Triisopropylsilane

Protective agents for peptide synthesis

Large volume of isopropyl (compared with ethyl) can achieve higher selectivity of reduction reaction? It should be (e.g., the synthesis of heterocephalic c-phenylketal) β- Selective reduction), but did not reduce their activity (trifluoromethane of trimethylsilyl ether? Sulfonic ketone catalytic reduction etherification. Highly amorphous synthesis of trans-1,2-diol catalyzed by Ni (o) N-heterocyclic carbene complex? Enantioselective preparation.