DSC using non-isothermal and isothermal-kinetic simulations.” Journal of Loss Prevention in The Process Industries 25 4 (2012): Pages 703-708.

Material Safety Data Sheet(MSDS)

Spectrum Detail

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