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4-甲氨基吡啶

产品名称 4-甲氨基吡啶

CAS号3731-53-1

分子式C6H8N2

分子量108.14

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  • Mass

    MS-NW-1083          
    4-(aminomethyl)pyridine
    C6H8N2              (Mass of molecular ion:    108)
    

       Source Temperature: 250 °C
       Sample Temperature: 170 °C
       Reservoir, 75 eV
    

          18.0       1.7
          26.0       1.9
          27.0       3.2
          28.0      11.5
          29.0       3.2
          30.0      46.0
          37.0       1.1
          38.0       2.0
          39.0       5.7
          40.0       1.3
          41.0       1.3
          49.0       1.0
          50.0       6.0
          51.0      11.3
          52.0      11.7
          53.0       7.4
          54.0       2.8
          63.0       2.3
          64.0       1.9
          65.0       3.6
          78.0       4.7
          79.0      27.1
          80.0     100.0
          81.0       6.1
          92.0       1.9
         105.0       1.4
         107.0      21.7
         108.0      12.2
         109.0       1.1
    

90 MHz in CDCl3

parameter in DMSO-d6


  • 1H NMR 89.56 MHz
    C6 H8 N2 0.04 ml : 0.5 ml CDCl3
    4-(aminomethyl)pyridine
    ChemicalStructure
        Assign.     Shift(ppm)
    A 8.538 B 7.252 C 3.898 D 1.52

         Hz     ppm     Int.
    

        767.81   8.574    461
        766.25   8.556    278
        763.38   8.524    290
        761.81   8.507    509
        653.13   7.293    256
        652.38   7.285    445
        651.63   7.276    333
        650.75   7.267    266
        650.00   7.258    148
        648.75   7.244    150
        647.94   7.235    251
        647.13   7.226    321
        646.38   7.218    411
        645.63   7.209    215
        349.06   3.898   1000
        345.88   3.862     41
        140.19   1.566     35
        136.50   1.525    713
    


  • 1H NMR 300 MHz
    C6 H8 N2 30 % in DMSO
    4-(aminomethyl)pyridine
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 8.60 D(B) 7.41 D(C) 3.83 J(A,A') 0.4 J(A,B) 5.2 J(A,B') 1.0 J(A,C) 0.0 J(A',B) 1.0 J(A',B') 5.2 J(A',C) 0.0 J(B,B') 1.6 J(B,C) 0.7 J(B',C) 0.7 D(D) 2.39 BRUEGEL,W. Z.ELEKTROCHEM.(BER.BUNSENGES.PHYS.CHEM.) 66, 159 (1962)

         Hz     ppm     Int.
    

       2583.15   8.610    324
       2581.53   8.605    198
       2578.59   8.595    196
       2576.97   8.590    339
       2226.09   7.420    243
       2219.97   7.400    233
       1149.08   3.830    672
        717.01   2.390   1000
    

in CDCl3



CCl4 solution



liquid film