TRIOLEIN(122-32-7) 1H NMR

Mass

MS-NW-9071          
1,2,3-propanetriyl trioleate
C57H104O6           (Mass of molecular ion:    884)

   Source Temperature: 250 °C
   Sample Temperature: 240 °C
   Direct, 75 eV

      18.0       1.7
      26.0       1.1
      27.0       7.4
      28.0       3.9
      29.0      12.3
      39.0       7.1
      40.0       1.5
      41.0      36.4
      42.0       8.0
      43.0      34.2
      44.0       2.5
      45.0       1.7
      53.0       4.1
      54.0      14.0
      55.0      64.6
      56.0      16.7
      57.0      36.7
      58.0       2.4
      59.0       1.2
      60.0       3.7
      65.0       1.3
      66.0       1.9
      67.0      35.5
      68.0      15.3
      69.0      56.9
      70.0      15.1
      71.0      17.7
      72.0       1.2
      73.0       5.1
      77.0       1.9
      78.0       1.1
      79.0       9.5
      80.0       7.1
      81.0      39.4
      82.0      21.3
      83.0      53.8
      84.0      17.7
      85.0      12.2
      86.0       1.0
      87.0       2.3
      91.0       4.1
      92.0       1.7
      93.0       9.2
      94.0       6.7
      95.0      36.7
      96.0      21.0
      97.0      42.3
      98.0      31.5
      99.0       7.3
     100.0       3.0
     101.0       3.0
     105.0       3.3
     107.0       7.8
     108.0       5.9
     109.0      23.0
     110.0      13.5
     111.0      24.1
     112.0      12.6
     113.0       6.1
     114.0       3.1
     116.0       3.4
     117.0       2.5
     119.0       3.9
     120.0       2.0
     121.0      13.7
     122.0       4.6
     123.0      15.3
     124.0       9.6
     125.0      11.4
     126.0       5.4
     127.0       6.3
     129.0       9.5
     131.0       1.3
     133.0       5.0
     134.0       3.7
     135.0      13.4
     136.0       4.6
     137.0      13.4
     138.0       8.0
     139.0       7.4
     140.0       2.7
     141.0       5.1
     143.0       2.1
     145.0       1.0
     147.0       4.4
     148.0       3.2
     149.0       8.5
     150.0       4.4
     151.0      12.9
     152.0       8.6
     153.0       6.7
     154.0       2.3
     155.0       5.5
     157.0       2.2
     158.0       3.4
     161.0       3.2
     162.0       1.7
     163.0       5.3
     164.0       4.8
     165.0       9.6
     166.0       6.6
     167.0       5.3
     168.0       2.1
     169.0       4.1
     171.0       6.9
     172.0       2.4
     175.0       2.4
     177.0       3.4
     178.0       3.5
     179.0       5.9
     180.0       4.5
     181.0       3.9
     182.0       1.7
     183.0       3.0
     185.0       6.1
     186.0       1.5
     187.0       1.3
     189.0       1.8
     191.0       2.4
     192.0       1.6
     193.0       3.8
     194.0       2.4
     195.0       2.5
     196.0       1.2
     197.0       1.6
     199.0       2.4
     201.0       1.2
     203.0       1.2
     205.0       1.7
     206.0       1.2
     207.0       4.0
     208.0       2.4
     209.0       2.5
     210.0       1.1
     211.0       1.5
     213.0       3.0
     214.0       1.5
     215.0       1.0
     218.0       1.1
     219.0       1.3
     220.0       6.7
     221.0       5.7
     222.0       4.0
     223.0       2.0
     225.0       1.4
     226.0       1.0
     227.0       5.3
     228.0       1.3
     229.0       1.6
     233.0       1.6
     234.0       2.4
     235.0       3.1
     236.0       3.2
     237.0       2.1
     238.0       1.0
     239.0       2.5
     240.0       2.0
     241.0       3.8
     242.0       2.3
     243.0       1.8
     245.0       4.2
     246.0       8.7
     247.0       8.0
     248.0       2.4
     249.0       1.7
     250.0       1.0
     251.0       1.2
     253.0       1.9
     254.0       1.2
     255.0       2.1
     256.0       1.7
     259.0       1.1
     260.0       3.3
     261.0       3.9
     262.0      33.7
     263.0      17.3
     264.0      62.7
     265.0      58.9
     266.0      11.1
     267.0       4.6
     268.0       1.1
     269.0       1.3
     275.0       1.2
     276.0       2.1
     277.0       2.7
     278.0       3.5
     279.0       6.9
     280.0       5.1
     281.0       5.1
     282.0       3.2
     283.0       2.1
     284.0       2.0
     293.0       1.0
     295.0       2.3
     297.0       1.7
     307.0       1.0
     309.0       1.3
     311.0       1.1
     313.0       1.1
     318.0       1.0
     320.0       2.0
     321.0       2.3
     322.0       1.9
     323.0       3.9
     324.0       1.1
     325.0       2.1
     335.0       1.7
     336.0       3.3
     337.0       9.3
     338.0      22.1
     339.0      59.5
     340.0      13.8
     341.0       7.3
     342.0       1.5
     351.0       1.5
     352.0       1.1
     353.0       2.8
     354.0       1.2
     355.0       2.4
     356.0       1.2
     357.0       1.2
     365.0       1.1
     367.0       2.1
     380.0       3.4
     381.0       3.4
     382.0       1.3
     393.0      21.3
     394.0       6.0
     395.0       2.6
     407.0       2.1
     409.0       1.1
     419.0       1.1
     421.0       1.3
     433.0       1.0
     435.0       2.5
     436.0       2.1
     437.0       1.1
     447.0       2.6
     448.0       1.4
     449.0      14.6
     450.0       5.6
     451.0       3.2
     452.0       1.0
     461.0       1.0
     463.0       2.8
     464.0       2.2
     465.0       2.8
     466.0       1.0
     475.0       1.3
     476.0       1.3
     477.0       2.4
     478.0       1.9
     479.0       2.1
     489.0       1.4
     490.0       1.4
     491.0       2.4
     492.0       2.6
     493.0       3.8
     494.0       1.6
     495.0       1.0
     503.0       2.8
     504.0       2.3
     505.0       4.2
     506.0       5.7
     507.0       3.2
     508.0       1.5
     509.0       1.2
     517.0       1.8
     518.0       1.7
     519.0       2.4
     520.0       3.6
     521.0       1.9
     529.0       2.0
     531.0       1.1
     534.0       1.0
     559.0       1.8
     576.0       1.3
     577.0       2.4
     578.0       1.0
     589.0       1.6
     590.0       1.3
     591.0       1.5
     600.0       7.1
     602.0      69.9
     603.0     100.0
     604.0      41.4
     605.0      18.3
     606.0       2.7
     616.0       3.7
     617.0       5.1
     618.0       4.5
     619.0       5.8
     620.0       3.0
     621.0       1.1
     866.0       1.7
     884.0       3.7

90 MHz in CDCl3

¹H NMR	89.56 MHz
C₅₇ H₁₀₄ O₆	0.04 ml : 0.5 ml CDCl₃
1,2,3-propanetriyl trioleate

    Assign.     Shift(ppm)

      A          5.59 to 5.05
      B     *1      4.29
      C     *1      4.14
      D             2.32
      E             2.01
      F             1.61
      G          1.46 to 1.11
      J             0.89
     
     J(A,B)=4.4HZ. J(A,C)=6.0HZ. J(B,C)=-11.9HZ.

     Hz     ppm     Int.

    482.88   5.392     65
    481.19   5.373     44
    478.13   5.339    162
    473.44   5.287     65
    472.69   5.278     66
    382.88   4.276     59
    377.63   4.217     73
    371.63   4.150     54
    213.81   2.388     37
    213.63   2.386     37
    206.94   2.311    105
    199.69   2.230     84
    182.38   2.037     97
    177.13   1.978    108
    172.69   1.929     56
    144.06   1.609     39
    142.56   1.592     37
    140.13   1.565     30
    139.75   1.561     30
    139.38   1.557     31
    138.69   1.549     31
    138.31   1.545     31
    138.06   1.542     31
    136.94   1.530     31
    136.56   1.525     31
    135.94   1.518     31
    130.94   1.463     30
    113.50   1.268   1000
     83.81   0.936     77
     80.88   0.904     62
     78.69   0.879    230
     72.69   0.812     57

CCl4 solution

liquid film