General Description
White to tan solid or beige powder. Musty odor.
Reactivity Profile
CHLORONEB(2675-77-6) is stable at temperatures up to 514° F, in water in the presence of dilute acids or alkalis, and in the common organic solvents. CHLORONEB(2675-77-6) is subject to microbial decomposition in soil under moist conditions.
Air & Water Reactions
Insoluble in water.
Potential Exposure
An organochlorine/substituted benzene
systemic fungicide used to control snow mold on turf grass;
used on cotton, sugar beets and bean seeds to control seedling disease. Not approved for use in EU countries.
Fire Hazard
This chemical is combustible.
First aid
Speed in removing material from eyes and skin
is of extreme importance. Eyes: Eye contact can cause dangerous amounts of these chemicals to be quickly absorbed
through the mucous membrane into the bloodstream.
Directly, irrigate with large amounts of plain, tepid water
or saline for 20 minutes, occasionally lifting the lower and
upper lids. During this time, remove contact lenses, if easily removable without additional trauma to the eye. Get
medical aid immediately. Have physician check for possible delayed damage. Skin: Get medical aid. Dermal contact
can cause dangerous amounts of these chemicals to be
absorbed into the bloodstream. Wearing the appropriate
PPE equipment and respirator for organochlorine pesticides, immediately flush exposed skin, hair, and under nails
with plain, running, tepid water for 20 minutes, then wash
twice with mild soap. Shampoo hair promptly if contaminated; protect eyes. Do not scrub skin or hair, since this
can increase absorption through the skin. Rinse thoroughly
with water. Victims who are able and cooperative may
assist with their own decontamination. Remove and doublebag contaminated clothing and personal belongings.
Leather absorbs many organochlorines; therefore, items
such as leather shoes, gloves, and belts should be discarded.
If the skin is swollen or inflamed, cool affected areas with
cold compresses. Ingestion: Call poison control. Loosen all
clothing. Never give anything by mouth to an unconscious person. Get medical aid. Do not induce vomiting. In cases
of ingestion, the patient is at risk of central nervous system
depression or seizures, which may lead to pulmonary aspiration during vomiting. If the victim is conscious and able
to swallow, administer an aqueous slurry of activated
charcoal at 1 g/kg (usual adult dose 6090 g, child dose
2550 g). A soda can and straw may be of assistance when
offering charcoal to a child. The efficacy of activated charcoal for some organo chlorine poisoning (such as chlordane) is uncertain. If victim is unconscious or having
convulsions, do nothing except keep victim warm. In some
cases you may be specifically instructed by Poison Control
to induce vomiting by way of 2 tablespoons of syrup of ipecac (adult) washed down with a cup of water. Do not give
activated charcoal before or with ipecac syrup. Inhalation:
Get medical aid. Do not contaminate yourself. Wearing the
appropriate PPE equipment and respirator for organochlorine pesticides, immediately remove the victim from the
contaminated area to fresh air. For inhalation exposures,
monitor for respiratory distress. If the victim is not breathing, administer artificial respiration. Do not use mouth-tomouth method if victim ingested or inhaled the substance;
give artificial respiration with the aid of a pocket mask
equipped with a one-way valve or other proper respiratory
medical device. If cough or breathing difficulty develops,
evaluate for respiratory tract irritation, bronchitis, or pneumonitis. If breathing is difficult, administer 100% humidified supplemental oxygen through bag/mask apparatus until
medical help arrives. Do not leave victim unattended.
Shipping
UN2761 Organochlorine pesticides, solid, toxic,
Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
UN3077 Environmentally hazardous substances, solid,
n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous
material, Technical Name Required.
Incompatibilities
May react with strong oxidizers such as
chlorates, peroxides, nitrates, etc
Description
Chloroneb was developed by Du Pont de Nemours Co.
in 1967. It differs from the compounds described above
in that it does not contain nitro-groups. In
common with other chlorobenzene fungicides, chloroneb
has a low mammalian toxicity and a significant
vapor pressure so that it was used as a soil fungicide in
the culture of beans, cucumber, and cotton (20). In contrast
with the nitrobenzene compounds, Phytophthora spp. are
rather sensitive to chloroneb. Pythium spp. vary
in sensitivity to chloroneb. Because of its low water
solubility, chloroneb is only very weakly systemic (21,22).
Chemical Properties
beige powder
Chemical Properties
Colorless crystalline solid. Musty odor
Waste Disposal
Do not discharge into drains
or sewers. Dispose of waste material as hazardous waste
using a licensed disposal contractor to an approved landfill.Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Incineration with
effluent gas scrubbing is recommended. Containers must be
disposed of properly by following package label directions
or by contacting your local or federal environmental control
agency, or by contacting your regional EPA office.
Uses
Chloroneb-D6 is a labelled analogue of Chloroneb (C370935). Chloroneb is a fungicide that has selective activity against certain fungi (e.g. Mucor and Pythium fungi), and is most commonly used for cotton seedlings and bean plants.
Definition
ChEBI: A dimethoxybenzene that is p-dimethoxybenzene which is substituted by chlorines at positions 2 and 5. A fungicide formerly used as a seed treatment, it is not approved for use in the European Union.
Agricultural Uses
Fungicide: A systemic fungicide used to control snow mold on turf grass; used on cotton, sugar beets and bean seeds to control seedling disease. Not approved for use in EU countries. Registered for use in the U.S. except California
Trade name
CHLORAXYL® SEED TREATER; DELTA-COAT® II; DEMOSAN®; SOIL FUNGICIDE®-1823; TERSAN® SP; TERRANEB® SP; SOIL FUNGICIDE 1823®
Pharmacology
Chloroneb is not
effective against Fusarium but has a relatively broad
spectrum of activity compared with other compounds
that are specifically active against oomycetes (24). By
controlling Rhizoctonia solani, by seed-piece or in
furrow applications, chloroneb increased potato yields in
Texas (25).