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2,3-Dibromo-1-propanol

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2,3-Dibromo-1-propanol Basic information
2,3-Dibromo-1-propanol Chemical Properties
  • Melting point:9 °C
  • Boiling point:95-97 °C/10 mmHg (lit.)
  • Density 2.12 g/mL at 25 °C (lit.)
  • refractive index n20/D 1.559(lit.)
  • Flash point:>230 °F
  • storage temp. Keep in dark place,Inert atmosphere,Room temperature
  • pka13.69±0.10(Predicted)
  • Water Solubility 5-10 g/100 mL at 20 ºC
  • BRN 1719127
  • CAS DataBase Reference96-13-9(CAS DataBase Reference)
  • IARC2B (Vol. 77) 2000
  • NIST Chemistry Reference1-Propanol, 2,3-dibromo-(96-13-9)
  • EPA Substance Registry System2,3-Dibromopropanol (96-13-9)
Safety Information
MSDS
2,3-Dibromo-1-propanol Usage And Synthesis
  • Chemical Propertiesclear colorless liquid
  • Chemical Properties2,3-Dibromo-1-propanol is a clear, colorless to slightly yellow thick liquid.
  • Uses2,3-Dibromo-1-propanol is a metabolite of the flame retardant tris(2,3-dibromopropyl) phosphate (T775560), previously shown to be a mutagen and carcinogen in experimental animals.
  • UsesThe major use of 2,3-dibromo-1-propanol is as an intermediate in the production of flame retardants, insecticides, and pharmaceuticals, and the chemical itself has been used as a flame retardant. 2,3-Dibromo-1-propanol was used in the production of tris(2,3-dibromopropyl) phosphate, a flame retardant used in children’s clothing and other products (HSDB 2009). Tris(2,3-dibromopropyl) phosphate was banned from use in sleepwear in 1977 by the Consumer Product Safety Commission after studies showed that it causedcancer in experimental animals (NTP 1993, HSDB 2009).
  • Synthesis Reference(s)The Journal of Organic Chemistry, 30, p. 587, 1965 DOI: 10.1021/jo01013a069
  • General DescriptionClear colorless to slightly yellow viscous liquid.
  • Air & Water ReactionsWater soluble.
  • Reactivity Profile2,3-Dibromo-1-propanol is incompatible with strong oxidizers.
  • Fire Hazard2,3-Dibromo-1-propanol is probably combustible.
  • Potential ExposureChemical intermediate used to pro- duce insecticides, pharmaceuticals, and flame retardants.
  • Carcinogenicity2,3-Dibromo-1-propanol is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.
  • ShippingUN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
  • IncompatibilitiesIncompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo- sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides.
  • Waste DisposalUse a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
2,3-Dibromo-1-propanol Preparation Products And Raw materials
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