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Thiocyclam hydrogen oxalate

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Thiocyclam hydrogen oxalate Basic information
Thiocyclam hydrogen oxalate Chemical Properties
Safety Information
  • Hazard Codes Xn,N
  • Risk Statements 21/22-50/53
  • Safety Statements 36/37-46-60-61
  • RIDADR 2588
  • WGK Germany 3
  • RTECS YL8300000
  • HazardClass 6.1(b)
  • PackingGroup III
Thiocyclam hydrogen oxalate Usage And Synthesis
  • UsesThiocyclam is used to protect against Lepidoptera, Coleoptera, some Diptera and Thysanoptera. It is used to control Colorado beetle in potatoes, Lepidoptera and Coleoptera pest complexes in rape, stem borers in irrigated rice, corn borers and Tanymecus in maize, weevils and other Coleoptera in sugar beet, stem borers in sugar cane, Lepidoptera in fruit trees and leaf miners in vegetables.
  • DefinitionChEBI: An oxalate salt resulting from the formal reaction of equimolar amounts of thiocyclam and oxalic acid. A nicotinic acetylcholine receptor agonist, it was used as a broad-spectrum insecticide. It is not approved for use within the European Union.
  • Metabolic pathwayThiocyclam is a propesticide of the natural product nereistoxin which is a potent insect neurotoxin isolated from the annelid Lumbviconeveis hetevopoda. Thiocyclam is rapidly converted into nereistoxin in biological media, the latter being relatively stable. See the entry for cartap for some further information on nereistoxin.
  • DegradationThe DT50 value for hydrolysis of thiocyclam hydrogen oxalate at pH 5 is 6 months and at pH values in the range 7-9 is 5-7 days (25 °C). It is degraded in natural water (not specified) via nereistoxin (2) and its oxide (3) to compounds of lower molecular weight. The rate of degradation is increased by irradiation with light. It is degraded by sunlight, the DT50 value being 2-3 days in surface waters (PM).
Thiocyclam hydrogen oxalate Preparation Products And Raw materials
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