ChemicalBook Product Catalog Flavors and fragrances Synthetic fragrances Carboxylic acids and esters Aliphatic dicarboxylic acid esters EUGENOL ACETATE

EUGENOL ACETATE

Product NameEUGENOL ACETATE
CAS93-28-7
MFC12H14O3
MW206.24
EINECS202-235-6
MOL File93-28-7.mol

Chemical Properties

Melting point	27 to 29 °C (81 to 84 °F; 300 to 302 K)
Boiling point	281.2 °C (538.2 °F; 554.3 K)
Density	1.0806 g/cm3
vapor pressure	0.041Pa at 20℃
FEMA	2469 \| EUGENYL ACETATE
refractive index	1.52
Flash point	142 °C - closed cup
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
solubility	Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol (Slightly)
form	powder to lump to clear liquid
color	White or Colorless to Light yellow
Odor	at 100.00 %. fresh sweet woody clove floral carnation malt spice
Odor Type	spicy
biological source	synthetic
Water Solubility	407mg/L at 20℃
JECFA Number	1531
Stability	Stable. Combustible. Incompatible with strong oxidizing agents.
Major Application	cleaning products cosmetics flavors and fragrances food and beverages personal care
Cosmetics Ingredients Functions	FRAGRANCE
InChI	1S/C12H14O3/c1-4-5-10-6-7-11(15-9(2)13)12(8-10)14-3/h4,6-8H,1,5H2,2-3H3
InChIKey	SCCDQYPEOIRVGX-UHFFFAOYSA-N
SMILES	COc1cc(CC=C)ccc1OC(C)=O
LogP	2.8 at 25℃
CAS DataBase Reference	93-28-7(CAS DataBase Reference)
NIST Chemistry Reference	Phenol, 2-methoxy-4-(2-propenyl)-, acetate(93-28-7)
EPA Substance Registry System	Phenol, 2-methoxy-4-(2-propenyl)-, acetate (93-28-7)

Safety Information

Hazard Codes	Xn
Risk Statements	22-38
Safety Statements	36
WGK Germany	2
RTECS	SJ4550000
TSCA	TSCA listed
HS Code	29147000
Storage Class	10 - Combustible liquids
Hazard Classifications	Acute Tox. 4 Oral Skin Sens. 1B
Toxicity	The acute oral LD₅₀ value in rats was reported as 1.67 g/kg (Jenner, Hagan, Taylor, Cook & Fitzhugh, 1964) and as 2.6 g/kg (2.3-2.9 g/kg) (Moreno, 1972b). The acute dermal LD₅₀ value in rabbits exceeded 5 g/kg (Moreno, 1972a).

MSDS

Provider	Language
SigmaAldrich	English

Usage And Synthesis

Chemical Properties

Eugenyl acetate has a characteristic odor reminiscent of clove oil, with a burning, aromatic favor.

Chemical Properties

Eugenol Acetate occurs in clove oil, together with eugenol. It is a crystalline solid (mp 29°C) or yellowish liquid with a slightly fruity, clove odor. Eugenol acetate is prepared by acetylation of eugenol with acetic anhydride and is used in floral compositions to accentuate floral, spicy characters.

Occurrence

Reported found in the essential oils of Laurus nobilis, clove buds and leaves, cassia leaf and cinnamon leaf, root and bark

Uses

Eugenol Acetate is a constituent of Clove oil, an essential oil from the clove plant, Syzygium aromaticum. Clove oil is a natural analgaesic and antiseptic used primarily in dentistry for its main ingredient Eugenol. Clove oil can also be purchased in pharmacies over the counter, as a home remedy for dental pain relief, mainly toothache; it is also often found in the aromatherapy section of health food stores.

Application

Mild and sweet-spicy, balsamic-fruity odour, reminiscent of carnation. Earthy-fresh notes or leafy-floral notes are not uncommon. Used in perfumes to emphasize floralness in carnation, along with iso-eugenol, Amyl oxy-iso-eugenol, etc. Fresher than these, but also milder. Not stable in white soap or alkali. It is in flavors for berry, fruit, mint, spice, and vanilla types.

Definition

ChEBI: Acetyleugenol is a member of phenols and a benzoate ester.

Preparation

By direct acetylation of eugenol using acetic anhydride.

Flammability and Explosibility

Not classified

Safety Profile

Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also EUGENOL, ALLYL COMPOUNDS, and ESTERS.

EUGENOL ACETATE

Chemical Properties

Safety Information

MSDS

Usage And Synthesis

Preparation Products And Raw materials

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