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ALPHA-METHYLBENZYL ALCOHOL

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ALPHA-METHYLBENZYL ALCOHOL Basic information
ALPHA-METHYLBENZYL ALCOHOL Chemical Properties
  • Melting point:19-20 °C(lit.)
  • Boiling point:204 °C745 mm Hg(lit.)
  • Density 1.012 g/mL at 25 °C(lit.)
  • vapor density 4.21 (vs air)
  • vapor pressure 0.1 mm Hg ( 20 °C)
  • refractive index n20/D 1.527(lit.)
  • Flash point:185 °F
  • CAS DataBase Reference13323-81-4(CAS DataBase Reference)
Safety Information
  • Hazard Codes Xn
  • Risk Statements 22-38-41
  • Safety Statements 26-39
  • RIDADR UN 2937 6.1/PG 3
  • WGK Germany 1
  • RTECS DO9275000
  • HazardClass 6.1
  • PackingGroup III
  • ToxicityThe acute oral LD50 in rats was reported as 400 mg/kg (Smyth & Carpenter, 1944). The acute dermal LD50 value in rabbits exceeded 2.5 g/kg (Moreno, 1973).
MSDS
ALPHA-METHYLBENZYL ALCOHOL Usage And Synthesis
  • Chemical PropertiesColorless liquid
  • OccurrenceHas apparently not been reported to occur in nature.
  • PreparationBy hydrogenation or reduction of acetophenone; or from methyl magnesium chloride plus benzaldehyde by a Grignard-type reaction (Bedoukian, 1967).
  • MetabolismStyrallyl alcohol is converted in rabbits into hippuric acid and methylphenylcarbinyl glucuronide, both optical forms of the carbinol behaving similarly. A small proportion (1-2%) is excreted as mandelic acid (Wjlliams, 1959).
  • Purification MethodsPurify the alcohol via its hydrogen phthalate. [See Houssa & Kenyon J Chem Soc 2260 1930.] Shake it with a solution of ferrous sulfate, and th
ALPHA-METHYLBENZYL ALCOHOL Preparation Products And Raw materials
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