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(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole

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(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Basic information
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Chemical Properties
  • Melting point:115-117°C
  • Boiling point:111 °C
  • Density 0.93 g/mL at 20 °C(lit.)
  • refractive index -68 ° (C=1, MeOH)
  • Flash point:40 °F
  • storage temp. Refrigerator
  • pka1.02±0.40(Predicted)
  • form Liquid
  • color Colorless to amber
  • Water Solubility Hydrolyzes in water.
  • Sensitive Air & Moisture Sensitive
  • BRN 8492123
  • InChIKeyVMKAFJQFKBASMU-KRWDZBQOSA-N
  • CAS DataBase Reference112022-81-8(CAS DataBase Reference)
Safety Information
MSDS
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Usage And Synthesis
  • Reaction
    1. Convenient catalyst for the enantioselective borane reduction of ketones at ambient temperatures.
    2. Asymmetric synthesis of α-chiral hydroxyalkylphosphines via a catalytic, enantioselective reduction of acylphosphines.
    3. Nickel-catalyzed cross-couplings of benzylic pivalates with arylboroxines: Stereospecific formation of diarylalkanes and triarylmethanes.
    4. Enantioselective reduction of prochiral ketones with NaBH4/Me2SO4/(S)-Me-CBS.
  • Chemical PropertiesColorless to yellow liquid
  • Usessuzuki reaction
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Preparation Products And Raw materials
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole(112022-81-8)Related Product Information
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