(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE

1. Ligand for Palladium-catalyzed C-N cross-coupling.
2. Ligand for Palladium-catalyzed C-S cross-coupling.
3. Ligand for Palladium-catalyzed Kumada couplings of aryl and vinyl tosylates.
4. Ligand for Rhodium-catalyzed hydroacylation of cyclopropenes, an enatioselective desymmetrization method.
5. Ligand for Palladium-catalyzed C-O cross-coupling.
6. Ligand for Rhodium-catalyzed coupling of imidazole derivatives with terminal allenes.
7. Ligand for Ruthenium-catalyzed C-C coupling of alkynes and alcohols to form branched products of carbonyl allylation

Orange powder

It may be used as a ligand in the palladium catalyzed hetero cross-coupling between aryl bromides/aryl triflates with potassium thioacetate to form S-aryl thioacetates.

sold in collaboration with Solvias AG

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings